全文获取类型
收费全文 | 278篇 |
免费 | 18篇 |
国内免费 | 4篇 |
专业分类
化学 | 170篇 |
力学 | 2篇 |
数学 | 48篇 |
物理学 | 80篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 13篇 |
2020年 | 10篇 |
2019年 | 11篇 |
2018年 | 8篇 |
2017年 | 9篇 |
2016年 | 13篇 |
2015年 | 11篇 |
2014年 | 8篇 |
2013年 | 13篇 |
2012年 | 19篇 |
2011年 | 22篇 |
2010年 | 12篇 |
2009年 | 7篇 |
2008年 | 24篇 |
2007年 | 16篇 |
2006年 | 18篇 |
2005年 | 12篇 |
2004年 | 16篇 |
2003年 | 14篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 5篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1958年 | 2篇 |
排序方式: 共有300条查询结果,搜索用时 15 毫秒
41.
42.
M. Sc. Benjamin Scheibe Clemens Pietzonka M. Sc. Otto Mustonen Prof. Dr. Maarit Karppinen Prof. Dr. Antti J. Karttunen Prof. Dr. Mihail Atanasov Prof. Dr. Frank Neese Dr. Matthias Conrad Prof. Dr. Florian Kraus 《Angewandte Chemie (International ed. in English)》2018,57(11):2914-2918
The D2h‐symmetric dinuclear complex anion [U2F12]2? of pastel green Sr[U2F12] shows a hitherto unknown structural feature: The coordination polyhedra around the U atoms are edge‐linked monocapped trigonal prisms, the UV atoms are therefore seven‐coordinated. This leads to a U–U distance of 3.8913(6) Å. A weak UV–UV interaction is observed for the dinuclear [U2F12]2? complex and described by the antiferromagnetic exchange Jexp of circa ?29.9 cm?1. The crystalline compound can be easily prepared from SrF2 and β‐UF5 in anhydrous hydrogen fluoride (aHF) at room temperature. It was studied by means of single crystal X‐ray diffraction, IR, Raman and UV/VIS spectroscopy, magnetic measurements, and by molecular as well as by solid‐state quantum chemical calculations. 相似文献
43.
Yu‐Hao Li Shaoping Zheng Dr. Yves‐Marie Legrand Dr. Arnaud Gilles Dr. Arie Van der Lee Dr. Mihail Barboiu 《Angewandte Chemie (International ed. in English)》2018,57(33):10520-10524
Self‐assembled alkyl‐ureido‐benzo‐15‐crown‐5‐ethers are selective ionophores for K+ cations, which are preferred to Na+ cations. The transport mechanism is determined by the optimal coordination rather than classical dimensional compatibility between the crown ether hole and the cation diameter. Herein, we demonstrate that systematic changes of the structure lead to unexpected modifications in the cation‐transport activity and suffice to produce adaptive selection. We show that the main contribution to performance arises from optimal constraints on the conformational freedom, which are determined by the binding macrocycles, the nature of the hydrogen‐bonding groups, and the hydrophobic tails. Simple changes to the flexible 15‐crown‐5‐ether lead to selective carriers for Na+. Hydrophobic stabilization of the channels through mutual interactions between lipids and variable hydrophobic tails appears to be an important cause of increased activity. Oppositely, restricted translocation is achieved when constrained hydrogen‐bonded macrocyclic relays are less dynamic in a pore superstructure. 相似文献
44.
A set A of real numbers is called universal (in measure) ifevery measurable set of positive measure necessarily containsan affine copy of A. All finite sets are universal, but no infiniteuniversal sets are known. Here we prove some results relatedto a conjecture of Erds that there is no infinite universalset. For every infinite set A, there is a set E of positivemeasure such that (x + tA)E fails for almost all (Lebesgue)pairs (x, t). Also, the exceptional set of pairs (x, t) (forwhich (x + tA)E) can be taken to project to a null set on thet-axis. Finally, if the set A contains large subsets whose minimumgap is large (in a scale-invariant way), then there is ER ofpositive measure which contains no affine copy of A. 1991 MathematicsSubject Classification 28A12. 相似文献
45.
