Limit on lorentz and CPT violation of the neutron using a two-species noble-Gas maser

A search for sidereal variations in the frequency difference between co-located 129Xe and 3He Zeeman masers sets the most stringent limit to date on leading-order Lorentz and CPT violation involving the neutron, consistent with no effect at the level of 10(-31) GeV.     

Microwave absorption investigation on the formation of YBa2Cu3O7−σ by a binary metal oxide route involving interaction of BaCuO2 and Y2Cu2O5

Low-field microwave absorption has been used to discriminate between the YBa₂Cu₃O_7?σ high temperature superconductor synthesized by reacting the binary metal oxides, BaCuO₂ and Y₂Cu₂O₅, versus synthesis with a single metal oxide route. This discrimination is more clearly seen by microwave absorption than by resistance measurements. Supplementary data was obtained by electron spin resonance in the g=2 region, scanning electron microscopy, thermal analysis and x-ray diffraction techniques. The scanning electron micrographs indicate a more separated granular structure for the material synthesized from the binary oxides. The low field non-resonant microwave absorption, which is characteristic of the superconducting phase, is twice as intense for the binary metal oxide preparation as compared to the single metal oxide preparation. Also, the superconducting transition temperature seems to be several degrees higher for the binary oxide preparation.     

Relationship between semi-conducting properties and sintering conditions for hot pressed galena powders

The decrease in room temperature resistivity produced by hot pressing powdered galena can be related to the degree and mechanism of sintering of the particles. Additions of sulphur or lead alter the semi-conducting properties of the compacts by changing the surface stoichiometry of the particles by grain boundary diffusion, or the bulk stoichiometry by volume diffusion.     

Syntheses, structural determination, and electrochemistry of Ru(2)(Fap)(4)Cl and Ru(2)(Fap)(4)(NO)Cl

Ru(2)(Fap)(4)Cl and Ru(2)(Fap)(4)(NO)Cl, where Fap is the 2-(2-fluoroanilino)pyridinate anion, were synthesized, and their structural, electrochemical, and spectroscopic properties were characterized. Ru(2)(Fap)(4)Cl, which was obtained by reaction between Ru(2)(O(2)CCH(3))(4)Cl and molten HFap, crystallizes in the monoclinic space group P2(1)/c, with a = 11.2365(4) A, b = 19.9298(8) A, c = 19.0368(7) A, beta = 90.905(1) degrees, and Z = 4. The presence of three unpaired electrons on the Ru(2)(5+) core and the 2.2862(3) A Ru-Ru bond length for Ru(2)(Fap)(4)Cl are consistent with the electronic configuration (sigma)(2)(pi)(4)(delta)(2)(pi*)(2)(delta*)(1). The reaction between Ru(2)(Fap)(4)Cl and NO gas yields Ru(2)(Fap)(4)(NO)Cl, which crystallizes in the orthorhombic space group Pbca, with a = 10.0468(6) A, b = 18.8091(10) A, c = 41.7615(23) A, and Z = 8. The Ru-Ru bond length of Ru(2)(Fap)(4)(NO)Cl is 2.4203(8) A, while its N-O bond length and Ru-N-O bond angle are 1.164(8) A and 155.8(6) degrees, respectively. Ru(2)(Fap)(4)(NO)Cl can be formulated as a formal Ru(2)(II,II)(NO(+)) complex with a linear Ru-N-O group, and the proposed electronic configuration for this compound is (sigma)(2)(pi)(4)(delta)(2)(pi*)(3)(delta*)(1). The binding of NO to Ru(2)(Fap)(4)Cl leads to some structural changes of the Ru(2)(Fap)(4) framework and a stabilization of the lower oxidation states of the diruthenium unit. Also, IR spectroelectrochemical studies of Ru(2)(Fap)(4)(NO)Cl show that NO remains bound to the complex upon reduction and that the first reduction involves the addition of an electron on the diruthenium core and not on the NO axial ligand.     

Effective and relative permeabilities of anisotropie porous media

A model composed of a three-dimensional orthogonal network of capillary tubes was used to simulate the flow behavior in an unsaturated anisotropic soil. The anisotropy in the network's permeability was introduced by randomly selecting the radii in the three mutually orthogonal directions of the network tubes from three different lognormal probability distributions, one for each direction. These three directions were assumed to be the principal directions of anisotropy. The sample was gradually drained, with only tubes smaller than a certain diameter remaining full at each degree of saturation. Computer experiments were conducted to determine the network's effective permeability as a function of saturation. The main conclusion was that the relationship between saturation and effective permeability depends on direction. Consequently the concept of relative permeability used in unsaturated flow should be limited to isotropic media and not extended to anisotropic ones.