PEROXIDASE INDUCED CHEMILUMINESCENCE IN THE OXIDATION OF PYROGALLOL AND PURPUROGALLIN. INFLUENCE OF AZIDE

Abstract— The chemiluminescence (CL) emitted during the peroxidase catalyzed oxidation of purpurogallin and pyrogallol depends on one and two molecules of enzyme, respectively. Using microperoxidase, CL with purpurogallin also depends on two molecules of enzyme (above 0.3 μ M enzyme). Sodium azide inhibits the CL emitted by all reactions depending on two molecules of enzyme but enhances the CL of reactions depending on one molecule of peroxidase (purpurogallin + 0.75 n M horseradish peroxidase). The formation of functional enzyme dimols during the oxidative process is discussed.     

Perturbations of molecular extravalence excitations by rare-gas fluids

In this paper we report the results of an experimental study of the vacuum ultraviolet absorption spectra of molecular impurity states of methyl iodide in Ar (density range ? = 0–1.4 g cm^?3) and in Kr (? = 0–2.3 g cm^?3), of carbon disulphide in Ar (? = 0–1.4 g cm^?3) and of formaldehyde in Ar (? = 0–1.25 g cm^?3). The experimental results provide new information regarding medium perturbations of intravalenc transitions, of the lowest extravalence transitions and of transitions to mixed valence—Rydberg configurations, which serve as a diagnostic tool to distinguish between different types of electronic excitations. All the lowest extravalence molecular excitations exhibit appreciable blue spectral shifts at moderate and at high fluid densities, intravalence transitions are practically insensitive to medium effects, while excitations to mixed valence—Rydberg configurations are characterized by a moderate blue spectral shift. New information has been obtained concerning the energetics of molecular ionization processes in a dense fluid. The high n = 2–5 Rydberg states of CH₃l exhibit a large red shift at moderate (? = 0–0.5 cm^?3) Ar densities. The ionization potential E_g and the effective Rydberg constant G for CH₃I in Ar was found to decrease from G = 13.6 eV and E_g = 9.55 eV at ? = 0 and E_g = 9.08 eV and constant G for CH₃l in Ar was found to decrease from G = 13.6 eV and E_g = 9.55eV at ? = 0 and E_g = 9.08 eV and G ≈ 7.15 eV at ? = 0.5 g cm^?3. Experimental evidence was obtained for the identification of n = 2 molecular Wannier impurity states of CH₃I and of CH₂O in liquid Ar. These spectroscopic data result in E_g ≈ 8.6 eV for CH₃I in liquid Ar and E_g ≈ 10.2 eV for CH₂O in liquid Ar.     

The heat equation with a stochastic solution-dependent boundary condition

In this paper a boundary value problem for the heat equation with solution-dependent boundary conditions is examined in the case when the dependence is of stochastic type.     

Quinonoid modified electrodes amplify the current from certain soluble one-electron redox reagents

Chemically modified carbon electrodes are prepared which hold polymeric layers of anthraquinone or dopamine units on the surface. In each case only those quinonoid units nearest the carbon are electroactive in neutral solution. Other units can be activated by one-electron redox shuttles dissolved in the solution phase which help propagate the redox process through the film. Cobalticinium dicarboxylic acid and methyl viologen are used to catalyze reductive reactions and ferrocene carboxylic acid catalyzes the oxidative propagation.     

Hardy algebras, <Emphasis Type="Italic">W</Emphasis>*-correspondences and interpolation theory

Given a von Neumann algebra M and a W*-correspondence E over M, we construct an algebra H(E) that we call the Hardy algebra of E. When M= =E, H(E) is the classical Hardy space H of bounded analytic functions on the unit disc. When M= and E= H(E) is the free semigroup algebra studied by Popescu, Davidson and Pitts and many others. We show that given any faithful normal representation of M on a Hilbert space H there is a natural correspondence E over the commutant (M), called the -dual of E, and that H(E) can be realized in terms of (B(H)-valued) functions on the open unit ball ((E)*) in the space of adjoints of elements in E. We prove analogues of the Nevanlinna-Pick theorem in this setting and discover other aspects of the value distribution theory for elements in H(E). We also analyze the boundary behavior of elements in H(E) and obtain generalizations of the Sz.-Nagy–Foia functional calculus and the functional calculus of Popescu for c.n.c. row contractions. The correspondence E has a dual that is naturally isomorphic to E and the commutants of certain, so-called induced representations of H(E) can be viewed as induced representations of H(E). For these induced representations a double commutant theorem is proved.Supported in part by grants from the National Science Foundation and from the U.S.-Israel Binational Science Foundation.Supported in part by the U.S.-Israel Binational Science Foundation and by the Fund for the Promotion of Research at the Technion.Revised version: 11 March 2004     

The Poisson Kernel for Hardy Algebras

This note contributes to a circle of ideas that we have been developing recently in which we view certain abstract operator algebras H^∞(E), which we call Hardy algebras, and which are noncommutative generalizations of classical H^∞, as spaces of functions defined on their spaces of representations. We define a generalization of the Poisson kernel, which “reproduces” the values, on , of the “functions” coming from H^∞(E). We present results that are natural generalizations of the Poisson integral formula. They also are easily seen to be generalizations of formulas that Popescu developed. We relate our Poisson kernel to the idea of a characteristic operator function and show how the Poisson kernel identifies the “model space” for the canonical model that can be attached to a point in the disc . We also connect our Poisson kernel to various “point evaluations” and to the idea of curvature. The first named author was supported in part by grants from the National Science Foundation and from the U.S.-Israel Binational Science Foundation. The second named author was supported in part by the U.S.-Israel Binational Science Foundation and by the B. and G. Greenberg Research Fund (Ottawa).     

Dynamic instability of a non-uniform beam modeled in a two-degree-of-freedom system

The behaviour of a non-uniform beam loaded by a parallel or tangential compressive force respectively is analyzed by exploiting a two-degree-of-freedom dynamic model. The same system has been analyzed previously by Lee and Reissner from a static point of view and by Neer and Baruch by a dynamic approach using a one-degree-of-freedom model. The previous analyses revealed only part of the phenomena by the present approach.Here, for the tangential force a classical flutter instability is obtained and for the parallel force only static instability is possible.     

A criterion for shape control robustness of space structures

In the shape control method of space structures a certain matrix plays a major role. It is proposed here that the reciprocal value of the characteristic number of this matrix be taken as criterion for the robustness of the method.