氧化锌在ITO导电玻璃上电沉积生长过程研究

采用恒电流电解法,以0.1mol/LNH4NO3、0.01mol/LZn(CH3COO)2水溶液为电解液,成功将ZnO电沉积于ITO导电玻璃的表面。利用扫描电子显微镜(SEM)研究了ZnO晶核在ITO导电玻璃表面上的生长过程,对其生长取向、排列方式及微观形貌等方面发生的一系列变化的规律进行了研究和讨论。利用X射线衍射分析(XRD)研究了电沉积时间对ZnO结晶性的影响。结果表明:ZnO在ITO导电玻璃上的电沉积过程,经历了晶核生成、增长成片、片状组合、定向排列、团聚成花、团聚成块等连续过程;随着沉积时间的增长,沉积厚度增加,使得ZnO晶体的结晶性变差。     

Physical and chemical studies on cement containing sugarcane molasses

Molasses is generally used as a grinding aid in cement and as a water reducer and retarder in concrete. In China, the output primarily consists of sugarcane molasses. In this paper, the effects of sugarcane molasses on the physical performance and hydration chemistry of conventional Portland cement were investigated. The setting times, the normal consistency of cement pastes, the compressive strengths and fluidities of the mortars were respectively determined according to Chinese Standard GB/T 1346, GB/T17671 and GB/T 2419. The effect of molasses on the hydration kinetics of cement was investigated using a calorimeter. The hydration products and pore size distribution of the cement pastes were analysed by X-ray powder diffraction, differential scanning calorimetry and a mercury injection apparatus. The results show that a small amount of sugarcane molasses retards the setting and hardening of cement paste and increases the fluidity of cement mortar, while excess molasses accelerates the setting and hardening. Molasses improves significantly the compressive strength at 3d due to the decrease of porosity. The addition of 1.0 % molasses accelerates the formation of ettringite, prevents the second hydration of aluminate phase and delays the hydration of C₃S.     

线性扫描伏安法测定辣椒制品中苏丹红Ⅰ含量

基于苏丹红Ⅰ分子中的-C=C-和-N=N-基团的电活性,在悬汞电极上还原产生还原波,其还原峰高与苏丹红的浓度呈线性关系。据此提出用线性扫描伏安法测定辣椒制品中苏丹红Ⅰ的含量。试验中用悬汞电极为工作电极,饱和甘汞电极为参比电极,铂微电极为对电极,饱和硼砂缓冲溶液(pH 9.2)为支持电解质,并以丙酮作为样品的溶剂,记录在-1 050mV处还原峰电流ip。测得苏丹红Ⅰ的质量浓度在0.1~1.4mg·L-1范围内与其峰高呈线性关系,检出限(3s/k)为9.8μg·L-1。用标准加入法进行回收试验,测得回收率在88.0%~98.4%之间,测定值的相对标准偏差(n=5)在0.72%~5.4%之间。     

解单障碍问题的Lagrangian乘子非匹配网格区域分解法

针对二阶椭圆型单障碍问题提出了一类基于非匹配网格的Lagrang ian乘子非重叠型区域分解方法.并在适当条件下给出了该方法的收敛性分析和收敛速度估计.     

CO2滚动活塞转子膨胀机样机的研制

随着对环境问题的日益关注,自然制冷工质CO2跨临界循环系统的研究受到重视.但其效率还不能满足实际应用的需要,需要开发新的设备提高其运行效率.本文对替代节流阀的CO2滚动活塞转子膨胀机进行研制开发,对流量,气缸的容积,以及吸气控制系统进行了分析与设计,得到了在设计条件下的吸气关闭角和排气角,以及采用机械方法控制吸气量,同时对滚动活塞转子膨胀机内CO2膨胀过程的压力进行了分析,得到了压力随角度变化的情况.     

