{N‐[2‐(η5‐Cyclopentadienyl)ethyl]‐4‐toluenesulfonamido‐N,O}(tetrahydrofuran‐O)bis(trifluoromethanesulfonato‐O)titanium(II)

The title compound, [Ti(CF₃O₃S)₂(C₁₄H₁₅NO₂S)(C₄H₈O)], contains a unique ligand system in which the Ti ion is bound to the N and O atoms of a 2‐p‐toluene­sulfon­amide ligand, which is linked by an ethyl group to a coordinated cyclo­penta­diene moiety. The distorted octahedral geometry about the Ti ion is completed by two tri­fluoro­methane­sulfonate ligands and a tetra­hydro­furan mol­ecule. Comparison with related compounds shows that both the Ti—N and Ti—O bonds of the sulfon­amide, although longer than normal values, indicate significant bonding interactions.     

Atomgewichte

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Atomgewichte

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Allgemeine Methoden

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