Radu Miculescu Alexandru Mihail 《Proceedings of the American Mathematical Society》2008,136(2):587-592
It is known that Lipscomb's space can be imbedded in Hilbert's space . Let be the imbedded version of endowed with the -induced topology. We show how to construct as the attractor of an iterated function system containing an infinite number of affine transformations of . In this way we answer an open question of J.C. Perry.
46.
Iuliana-Marilena Andrei Dmytro Strilets Dr. Shixin Fa Marc Baaden Prof. Tomoki Ogoshi Dr. Mihail Barboiu 《Angewandte Chemie (International ed. in English)》2023,62(42):e202310812
Artificial water channels (AWCs) that selectively transport water and reject ions through bilayer membranes have potential to act as synthetic Aquaporins (AQPs). AWCs can have a similar osmotic permeability, better stability, with simpler manufacture on a larger-scale and have higher functional density and surface permeability when inserted into the membrane. Here, we report the screening of combinatorial libraries of symmetrical and unsymmetrical rim-functionalized PAs A – D that are able to transport ca. 107–108 water molecules/s/channel, which is within 1 order of magnitude of AQPs’ and show total ion and proton rejection. Among the four channels, C and D are 3–4 times more water permeable than A and B when inserted in bilayer membranes. The binary combinations of A – D with different molar ratios could be expressed as an independent (linear ABA ), a recessive (inhibition AB , AC , DB , ACA ), or a dominant (amplification, DBD ) behavior of the water net permeation events. 相似文献
47.
Carlos Jesus Muvdi Nova Delphine Paolucci-JeanjeanMarie-Pierre Belleville Mihail BarboiuMatthieu Rivallin Gilbert Rios 《Journal of membrane science》2008
A new kind of metal affinity membrane based on a ceramic support was prepared. It was elaborated in four steps: (i) deposition of a chitosan layer in order to functionalize the ceramic support, (ii) cross-linking with epichlorohydrin to stabilise the polymer layer and to enable the grafting, (iii) iminodiacetic acid grafting, (iv) Cu2+ adsorption. Due to the ceramic support, this membrane is highly resistant and the chitosan layer brings its biocompatibility properties. Each step of the membrane elaboration was studied and the membrane structure was characterized. Both thin coating of the polymer on the alumina grains of the support and the chemical modification of the membrane were proved. Then, bovine serum albumin (BSA) was used as a model protein to test protein retention of the affinity membrane. The protein/membrane interactions were investigated showing that some non-specific ones are involved. Finally, the effect of buffer concentration was checked and it appears that, in the studied range, an increase of the buffer concentration entailed a limitation of the non-specific interactions inducing a better BSA recovering and a higher selectivity. 相似文献
48.
José Gaspar Mihail Fontul Elsa Henriques António Ribeiro Arlindo Silva Nuno Valverde 《Applied Acoustics》2016
The car interior is becoming quieter and other sounds are now exposed to user perception, such as the sound produced by interface buttons when actuated. So, the functional role of the button sound on interface operation and its aesthetic and emotional role on the user experience are now more important than before. However, little research and design effort has been paid to understand how to design buttons that produce a pleasant sound. Moreover, the button’s sound requirements received by interface manufacturers are ill-defined, insufficient or even inexistent, and consequently their conversion into specifications for manufacturing is problematic and leads to long and costly development processes. The purpose of this paper is to contribute to identify relevant acoustic parameters that explain the users sound preferences. Data on preference subjective judgments were collected and buttons acoustic signals were measured allowing the development of preference models based on partial least squares regression and neural networks methods. The former was successful in selecting the relevant parameters to describe the preference ratings of the buttons sound. The later, dealing with the non-linear nature of acoustic perception, was able to predict preferences based on the relevant parameters. 相似文献
49.
50.
Functional G-quartet macroscopic membrane films 总被引:1,自引:0,他引:1
Arnal-Hérault C Pasc A Michau M Cot D Petit E Barboiu M 《Angewandte Chemie (International ed. in English)》2007,46(44):8409-8413