全文获取类型
收费全文 | 895篇 |
免费 | 23篇 |
国内免费 | 1篇 |
专业分类
化学 | 564篇 |
晶体学 | 6篇 |
力学 | 41篇 |
数学 | 139篇 |
物理学 | 169篇 |
出版年
2023年 | 4篇 |
2022年 | 22篇 |
2021年 | 29篇 |
2020年 | 10篇 |
2019年 | 13篇 |
2018年 | 16篇 |
2017年 | 11篇 |
2016年 | 19篇 |
2015年 | 14篇 |
2014年 | 26篇 |
2013年 | 71篇 |
2012年 | 65篇 |
2011年 | 66篇 |
2010年 | 31篇 |
2009年 | 39篇 |
2008年 | 54篇 |
2007年 | 62篇 |
2006年 | 37篇 |
2005年 | 40篇 |
2004年 | 31篇 |
2003年 | 20篇 |
2002年 | 15篇 |
2001年 | 7篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1996年 | 10篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 14篇 |
1984年 | 7篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 16篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1976年 | 15篇 |
1975年 | 5篇 |
1974年 | 4篇 |
1973年 | 3篇 |
1970年 | 4篇 |
1906年 | 3篇 |
1905年 | 3篇 |
排序方式: 共有919条查询结果,搜索用时 296 毫秒
81.
82.
Luciano Lepori Paolo Gianni Andrea Spanedda Enrico Matteoli 《The Journal of chemical thermodynamics》2011,43(10):1453-1462
Excess molar volumes VE at 298.15 K were determined by means of a vibrating tube densimeter for binary mixtures of {heptane + open chain secondary (diethyl to dibutyl) and tertiary (triethyl to tripentyl) amines} as well as for cyclic imines (C2, C3, C4, C6, and C7) and primary cycloalkylamines (C5, C6, C7, and C12). The VE values were found positive for mixtures involving small size amines, with VE decreasing as the size increases. Negative VE’s were found for tributyl- and tripentylamine, heptamethylenimine, and cyclododecylamine. Mixtures of heptane with cycloheptylamine showed an s-shaped curve.Partial molar volumes of amines at infinite dilution in heptane were obtained from VE and compared with of hydrocarbons and other classes of organic compounds taken from literature. An additivity scheme, based on the intrinsic volume approach, was applied to estimate group (CH3, CH2, CH, C, NH2, NH, N, OH, O, CO, and COO) contributions to . These contributions, the effect of cyclization on , and the limiting slope of the apparent excess molar volumes were discussed in terms of solute–solvent and solute–solute interactions. 相似文献
83.
Nagy EM Nardon C Giovagnini L Marchiò L Trevisan A Fregona D 《Dalton transactions (Cambridge, England : 2003)》2011,40(44):11885-11895
During the last decade, our research group has prepared a number of metal dithiocarbamato derivatives of Pt, Pd and Au that were expected to resemble the main features of cisplatin together with higher activity, improved selectivity and bioavailability, and lower side-effects. Furthermore, we have already published the synthesis, characterization and in vitro cytotoxicity studies of novel ruthenium(III) dithiocarbamato complexes such as [RuL(3)] monomers (11) and α-[Ru(2)L(5)]Cl dimers (12) with five different dithiocarbamate ligands. As both the monomer and the dinuclear complexes have shown significant antitumor activity in different human tumor cell lines, we decided to widen the characterization studies and to analyse thoroughly their behavior in physiological-like medium by UV-visible and CD spectroscopy. In the present paper we report on the crystal structure of [Ru(DMDT)(3)], [Ru(PDT)(3)] and [Ru(ESDT)(3)] complexes and we determine the spin state of the paramagnetic Ru(III) by means of Evans' method. Then, we discuss in detail the UV-visible spectral data of the complexes in different medium. All the studied complexes are stable in dimethyl sulfoxide, and show low solubility in phosphate buffered saline solution, particularly the monomer species, even at low concentration, while increased solubility for both types of complexes have been found in the presence of bovine serum albumin (BSA). Moreover, no changes on the coordination sphere of the metal, as well as no direct interaction between the BSA protein and the complex have been identified by UV-visible spectroscopy. However, some conformational changes on the BSA structure, induced by the ruthenium(III) complexes have been confirmed by CD spectroscopy, indicating a probable secondary electrostatic interaction between the metal complex and the peptide. In addition, no significant interaction has been demonstrated with the components of Dulbecco's Modified Eagle's Medium, used for the in vitro assays. 相似文献
84.
