全文获取类型
收费全文 | 12931篇 |
免费 | 437篇 |
国内免费 | 48篇 |
专业分类
化学 | 8909篇 |
晶体学 | 57篇 |
力学 | 423篇 |
数学 | 1718篇 |
物理学 | 2309篇 |
出版年
2023年 | 91篇 |
2022年 | 115篇 |
2021年 | 181篇 |
2020年 | 199篇 |
2019年 | 228篇 |
2018年 | 194篇 |
2017年 | 151篇 |
2016年 | 336篇 |
2015年 | 342篇 |
2014年 | 365篇 |
2013年 | 702篇 |
2012年 | 864篇 |
2011年 | 890篇 |
2010年 | 537篇 |
2009年 | 416篇 |
2008年 | 825篇 |
2007年 | 788篇 |
2006年 | 728篇 |
2005年 | 677篇 |
2004年 | 632篇 |
2003年 | 570篇 |
2002年 | 458篇 |
2001年 | 221篇 |
2000年 | 228篇 |
1999年 | 132篇 |
1998年 | 153篇 |
1997年 | 130篇 |
1996年 | 169篇 |
1995年 | 97篇 |
1994年 | 97篇 |
1993年 | 91篇 |
1992年 | 92篇 |
1991年 | 67篇 |
1990年 | 77篇 |
1989年 | 61篇 |
1988年 | 65篇 |
1986年 | 54篇 |
1985年 | 83篇 |
1984年 | 106篇 |
1983年 | 67篇 |
1982年 | 79篇 |
1981年 | 82篇 |
1980年 | 88篇 |
1979年 | 65篇 |
1978年 | 79篇 |
1977年 | 83篇 |
1976年 | 89篇 |
1975年 | 66篇 |
1974年 | 43篇 |
1973年 | 50篇 |
排序方式: 共有10000条查询结果,搜索用时 421 毫秒
991.
Gnida M Margulès L Cosléou J Bocquet R Demaison J Mkadmi EB Bürger H Harder H Mäder H 《Journal of Molecular Spectroscopy》2000,200(1):40-54
The present paper deals with the analysis of the microwave, millimeter-wave, and infrared spectra of (28)SiHF(3) in its ground, v(6) = 1 and v(4) = 1 excited states. The former was observed up to 1055 GHz leading to the determination of one octic centrifugal distortion constant, L(J) = -0.0749(55) μHz. Furthermore the interaction term ||h(3,GS) || = 1.1032(70) mHz has been fitted from splittings of six K = 3 lines. The excited states have been regarded as isolated ones. This enabled fits according the Q-, D-, and QD-reduction schemes proposed by E. I. Lobodenko, O. N. Sulakshina, V. I. Perevalov, and Vl. G. Tyuterev, (J. Mol. Spectrosc. 126, 159-170 (1987)) and further developed by J. K. G. Watson, C. Gerke, H. Harder, and K. Sarka, (J. Mol. Spectrosc. 187, 131-141 (1997)) and Harder (J. Mol. Spectrosc. 194, 145 (1999)). A multiple fit analysis was performed confirming the assumption that the excited states are not affected by intervibrational resonances. Finally the millimeter spectrum of (29)SiHF(3) and (30)SiHF(3) in their ground state was also measured up to 460 GHz and accurate rotational and centrifugal distortion parameters were derived. Copyright 2000 Academic Press. 相似文献
992.
J.-M. Chauveau C. Morhain B. Lo B. Vinter P. Vennéguès M. Laügt D. Buell M. Tesseire-Doninelli G. Neu 《Applied Physics A: Materials Science & Processing》2007,88(1):65-69
Non polar ZnO and (Zn, Co)O layers were successfully grown on (11̄02) sapphire (R-plane sapphire). The growth process was
shown to directly influence the surface morphology as well as the strain state in (112̄0) ZnO (A-plane ZnO). The dominant
defect lines seen in photoluminescence were due to basal stacking faults as demonstrated by means of selective photoluminescence
and transmission electron microscopy. We present a novel method for growing high quality A-plane ZnO by inserting a (Zn, Co)O
thin buffer layer, which strongly reduced the surface roughness. Finally (Zn, Mg)O/ZnO quantum well structures were grown
on such a buffer layer. These quantum wells exhibited no intrinsic quantum confined Stark effect.
PACS 81.05.Dz; 81.15.Hi; 78.67.Hc; 68.65.Fg 相似文献
993.
