Low temperature synthesis and characterization of Mn3O4 nanoparticles

Heating hydrous manganese (II) hydroxide gel at 85 °C for 12 hours produces Mn₃O₄ nanoparticles. They were characterized by X-ray powder diffraction (XRD) and infrared spectroscopy (FTIR). The particle size estimated from the SEM and X-ray peak broadening is approximately 32 nm, showing them to be nanocrystalline. EPR measurements confirm a typical Mn²⁺signal with a highly resolved hyperfine structure.      

Synthesis, structural and conductivity characterization of alginic acid–Fe3O4 nanocomposite

Alginic acid–Fe₃O₄ nanocomposite is synthesized by the precipitation of Fe₃O₄ in the presence of alginic acid (AA). Structural, surface, morphological, thermal and electrical transport properties of the nanocomposite were performed by XRD, FT-IR, TEM-SEM, TGA and conductivity measurements respectively. FT-IR analysis revealed that Fe₃O₄ NPs are strongly capped with AA and TGA analysis showed that nanocomposite have 80% of Fe₃O₄ content. TEM analysis of Fe₃O₄ NPs show an average particle size of 9.5 nm, and upon nanocomposite formation with AA these particles are observed to form aggregates of ~150 nm. The frequency-dependency of the AC conductivity show electrode polarization effect. Analysis of electrical modulus and dielectric permittivity functions suggest that ionic and polymer segmental motions are strongly coupled. DC electrical conductivity is strongly temperature dependent, and is classified into three regions over a limited temperature range of up to 100 °C.     

Synthesis and magnetic characterization of Zn0.7Ni0.3Fe2O4 nanoparticles via microwave-assisted combustion route

We report on the synthesis of Zn_0.7Ni_0.3Fe₂O₄ nanoparticles via microwave assisted combustion route by using urea as fuel. XRD and FT-IR analyses confirm the composition and structure as spinel ferrite. The crystallite size estimated from XRD (16.4 nm) and the magnetic core size (15.04 nm) estimated from VSM agree well, while a slightly smaller magnetic diameter reflects a very thin magnetically dead layer on the surface of the nanoparticles. Morphological investigation of the products was done by TEM which revealed the existence of irregular shapes such spherical, spherodial and polygon. Magnetization measurements performed on Zn_0.7Ni_0.3Fe₂O₄ nanoparticles showed that saturation was not attained at even in the high magnetic field. The sample shows superparamagnetic behavior at around the room temperature and ferromagnetic behavior below the blocking temperature which is measured as 284 K.     

Propagation properties of anomalous hollow beams in a turbulent atmosphere

Propagation of circular and elliptical anomalous hollow beams in a turbulent atmosphere is investigated in detail. Based on the extended Huygens–Fresnel integral, analytical formulae for the average irradiance of circular and elliptical anomalous hollow beams propagating in a turbulent atmosphere are derived. The irradiance and spreading properties of circular and elliptical anomalous hollow beams in a turbulent atmosphere and in free space are studied numerically. It is found that circular and elliptical anomalous hollow beams at short propagation distance in turbulent atmosphere have similar propagation properties to those of free space, while at long propagation distance, circular and elliptical anomalous hollow beams eventually become circular Gaussian beams in a turbulent atmosphere, which is much different from their propagation properties in free space. The conversion from an anomalous hollow beam to a circular Gaussian beam becomes quicker and the beam spot spreads more rapidly for a larger structure constant, a shorter wavelength and a smaller waist size of the initial beam.     

Arbitrary laser beam propagation in free space

The propagation of arbitrary laser beams in free space is examined. For this purpose, starting with an incident field of arbitrary field distribution, the intensity at the receiver plane is formulated via Huygens Fresnel diffraction integral. Arbitrary source field profile is produced by decomposing the source into incremental areas (pixels). The received field through the propagation in free space is found by superposing the contributions from all source incremental areas. The proposed method enables us to evaluate the received intensity originating from any type of source field. Using the arbitrary beam excitation, intensity of various laser beams such as cos-Gaussian, cosh-Gaussian, general type beams are checked to be consistent with the already existing results in literature, and the received intensity distributions are obtained for some original arbitrary beam field profiles. Our received intensity formulation for the arbitrary source field profiles presented in this paper can find application in optics communication links, reflection from rough surfaces, optical cryptography and optical imaging systems.     