Boga C Forlani L Calienni R Hindley T Hochkoeppler A Tozzi S Zanna N 《Natural product research》2011,25(4):417-421
A decoction of Capparis spinosa L. roots, widely used in the traditional folk medicine of southern Italy, was prepared and submitted to antibacterial activity tests, which showed an interesting bacteriostatic activity on the growth of Deinococcus radiophilus. Heterocyclic compounds were also recovered from the chloroformic extract of the roots. 相似文献
85.
The aim of this study was to develop a fast CE separation method by using multiple short-end injections in a capillary coated with quaternary ammonium chitosan (HACC), in order to determine the iodide content of pharmaceutical formulations. The BGE was composed of 20 mM tris(hydroxymethyl)aminomethane and 11 mM hydrochloric acid, at pH 8. The internal standard used was thiocyanate. Separations were performed in a fused silica capillary (32 cm total length, 8.5 cm effective length and 50 μm i.d.) coated with HACC and direct UV detection at 220 nm. EOF was modified by flushing the capillary with polymeric solution, resulting in a semi-permanent coating of controlled and stable EOF. The EOF was anodic at pH 8. Different strategies, using single and multiple injection short-end configurations, were studied to develop a CE method that resulted in a maximum number of iodide samples analyzed per hour: one plug and flush (Sflush) 35 samples/h, one plug without flush (SWflush) 76 samples/h, four plugs and flush (Mflush) 61 samples/h, and four plugs without flush (MWflush) 80 samples/h. Using the multiple injection configuration, it was possible to inject up to four plugs using spacer electrolytes with good separation efficiency and selectivity. The voltage application time needed to separate the eight peaks (iodide and thiocyanate) with MWflush was only 12s. The method was validated and samples were analyzed using MWflush. Good linearity (R(2)>0.999); a limit of detection 0.4 mg L(-1); intermediate precision better than 3.8% (peak area) and recovery in the range of 99-102% were obtained. 相似文献
86.
Luciano N. Batista Rosane A. S. San Gil Luciana B. R. Lopes Vera L. P. Soares 《Journal of Thermal Analysis and Calorimetry》2011,106(3):697-702
This work describes thermal analysis evaluation of a glycerol derived compound (fatty acid esters of (2,2-dimethyl-1,3-dioxolan-4-yl)
methanol) developed to work as a biofuel. Mixtures of these ketal–glyceryl esters with fatty acid methyl esters typical of
soybean biodiesel were prepared and evaluated in relation to biodiesel critical thermal properties such as temperature of
crystallization, thermal stability and volatilization measured by differential scanning calorimetry and thermogravimetric
analysis. The volatility of the products containing fatty acid methyl esters and (2,2-dimethyl-1,3-dioxolan-4-yl) methyl esters
could be predicted by thermogravimetric analyses conducted in nitrogen that avoided time consuming distillation and greatly
reduced material expenditure. 相似文献
87.
Paul-Antoine Santoni Frédéric Morandini Toussaint Barboni 《Journal of Thermal Analysis and Calorimetry》2011,104(3):1005-1015
Fireline intensity is one of the most relevant quantities used in forest fire science. It helps to evaluate the effects of
fuel treatment on fire behavior, to establish limits for prescribed burning. It is also used as a quantitative basis to support
fire suppression activities. However, its measurement is particularly tricky for different reasons: difficulty in measuring
the weight of the fuel consumed in the active fire front, difficulty to evaluate the rate of spread of the fire front, and
uncertainty on combustion efficiency. In this study, an innovative and original approach to directly measure the fireline
intensity at laboratory scale is proposed. Based on the oxygen consumption calorimetry principle, this methodology is applied
here in case of spreading fires, for the first time. It allows for directly measuring the heat released by the fire front.
The results are then used to test the famous Byram’s formulation that is generally applied to determine the fireline intensity.
Combustion efficiency and effective heat of combustion results are provided. The uncertainty and the use of a full scale calorimeter
instead of a bench scale calorimeter for this study are discussed. 相似文献
88.
Novais Luciano Maqueira Juan Manuel Ortiz Ángel Bruque Sebastián 《Central European Journal of Operations Research》2021,29(4):1185-1218
Central European Journal of Operations Research - Hypothesis contrast using statistical models with Structural Equations is a technique widely used in Supply Chain Management research. However,... 相似文献
89.
90.
Maurizio Brunetti Adriana Ciampella Luciano A. Lomonaco 《manuscripta mathematica》2005,118(3):271-282
The mod 2 universal Steenrod algebra Q is a homogeneous quadratic algebra closely related to the ordinary mod 2 Steenrod algebra and the Lambda algebra introduced
in [1]. In this paper we show that Q is Koszul. It follows by [7] that its cohomology, being purely diagonal, is isomorphic to a completion of Q itself with respect to a suitable chain of two-sided ideals. 相似文献