M. C. Desjonquères C. Barreteau G. Autès D. Spanjaard 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,55(1):23-27
We show that considerable orbital magnetic moments and magneto-crystalline anisotropy energies are obtained for a Fe monatomic
wire described in a tight-binding method with intra-atomic electronic interactions treated in a full Hartree Fock (HF) decoupling
scheme.
Even though the use of the orbital polarization ansatz with simplified Hamiltonians leads to fairly good results when the
spin magnetization is saturated this is not the case of unsaturated systems. We conclude that the full HF scheme is necessary
to investigate low dimensional systems. 相似文献
994.
Patrick F. Conforti Manish Prasad Barbara J. Garrison 《Applied Surface Science》2007,253(15):6386-6389
The effects of absorption of 7.9 and 5.0 eV photons by the polymer poly(methyl methacrylate) are studied using molecular dynamics simulations. By rapidly depositing a critical amount of thermal energy in the surface region (greater than 0.03 eV Å−3), a pressure wave is formed which causes spallation of the substrate. If there is only one photon absorbed per monomer unit of the polymer, the 7.9 eV photons can supply sufficient energy density to initiate ejection. 相似文献
995.
We address the problem of degree of polarization (DOP) estimation in images limited by additive Gaussian detector noise. We derive and analyze the probability density function (PDF) of the pixelwise DOP estimate, which is shown to have significantly different statistical properties than when noise is Gamma distributed (speckle). We then determine the Cramer-Rao Lower Bound and the maximum likelihood estimator of the DOP. We deduce from this study practical solutions for characterizing and reducing the noise in these images. 相似文献
996.
Nadia Tagnaouti Sven Loebrich Frank Heisler Yvonne Pechmann Susanne Fehr Adèle De Arcangelis Elisabeth Georges-Labouesse Josephine C Adams Matthias Kneussel 《BMC neuroscience》2007,8(1):28
Background
The kelch repeat protein muskelin mediates cytoskeletal responses to the extracellular matrix protein thrombospondin 1, (TSP1), that is known to promote synaptogenesis in the central nervous system (CNS). Muskelin displays intracellular localization and affects cytoskeletal organization in adherent cells. Muskelin is expressed in adult brain and has been reported to bind the Cdk5 activator p39, which also facilitates the formation of functional synapses. Since little is known about muskelin in neuronal tissues, we here analysed the tissue distribution of muskelin in rodent brain and analysed its subcellular localization using cultured neurons from multiple life stages. 相似文献997.
Sakari Leino Patrick JC May Paavo Alku Lassi A Liikkanen Hannu Tiitinen 《BMC neuroscience》2007,8(1):78
Background
In the field of auditory neuroscience, much research has focused on the neural processes underlying human sound localization. A recent magnetoencephalography (MEG) study investigated localization-related brain activity by measuring the N1m event-related response originating in the auditory cortex. It was found that the dynamic range of the right-hemispheric N1m response, defined as the mean difference in response magnitude between contralateral and ipsilateral stimulation, reflects cortical activity related to the discrimination of horizontal sound direction. Interestingly, the results also suggested that the presence of realistic spectral information within horizontally located spatial sounds resulted in a larger right-hemispheric N1m dynamic range. Spectral cues being predominant at high frequencies, the present study further investigated the issue by removing frequencies from the spatial stimuli with low-pass filtering. This resulted in a stepwise elimination of direction-specific spectral information. Interaural time and level differences were kept constant. The original, unfiltered stimuli were broadband noise signals presented from five frontal horizontal directions and binaurally recorded for eight human subjects with miniature microphones placed in each subject's ear canals. Stimuli were presented to the subjects during MEG registration and in a behavioral listening experiment. 相似文献998.
999.
Dr. Ilaria Gamba Iria Salvadó Gustavo Rama Miriam Bertazzon Mateo I. Sánchez Prof. Víctor M. Sánchez‐Pedregal Prof. José Martínez‐Costas Rosa F. Brissos Prof. Patrick Gamez Prof. José L. Mascareñas Prof. Miguel Vázquez López Prof. M. Eugenio Vázquez 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(40):13369-13375
A new bipyridine building block has been used for the solid‐phase synthesis of dinuclear DNA‐binding ruthenium(II) metallopeptides. Detailed spectroscopic studies suggest that these compounds bind to the DNA by insertion into the DNA minor groove. Moreover, the potential of the solid‐phase peptide synthesis approach is demonstrated by the straightforward synthesis of an octaarginine derivative that shows effective cellular internalization and cytotoxicity linked with strong DNA interaction, as evidenced by steady‐state fluorescence spectroscopy and AFM studies. 相似文献