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91.
R. Sankar 《European Polymer Journal》2007,43(11):4639-4646
8-Hydroxy-5-azoquinoline phenyl methacrylate-formaldehyde (8H5AQPMA-F) macromonomer was prepared from methacryloyl chloride with condensation products of 8-hydroxy-5-azoquinoline phenol-formaldehyde, and polymerized in DMF at 70 °C using benzoyl peroxide as free radical initiator. Poly(8H5AQPMA-F) was characterized by infrared and nuclear magnetic resonance spectroscopic techniques. Polychelates were obtained when the DMF solution of the resin containing few drops of ammonia was treated with the aqueous solution of Cu(II)/Ni(II). Elemental analysis of the polychelates indicates that the metal to ligand ratio was about 1:2. The IR spectra of polychelates suggest that the metals were coordinated through the oxygen of the phenolic-OH group and nitrogen of the quinoline ligand. The DRS and magnetic moment data indicate a square planar for Cu(II) complex whereas octahedral for Ni(II) complex. The TGA data revealed the thermal stability of the resin and the polychelates. X-ray diffraction study revealed the incorporation of the metal ions significantly enhanced the degree of crystallinity. The sorption properties of the chelate-forming resin towards various divalent metal ions [Cu(II) and Ni(II)] were studied as a function of pH and electrolyte. 相似文献
92.
Eight differently substituted title dye compounds have been investigated regarding intersystem crossing, triplet state, fluorescence and singlet excited state pKa properties. In general, non-halogenated oxazines and thiazines as well as a mono bromooxazine show very low triplet quantum yields, phi tau (less than 0.03) and relatively long triplet lifetimes (approximately 40 microseconds) in acidic methanol. The phi tau data correlate well with known singlet oxygen yields. In basic methanol no triplet transient is observed but a significant yield of a ground state transient protonated (base dye) form is produced with a short lifetime, approximately 400 ns. Fluorescence can be seen simultaneously from both the excited base and the protonated base dye forms in basic methanol. For iodinated oxazine or thiazines, the triplet yield increases and can be as high as 0.5 (diiodo case) in acidic methanol. The triplet lifetimes are further shortened to approximately 10 microseconds compared to the non-iodinated derivatives above. The triplet yields of the iodo compounds are higher or equal to known singlet oxygen yields. In basic methanol triplet yields up to 0.2 can be seen, the triplet lifetime are shortened still further to 1 microsecond but no observable protonated form is produced (in distinction to the non-iodinated cases). Consideration is given to the correlation of triplet and singlet oxygen yields, ground and excited pKa properties, spin-orbit coupling and internal conversion properties, solvent effects, and phototherapeutic activity of these dyes. 相似文献
93.
Three spray reagents for the detection of amino-acids on silica-gel thin-layer chromatography plates are reported. The reagents produce various colours, which may be used to identify some of the amino-acids directly, and assist in their detection. 相似文献
94.
A. Morisato H. C. Shen S. S. Sankar B. D. Freeman I. Pinnau C. G. Casillas 《Journal of Polymer Science.Polymer Physics》1996,34(13):2209-2222
Pure gas and hydrocarbon vapor transport properties of blends of two glassy, polyacetylene-based polymers, poly(1-trimethylsilyl-1-propyne) [PTMSP] and poly(1-phenyl-1-propyne) [PPP], have been determined. Solid-state CP/MAS NMR proton rotating frame relaxation times were determined in the pure polymers and the blends. NMR studies show that PTMSP and PPP form strongly phase-separated blends. The permeabilities of the pure polymers and each blend were determined with hydrogen, nitrogen, oxygen, carbon dioxide, and n-butane. PTMSP exhibits unusual gas and vapor transport properties which result from its extremely high free volume. PTMSP is more permeable to large organic vapors, such as n-butane, than to small, permanent gases, such as hydrogen. PPP exhibits gas permeation characteristics of conventional low free volume glassy polymers; PPP is more permeable to hydrogen than to n-butane. In PTMSP/PPP blends, both n-butane permeability and n-butane/hydrogen selectivity increase as the PTMSP content of the blends increases. © 1996 John Wiley & Sons, Inc. 相似文献
95.
