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561.
The stack of base pairs within double helical DNA has been shown to mediate charge transport reactions. Charge transport through DNA can result in chemistry at a distance, yielding oxidative DNA damage at a site remote from the bound oxidant. Since DNA charge transport chemistry depends on coupling within the stacked base pair array, this chemistry is remarkably sensitive to sequence-dependent DNA structure and dynamics. Here, we discuss different features of DNA charge transport chemistry, including applications as well as possible biological consequences and opportunities. 相似文献
562.
Albermann C Soriano A Jiang J Vollmer H Biggins JB Barton WA Lesniak J Nikolov DB Thorson JS 《Organic letters》2003,5(6):933-936
[reaction: see text] In an effort to expand the scope of natural product in vitro glycorandomization (IVG), the substrate specificity of NovM was investigated. A test of four aglycon analogues and over 40 nucleotide sugars revealed NovM has a surprisingly stringent substrate specificity and provided only three new "unnatural" natural products. On the basis of the determined substrate specificity, an alternative to the sugar nucleotide biosynthetic dogma and a cautionary note for the general applicability of IVG are introduced. 相似文献
563.
M.A. Caprio N.V. Zamfir E.A. McCutchan R.F. Casten Z. Berant H. Amro C.J. Barton C.W. Beausang D.S. Brenner J.R. Cooper R.L. Gill G. Gürdal A.A. Hecht C. Hutter R. Krücken D.A. Meyer J.R. Novak N. Pietralla P.H. Regan J.J. Ressler 《The European Physical Journal A - Hadrons and Nuclei》2003,16(2):177-180
Lifetime measurements for the 2+
1 levels of 162Er and 162Yb were obtained in β+/ɛ decay at the Yale Moving Tape Collector by fast electronic scintillation timing of β+γ coincidences.
Received: 2 September 2002 / Accepted: 1 October 2002 / Published online: 4 February 2003
RID="a"
ID="a"e-mail: mark.caprio@yale.edu
Communicated by J. ?yst? 相似文献
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567.
The probability of reaction of cyclobutane molecules in a fixed time interval after experiencing a known variable number of collisions with a hot surface at temperatures between 749 K and 1126 K has been determined using the Variable Encounter Method. Calculations utilizing exponential or gaussian models for energy transfer enable the average amounts of energy transferred for deactivating collisions, <ΔE′?, to be estimated. The exponential model fits the experimental data the best and, using this model, <ΔE′? is 2430 cm?1 at 749 K and decreases to 1470 cm?1 at 1126 K. Incubation times are derived from the mean first passage times. 相似文献
568.
Molecular beam deflection studies of the carbon dioxide dimer indicate a non-polar molecule. This result is shown to be incompatible with the normally accepted T-shaped geometry. Other possible structures are compared and contrasted. 相似文献
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The magnetic susceptibility of dilute magnetic alloys of Mn in Rh and Fe in a Nb-Mo solid solution deviates from the Curie-Weiss law. The following temperature dependence is observed: Δχ = C/(T + TK) + log (TK/T), with ≡ 0 for T > TK0. 相似文献