The α stable distribution model in ocean ambient noise

In view of the non-Gaussian ocean ambient noise,the a stable distribution is applied to the statistical modeling.Firstly,the correspondence between the model characteristic exponent and the sample kurtosis is established based on the similarity in physical meaning of the two.And the kurtosis of the sum of two independent random variables is deduced,and this can be used to explain the kurtosis characteristic of interfered background noise.Secondly,some numerical simulations are made to model samples with higher and lower kurtosis than three,the results show good adaptability in leptokurtic distribution.Finally,three typical samples are taken under quiet environment,air gun interference and ship interference environment.Their Gaussianities are judged by the quantile-quantile plot.And then the four parameters of the model are estimated by the quantile based method and characteristic function based method jointly of the three categories.The statistical law of the characteristic exponent is emphatically analyzed:in the quiet environment,the characteristic exponent is close to 2.0,which is the value of Gaussian model;but for the air gun data,it is between 1.2 and 1.7,which means leptokurtic;and under the interference of the sailing ship,the value of a is related to the ship speed and the distance from the ship source to the receiving location,the more significant the ship impact is,the smaller the characteristic exponent is,which is consistent with the variation of kurtosis of disturbing noise in physical meaning.The results of the model verification show that the a stable distribution behaves well under the above three kinds of trial conditions,especially for the air gun environment which is far superior to the normal distribution.     

Sm3+掺杂稀土硼酸盐玻璃的光谱参数计算和荧光光谱分析

制备了具有高效可见荧光发射的Sm3 掺杂稀土硼酸盐(LBLB)玻璃,对玻璃的吸收和荧光光谱展开了测试与分析.根据Judd-Ofelt理论对吸收光谱进行了拟合,求得Sm3 离子的晶场调节参数Ωt=(2,4,6)分别为6.81×10-20,4.43×10-20和2.58×10-20 cm2,并进一步计算出各能级跃迁的谱线强度、自发辐射跃迁概率、辐射寿命和荧光分支比等光谱参数.紫外光激发下,Sm3 掺杂LBLB玻璃发出明亮的橙红色光.激发光谱表明,氩离子激光器是Sm3 掺杂LBLB玻璃有效的激发光源.     

环境光对谷氨酸钠溶液激光拉曼光谱的影响

探讨了环境光的存在,对谷氨酸钠溶液的激光拉曼光谱的影响。研究表明,不同的环境光,自然光和室内荧光灯光,会对拉曼光谱产生不同的干扰效应,存在着特征谱峰、负峰或尖锐正峰, 干扰的影响不能忽略。建议在进行溶液激光拉曼光谱检测时,需在暗室或暗罩中进行,以完全隔离环境光的影响。     

壳聚糖混合膜酶降解的FTIR分析

生物可降解性是壳聚糖的重要性质之一,但利用傅里叶变换红外光谱(FTIR)研究降解过程中壳聚糖的变化则较少。文章制备了由高脱乙酰度壳聚糖(HDC)和中脱乙酰度壳聚糖(MDC)组成的混合膜。运用FTIR分析了壳聚糖混合膜组分变化对其红外谱图和脱乙酰度(DD)的影响,并研究了该混合膜在溶菌酶的降解作用下红外谱图和脱乙酰度的变化。发现壳聚糖混合膜材料的脱乙酰度与膜中MDC组分的比例呈线性关系;随降解的进行,混合膜的脱乙酰度增加。结果证实了溶菌酶对较低脱乙酰度壳聚糖的选择性降解作用,而且表明FTIR可用于分析壳聚糖混合膜降解过程中的化学变化。     

荧光法研究牛血清白蛋白与三羟基苯基荧光酮-钼(Ⅵ) 配合物探针的作用机理

用荧光光谱法研究了三羟基苯基荧光酮(TH-PF)-钼(Ⅵ)配合物与牛血清白蛋白的结合反应。探讨了TH-PF-Mo(Ⅵ)配合物对蛋白质内源荧光的猝灭机理,并测定了不同温度下的结合常数,温度为25 ℃时,荧光猝灭法测得该反应的结合常数为K=4.78×104 L·mol-1,温度为40 ℃时,荧光猝灭法测得该反应的结合常数为K=3.72×104 L·mol-1。根据Frster非辐射能量转移理论,确定了给体-受体之间的作用距离和能量转移效率(E=0.314),并根据热力学参数确定了TH-PF-Mo(Ⅵ)配合物与牛血清白蛋白之间的作用力类型,以静电引力为主。