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131.
Y.N. Rao D. Banerjee A. Datta S.K. Das R. Guin A. Saha 《Radiation Physics and Chemistry》2010,79(12):1240-1246
Aqueous dispersions of highly stable, redispersible silver nanoparticles (Ag NPs) were synthesized using gamma radiolysis with gum acacia as a protecting agent. The formation of nanosized silver was confirmed by its characteristic surface plasmon absorption peak at around 405 nm in UV–vis spectra. The size of the silver nanoparticles can be tuned by controlling the radiation dose, ratio of gum acacia to silver ions and also the ionic strength of the medium. Dynamic light scattering (DLS) measurement of the as-synthesized nanoparticles indicated the size less than 3 nm at higher dose of radiation and this also corroborated the size measurement from the width of the corresponding X-ray diffraction (XRD) peak. The face centered cubic (fcc) crystallinity of the nanoparticles was evident from XRD and high resolution transmission electron microscopic (HRTEM) measurements. Fourier transform infra-red (FTIR) spectroscopic data indicate a bonding of Ag NPs with COO? group of acacia through bridging bidentate linkage. 相似文献
132.
A two dimensional simulation study was performed to investigate the photoacoustic signal properties of non-aggregated and aggregated erythrocytes. Spatial distributions of non-aggregated blood samples were generated by employing a Monte Carlo method and aggregated blood samples were simulated using a hexagonal packing scheme. For the non-aggregating case photoacoustic signals demonstrated a monotonic rise with hematocrit. For the aggregating case it was found that spectral (<20 MHz) intensity increased (11 dB at 15.6 MHz) when the aggregate size increased. This study strongly suggests that the assessment of erythrocyte aggregation level in human blood might be possible by using a photoacoustic spectroscopic method. 相似文献
133.
Swarup Kumar Maji Anup Mondal Bibhutosh Adhikary Basudeb Karmakar 《Journal of Physics and Chemistry of Solids》2011,72(6):784-788
We report the formation of mesoporous zinc sulphide, composed by the fine network of nanoparticles, which was formed via a single precursor Zn(SOCCH3)2Lut2 complex. The complex was chemically synthesized using zinc carbonate basic, 3,5-lutidine and thioacetic acid, in air. The metal precursor complex was characterized using different conventional techniques. Thermogravimetric analysis (TGA) result indicates that the decomposition of the complex starts at 100 °C and continues up to 450 °C, finally yielding ZnS. ZnS nanocrystals were characterized by powder X-ray diffraction (XRD) technique, field emission scanning electron microscopy (FESEM), N2-sorption isotherm, UV-vis spectroscopy and photoluminescence (PL) spectroscopy. The grain diameter of nanocrystals was found to be 4-5 nm. The material followed Type-IV N2-sorption isotherm, which is the characteristic of mesoporous materials. The band gap energy, as obtained from optical measurements was around 3.8 eV. 相似文献
134.
We present simple and accurate analytical expressions for transmission coefficient at the splice with angular offset and transverse offset in case of first higher mode propagation in graded index fibers. We employ the simple series expression for first higher order modal field for graded index fiber. The evaluation of the concerned parameters based on our formalism requires very little computations. Here, we show that our estimations match excellently well with the exact results in case of step and parabolic index fibers. Further, splice being highly tolerant for longitudinal separation, our analysis is judiciously restricted to the case of transverse and angular mismatches only. The analysis should find application in dual mode graded index fiber in all optical technology. 相似文献
135.
In this study, in situ control growth of bismuth nanoparticles (Bi0 NPs) was demonstrated in bismuth-based glass dielectrics under an electron beam (EB) irradiation at room temperature. The
effects of EB irradiation were investigated in situ using transmission electron microscopy (TEM), selected-area electron diffraction
and high-resolution transmission electron microscopy. The EB irradiation for 2–8 min enhanced the construction of bismuth
nanoparticles with a rhombohedral structure and diameter of 4–9 nm. The average particle size was found to increase with the
irradiation time. Bismuth metal has a melting point of 271 °C and this low melting temperature makes easy the progress of
energy induced structural changes during in situ TEM observations. This is a very useful technique in nano-patterning for
integrated optics and other applications. 相似文献
136.
Yuri P. Rybakov Georgi N. Shikin Yuri A. Popov Bijan Saha 《Central European Journal of Physics》2011,9(5):1165-1172
We consider an interacting system of massless scalar and electromagnetic fields, with the Lagrangian explicitly depending
on the electromagnetic potentials, i.e., interaction with broken gauge invariance. The Lagrangian for interaction is chosen
in such a way that the electromagnetic field equation acquires an additional term, which in some cases is proportional to
the vector potential of the electromagnetic field. This equation can be interpreted as the equation of motion of photon with
induced nonzero rest-mass. This system of interacting fields is considered within the scope of Bianchi type-I (BI) cosmological
model. It is shown that, as a result of interaction the isotropization process of the expansion takes place. 相似文献
137.
A device for performing vector transmission spectroscopy on aqueous and polar solvent specimens at terahertz frequencies is presented. The device enables the direct measurement of the complex dielectric function across the terahertz band using a Fourier transform IR spectrometer for lossy solutions. Using microfluidic sampling, specimen handling is straightforward and direct measurements on polar specimens are made possible. The method is scalable to longer or shorter wavelengths. 相似文献
138.
139.
Sumit Saha 《Tetrahedron》2010,66(24):4278-3130
Enantioselective synthesis of two anti-tumor antibiotics, (−)-methylenolactocin and (−)-protolichesterinic acid, has been achieved through titanocene(III) chloride mediated radical cyclization reaction starting from commercially available d-mannitol. Titanocene(III) chloride (Cp2TiCl) was prepared in situ from commercially available titanocene dichloride (Cp2TiCl2) and zinc dust in THF. 相似文献
140.
Sujoy Kumar Saha 《Experimental Thermal and Fluid Science》2010,34(6):744-752
The heat transfer and the pressure drop characteristics of turbulent flow of air (10,000 < Re < 100,000) through rectangular and square ducts with combined internal axial corrugations on all the surfaces of the ducts and with twisted-tape inserts with and without oblique teeth have been studied experimentally. The axial corrugations in combination with twisted-tapes of all types with oblique teeth have been found to perform better than those without oblique teeth in combination with axial corrugations. The heat transfer and the pressure drop measurements have been taken in separate test sections. Heat transfer tests were carried out in electrically heated stainless steel ducts incorporating uniform wall heat flux boundary conditions. Pressure drop tests were carried out in acrylic ducts. The flow friction and thermal characteristics are governed by duct aspect ratio, corrugation angle, corrugation pitch, twist ratio, space ratio, length, tooth horizontal length and tooth angle of the twisted-tape, Reynolds number and Prandtl number. Correlations developed for friction factor and Nusselt number have predicted the experimental data satisfactorily. The performance of the geometry under investigation has been evaluated. It has been found that on the basis of constant pumping power, up to 55% heat duty increase occurs for the combined axial corrugation and regularly spaced twisted-tape elements inserts with oblique teeth case compared to without oblique teeth twisted-tape inserts cases in the measured experimental parameters space. On the constant heat duty basis, the pumping power has been reduced up to 47% for the combined enhancement geometry than the individual enhancement geometries. However, full-length and short-length twisted-tapes with oblique teeth in combination with axial corrugations show only marginal improvements over the twisted-tapes without oblique teeth. 相似文献