Synthesis and magnetic characterization of Zn0.6Ni0.4Fe2O4 nanoparticles via a polyethylene glycol-assisted hydrothermal route

Zn-doped nickel ferrite nanoparticles (Zn_0.6Ni_0.4Fe₂O₄) have been prepared via a surfactant, polyethylene glycol assisted hydrothermal route. X-ray powder diffractometry (XRD), Fourier transform infrared spectroscopy, transmission electron microscopy (TEM), and vibrating scanning magnetometry (VSM) were used for the structural, morphological, and magnetic characterizations of the product, respectively. TEM analysis revealed that the nanoparticles have a narrow size distribution, with average particle size of 15±1 nm, which agrees well with the XRD based estimate of 14±2 nm. The absence of saturation and remanent magnetization, and coercivity in the high temperature region of the M-H curve and non-zero magnetic moments indicate superparamagnetism of the nanoparticles with a canted spin structure. The appearance of a peak on the temperature-dependent zero-field cooling magnetization curve at ∼190 K indicates the blocking temperature of the sample.     

Intensity fluctuations of partially coherent laser beam arrays in?weak atmospheric turbulence

The intensity fluctuation of a partially coherent laser beam array is examined. For this purpose, the on-axis scintillation index at the receiver plane is analytically formulated via the extended Huygens–Fresnel diffraction integral in conditions of weak atmospheric turbulence. The effects of the propagation length, number of beamlets, radial distance, source size, wavelength of operation and coherence level on the scintillation index are investigated for a horizontal propagation path. It is found that, regardless of the number of beamlets, the scintillation index always rises with an increasing propagation length. If laser beam arrays become less coherent, the scintillation index begins to fall with growing source sizes. Given the same level of partial coherence, slightly less scintillations will occur when the radial distance of the beamlets from the origin is increased. At partial coherence levels, lower scintillations are observed for larger numbers of beamlets. Both for fully and partially coherent laser beam arrays, scintillations will drop on increasing wavelengths.     

Twist phase-induced reduction in scintillation of a partially coherent beam in turbulent atmosphere

The scintillation index of a Gaussian Schell-model beam with twist phase (i.e., twisted GSM beam) in weak turbulent atmosphere is formulated with the help of a tensor method. Variations of the scintillation index of a twisted GSM beam on propagation in turbulent atmosphere are studied in detail. It is interesting to find that the scintillation index of a twisted GSM beam can be smaller than that without twist phase in weak turbulent atmosphere. Thus, modulation of the twist phase of a partially coherent beam provides a new way to reduce turbulence-induced scintillation.     

Generalized expression for optical source fields

A generalized optical beam expression is developed that presents the majority of the existing optical source fields such as Bessel, Laguerre–Gaussian, dark hollow, bottle, super Gaussian, Lorentz, super-Lorentz, flat-topped, Hermite–sinusoidal-Gaussian, sinusoidal-Gaussian, annular, Gauss–Legendre, vortex, also their higher order modes with their truncated, elegant and elliptical versions. Source intensity profiles derived from the generalized optical source beam fields are checked to match the intensity profiles of many individual known beam types. Source intensities for several interesting beam combinations are presented. Our generalized optical source beam field expression can be used to examine both the source characteristics and the propagation properties of many different optical beams in a single formulation.     

Effects of extremely strong turbulent medium on scintillations of partially coherent annular and flat-topped Gaussian beams

Scintillation index of partially coherent annular and partially coherent flat-topped Gaussian beams propagating in horizontal links is found at the receiver origin when these beams propagate in extremely strong atmospheric turbulence. Scintillation index of coherent versions of such beams attain unity saturation value whereas the decrease in the degree of source coherence results in the decrease of the scintillations. At a fixed degree of partial coherence, thin ring sized annular beams possess smaller scintillations than thick ones. For partially coherent flat-topped Gaussian beams, higher flatness yields smaller intensity fluctuations. In extremely strong turbulence, partially coherent annular and partially coherent flat-topped Gaussian beams have smaller scintillations when compared to partially coherent single Gaussian beam scintillations.