Mal SS Nsouli NH Dickman MH Kortz U 《Dalton transactions (Cambridge, England : 2003)》2007,(25):2627-2630
Reaction of [Ru(p-cymene)Cl2]2 with [H7P8W48O184]33- (P8W48) in aqueous acidic medium results in the organometallic derivative [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor. 相似文献
96.
Subhash C. Basak Gerald J. Niemi Gilman D. Veith 《Journal of mathematical chemistry》1991,7(1):243-272
Topological indices (TIs) have been used to study structure-activity relationships (SAR) with respect to the physical, chemical, and biological properties of congeneric sets of molecules. Since there are many TIs and many are correlated, it is important that we identify redundancies and extract useful information from TIs into a smaller number of parameters. Moreover, it is important to determine if TIs, or parameters derived from TIs, can be used for global SAR models of diverse sets of chemicals. We calculated seventy-one TIs for three groups of molecules of increasing complexity and diversity: (a) 74 alkanes, (b) 29 alkylbenzenes, and (c) 37 polycyclic aromatic hydrocarbons (PAHs). Principal components analysis (PCA) revealed that a few principal components (PCs) could extract most of the information encoded by the seventy-one TIs. The structural basis of the first few PCs could be derived from their pattern of correlation with individual TIs. For the three sets of molecules, viz. alkanes, alkylbenzenes and PAHs, PCs were able to predict the boiling points reasonably well. Also, for the combined set of 140 chemicals consisting of the alkanes, alkylbenzenes and PAHs, the derived PCs were not as effective in predicting properties as in the case of individual classes of compounds. 相似文献
97.
98.
Rupom Borah Eramoni Saikia Sankar Jyoti Bora Bolin Chetia 《Tetrahedron letters》2017,58(12):1211-1215
A green and facile novel procedure has been developed for the synthesis of Cu2O nanoparticles within a very short reaction time using banana pulp extract as a reducing agent. The synthesized nanoparticles are well characterized by SEM (Scanning Electron Microscope), TEM (Transmission Electron Microscope) and powder XRD (X-ray Diffraction) methods. An environmental benign and highly efficient protocol for the ipso-hydroxylation of aryl and hetero arylboronic acids using bio-fabricated Cu2O nanoparticles as a catalyst and aqueous H2O2 as an oxidant has also been developed. The main advantages of this protocol are the base free reaction condition, reusable and heterogeneous catalytic system, and short reaction time with excellent yields. 相似文献
99.
Debaki Ghosh Souradeep Basu Monisha Singha Joyee Das Prabuddha Bhattacharya Amit Basak 《Tetrahedron letters》2017,58(21):2014-2018
Three crescent shaped heterocycle-fused phenanthrene based systems 1–3 have been synthesized starting from benzene (or substituted benzene) 1,2-bis-propargyl alcohols. Bis-alkylation with propargylic bromides provided the key intermediate, the bis-propargyl bis-ethers. In spite of the possibility of many competing reactions, the latter underwent facile double Garratt-Braverman cyclization to provide compounds 1–3 in near quantitative yield, in a striking reaction involving the formation of four C–C bonds in a single step. Compounds 1–3 showed binding interaction with DNA, predominantly, via groove binding along with partial intercalation (combilexins). Molecular docking study supported the proposed binding modes. 相似文献
100.
The current understanding of deviations of human microbiota caused by antibiotic treatment is poor. In an attempt to improve it, a proof-of-principle spectroscopic study of the breath of one volunteer affected by a course of antibiotics for Helicobacter pylori eradication was performed. Fourier transform spectroscopy enabled searching for the absorption spectral structures sensitive to the treatment in the entire mid-infrared region. Two spectral ranges were found where the corresponding structures strongly correlated with the beginning and end of the treatment. The structures were identified as methyl ester of butyric acid and ethyl ester of pyruvic acid. Both acids generated by bacteria in the gut are involved in fundamental processes of human metabolism. Being confirmed by other studies, measurement of the methyl butyrate deviation could be a promising way for monitoring acute gastritis and anti-Helicobacter pylori antibiotic treatment. 相似文献