A new structural form for a decanuclear copper(II) assembly

The synthesis and structure of a novel decanuclear copper(II) cage is reported. The assembly of the cage is facilitated by the cumulative coordinative interaction of tert-butyl phosphonate, 2-pyridylpyrazole and hydroxide ligands with copper(II) ions. Magnetic studies of this decanuclear copper(II) cage indicate complex antiferromagnetic behaviour.     

A hydrogelator derived from polymerisable amphiphilic octadecyl maleamic acid and its potential as a reactor in aqueous copolymerisation reactions

Octadecyl maleamic acid, a polymerisable surfactant, on coversion to its sodium salt, is shown to exhibit hydrogelation phenomenon. This hydrogelator, consisting of a lamellar structure is further shown to act as an organized reactor for controlled polymerisation reactions in order to generate copolymers with a narrow weight and size distribution.     

A new structural form of tin in a double O-capped cluster

A novel hexameric organooxotin cage [{(n-BuSn)3(PhO)3O}2{HPO3}4] 1 has been assembled by the reaction of [n-BuSnO(OH)] with (PhO)2P(O)H. The structure of 1 consists of two O-capped Sn3 clusters that are attached to each other by four bridging tripodal [HPO3]2- ligands.     

A Robin-type non-overlapping domain decomposition procedure for second order elliptic problems

This article deals with the analysis of an iterative non-overlapping domain decomposition (DD) method for elliptic problems, using Robin-type boundary condition on the inter-subdomain boundaries, which can be solved in parallel with local communications. The proposed iterative method allows us to relax the continuity condition for Lagrange multipliers on the inter-subdomain boundaries. In order to derive the corresponding discrete problem, we apply a non-conforming Galerkin method using lowest order Crouzeix–Raviart elements. The convergence of the iterative scheme is obtained by proving that the spectral radius of the matrix associated with the fixed point iterations is less than 1. Parallel computations have been carried out and the numerical experiments confirm the theoretical results established in this paper.