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991.
Whereas glucose oxidase and related proteins are encapsulated readily in silica sol–gels, α-hydroxy enzymes such as lactate
oxidase (LOx), are reported to be damaged by electrostatic interaction with these matrices. Based on a previous report, poly(ethyleneimine),
PEI, was evaluated as a protecting compound under conditions suited to analytical measurements. With LOx and PEI co-encapsulated
in a silica sol–gel, the enzyme retained 62% of its initial activity after 20 days. In the absence of PEI, activity was lost
during the processing. Batch analytical measurements with enzyme-doped sol–gel yielded a linear response over the range 0.5–2.0 mM
lactate and a detection limit of 0.03 mM lactate. Both simple incorporation of LOx in a silica sol–gel and an alternative
protection method, blocking the ion-exchange sites on silica with La(III), failed. These negative results supported the hypothesis
that the efficacy of PEI was related to its formation of a protective sheath around the enzyme.
Author for correspondence. E-mail: coxja@muohio.edu
Received July 29, 2002; accepted December 15, 2002
Published online May 19, 2003 相似文献
992.
993.
T. Mihara K. Miyamoto M. Kida T. Sasaki N. Aoki Y. Ochiai 《Superlattices and Microstructures》2003,34(3-6):383
A multiwall carbon nanotube crossroads has been fabricated by a manipulation technique using a glass microcapillary, and the low temperature transport properties investigated. The two-terminal conductance of an individual tube shows Tomonaga–Luttinger liquid behavior G∝Tα at high temperature and dI/dV ∝V α at low temperature. However, no evidence of such a power-law behavior is obtained in the four-terminal conductance at the junction, where the conductance shows an almost metallic behavior ‘corrected’ by weak localization. Weak localization would essentially appear in electron states at the junctions of MWNTs. 相似文献
994.
E. García-Matres N. Stüßer M. Hofmann M. Reehuis 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,32(1):35-42
The magnetic structures of Mn1-xFexWO4 with x
= 0.0, 0.16, 0.21, 0.225, 0.232, 0.24, 0.27, 0.29, and 1.0 were refined from neutron powder diffraction data. The magnetic phase
diagram could be completed in the coexistence range of different magnetic structures up to x
= 0.29. For the magnetic state at 1.5 K a commensurate antiferromagnetic structure with a propagation vector
= (±1/4, 1/2, 1/2) was found for x
⩽ 0.22 while the magnetic spins order with
= (1/2, 0, 0) for x
≥ 0.22. In the latter phase, additionally, weak magnetic reflections indexed to an incommensurate ordering with
= (- 0.214, 1/2, 0.457) occur in the diffraction pattern up to x
= 0.29 indicating the occurence of a reentrant phase. For 0.12 ⩽
x
⩽ 0.29 the low temperature phases are separated from a magnetic high temperature phase showing only magnetic reflections indexed
to a spin arrangement with
= (1/2, 0, 0). The magnetic phase diagram is discussed qualitatively considering random superexchange between the statistically distributed
Mn2+- and Fe2+-ions in the coexistence range 0.12 ⩽
x
⩽ 0.29 of different magnetic structures related to those of pure MnWO4 and FeWO4.
Received 9 October 2002 Published online 14 March 2003 相似文献
995.
In this paper a predictive control strategy is applied to a periodic-review dynamic inventory system with deteriorating items.
Given the current inventory level, we determine the optimal production rates to be implemented at the beginning of each of
the following periods over the control horizon. The effectiveness of this approach is the use of future information of the
inventory target level and the desired production rate, which are available, along the fixed horizon. The deterioration coefficient
may be known or unknown and both cases are considered. In the case where it is unknown, the self-tuning predictive control
is applied. The proposed control algorithms are illustrated by simulations. 相似文献
996.
This note investigates two long-standing conjectures on the Krull dimension of integer-valued polynomial rings and of polynomial rings in the context of (locally) essential domains.
997.
Bahraminasab A. Tabei S. M. A. Masoudi A. A. Shahbazi F. Reza Rahimi Tabar M. 《Journal of statistical physics》2004,116(5-6):1521-1544
The joint probability distribution function (PDF) of the height and its gradients is derived for a zero tension d + 1-dimensional Kardar-Parisi-Zhang (KPZ) equation. It is proved that the height's PDF of zero tension KPZ equation shows lack of positivity after a finite time t c . The properties of zero tension KPZ equation and its differences with the case that it possess an infinitesimal surface tension is discussed. Also potential relation between the time scale t c and the singularity time scale t c.v→0 of the KPZ equation with an infinitesimal surface tension is investigated. 相似文献
998.
In bricklayers' model, which is a generalization of the misanthrope processes, we show that a nontrivial class of product distributions is closed under the time-evolution of the process. This class also includes measures fitting to shock data of the limiting PDE. In particular, we show that shocks of this type with discontinuity of size one perform ordinary nearest neighbor random walks only interacting, in an attractive way, via their jump rates. Our results are related to those of Belitsky and Schütz(4) on the simple exclusion process, although we do not use quantum formalism as they do. The structures we find are described from a fixed position. Similar ones were found in Balázs,(2) valak as seen from the random position of the second class particle. 相似文献
999.
Christian J. Bordé Claus Lämmerzahl Ernst M. Rasel 《General Relativity and Gravitation》2004,36(10):2193-2196
1000.
The diffraction of a plane wave incident on a thick hologram at the first and second Bragg angles in the process of nonlinear recording is analyzed using the coupled-wave equations. It is shown that, in this case, the two-wave approximation with the use of effective modulation amplitudes of the refractive index, n 1ef and n 2ef, can be applied. Analytical dependences of n 1ef and n 2ef on the modulation amplitudes of the refractive index n 1 and n 2 at the fundamental and doubled spatial frequencies are obtained and the criteria of their applicability are determined. The dependences found are used to calculate the parameters of gratings recorded in a photopolymeric material. 相似文献