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41.
Akhil R Chakravarty Pattubala A. N. Anreddy Bidyut K. Santra Anitha M. Thomas 《Journal of Chemical Sciences》2002,114(4):391-401
Redox active mononuclear and binuclear copper(II) complexes have been prepared and structurally characterized. The complexes have planar N-donor heterocyclic bases like 1,10-phenanthroline
(phen), dipyridoquinoxaline (dpq) and dipyridophenazine (dppz) ligands that are suitable for intercalation to B-DNA. Complexes
studied for nuclease activity have the formulations [Cu(dpq)2(H2O)] (ClO4)2.H2O (1), [CuL(H2O)2(μ-ox)](ClO4)2 (L = bpy,2; phen,3; dpq,4; and dppz,5) and [Cu(L)(salgly)] (L = bpy,6; phen,7; dpq,8; and dppz,9), where salgly is a tridentate Schiff base obtained from the condensation of glycine and salicylaldehyde. The dpq complexes
are efficient DNA binding and cleavage active species. The dppz complexes show good binding ability but poor nuclease activity.
The cleavage activity of thebis-dpq complex is significantly higher than thebis-phen complex of copper(II). The nuclease activity is found to be dependent on the intercalating nature of the complex and
on the redox potential of the copper(II)/copper(I) couple. The ancillary ligand plays a significant role in binding and cleavage
activity. 相似文献
42.
The presence of hexavalent chromium in wastewater is a potential hazard to aquatic animals and humans. There are various mechanisms proposed, kinetic models used and adsorption isotherms employed for the efficient removal of hexavalent chromium from industrial and municipal wastewaters using biosorbents. Biosorption of heavy metals is a most promising technology involved in the removal of toxic metals from industrial waste streams and natural waters. Metal removal treatment systems using microorganisms are cheap because of the low cost of sorbent materials used and may represent a practical replacement to conventional processes. The present review discusses hexavalent chromium biosorption properties of algae, bacteria, fungi, and agricultural products, as well as adsorption properties of non-living substances. Cell walls are responsible for biosorption of dead biomaterial; compositions of cell walls are discussed. Chemical modification of biosorbents, optimization of biosorption parameters, mixtures of different biosorbents and the study of biosorption mechanisms are the main keys to transfer the biosorption process from lab to industry. 相似文献
43.
Okada Y Dhital C Zhou W Huemiller ED Lin H Basak S Bansil A Huang YB Ding H Wang Z Wilson SD Madhavan V 《Physical review letters》2011,106(20):206805
We study interference patterns of a magnetically doped topological insulator Bi(2-x)Fe(x)Te(3+d) by using Fourier transform scanning tunneling spectroscopy and observe several new scattering channels. A comparison with angle-resolved photoemission spectroscopy allows us to unambiguously ascertain the momentum-space origin of distinct dispersing channels along high-symmetry directions and identify those originating from time-reversal symmetry breaking. Our analysis also reveals that the surface state survives far above the energy where angle-resolved photoemission spectroscopy finds the onset of continuum bulk bands. 相似文献
44.
Basak R Mukhopadhyay N Bandyopadhyay R 《The European physical journal. E, Soft matter》2011,34(9):103
Photon correlation spectroscopy and rheological measurements are performed to investigate the microscopic dynamics and mechanical
responses of aqueous solutions of triblock copolymers and aqueous mixtures of triblock copolymers and anionic surfactants.
Increasing the concentration of triblock copolymers results in a sharp increase in the magnitude of the complex moduli characterising
the samples. This is understood in terms of the changes in the aggregation and packing behaviours of the copolymers and the
constraints imposed upon their dynamics due to increased close packing. The addition of suitable quantities of an anionic
surfactant to a strongly elastic copolymer solution results in a decrease in the complex moduli of the samples by several
decades. It is argued that the shape anisotropy and size polydispersity of the micelles comprising mixtures cause dramatic
changes in the packing behaviour, resulting in sample unjamming and the observed decrease in complex moduli. Finally, a phase
diagram is constructed in the temperature-surfactant concentration plane to summarise the jamming-unjamming behaviour of aggregates
constituting triblock copolymer-anionic surfactant mixtures. 相似文献
45.
In this article, we have decorated multiwalled carbon nanotubes (MWCNTs) scaffold with ZnO quantum dots (QDs, size in the
range of 2.9–4.5 nm) and investigated their prospects for photovoltaic applications. ZnO QDs, in the present study, work
as photosensitizer instead of electron transporting media as used in recent conventional strategic solar cells. ZnO QDs/MWCNTs
composite shows an increased visible absorbance and quenching of the broad visible emission at around ~560 nm, while only
ZnO QDs exhibit a strong visible emission. An efficient electron–hole separation facilitates an increase in the short-circuit
current. These results show a possibility of developing a nontoxic, ZnO QDs sensitized MWCNTs composite-based photovoltaic
solar cell. 相似文献
46.
47.
Summary Cosmic-ray air shower structure functions for the distance dependence of electron density in cosmic-ray air showers in the
size range 104⋎108 have been computed for their intercomparison and comparison with Monte Carlo simulation results and measurements from recent
experiments. The analysis has yielded the present status of theoretical structure functionsvis à vis experimental results and Monte Carlo simulation distributions. The effect of core location error on the lateral distribution
of electrons is also discussed from the point of view of different theoretical and experimental results. The energy flow in
the soft component of air showers of size ∼4·105 has been evaluated within a ring of radius 10m about the axis of the showers. 相似文献
48.
Subhash C. Basak Gerald J. Niemi Gilman D. Veith 《Journal of mathematical chemistry》1991,7(1):243-272
Topological indices (TIs) have been used to study structure-activity relationships (SAR) with respect to the physical, chemical, and biological properties of congeneric sets of molecules. Since there are many TIs and many are correlated, it is important that we identify redundancies and extract useful information from TIs into a smaller number of parameters. Moreover, it is important to determine if TIs, or parameters derived from TIs, can be used for global SAR models of diverse sets of chemicals. We calculated seventy-one TIs for three groups of molecules of increasing complexity and diversity: (a) 74 alkanes, (b) 29 alkylbenzenes, and (c) 37 polycyclic aromatic hydrocarbons (PAHs). Principal components analysis (PCA) revealed that a few principal components (PCs) could extract most of the information encoded by the seventy-one TIs. The structural basis of the first few PCs could be derived from their pattern of correlation with individual TIs. For the three sets of molecules, viz. alkanes, alkylbenzenes and PAHs, PCs were able to predict the boiling points reasonably well. Also, for the combined set of 140 chemicals consisting of the alkanes, alkylbenzenes and PAHs, the derived PCs were not as effective in predicting properties as in the case of individual classes of compounds. 相似文献
49.
50.