激光气体靶产生的类氖氪离子4d-2p共振跃迁及其类Na3l4l′双电子伴线的研究

用相对论多组态 (HXR)方法 ,详细计算了类Ne氪离子 4d 2 p类Na 3l4l′双电子伴线波长和强度因子 ,并模拟了实验光谱 ,解释了最新利用激光气体靶产生的 0 .5 2 5～ 0 .5 5 5nm范围的氪X Ray光谱 ,计算结果与实验符合得相当好。此外 ,还讨论了组态相互作用对双电子伴线结构的影响。     

Invariant Measures for a Random Evolution Equation with Small Perturbations

In this paper we consider a random evolution equation with small perturbations, and show how to construct coupled solutions to the equations. As applications, we prove the Feller continuity of the solutions and the existence and uniqueness of invariant measures. Furthermore, we establish a large deviations principle for the family of invariant measures as the perturbations tend to zero. Received March 20,1998, Accepted June 1, 2000     

边界条件对生物组织漫射光时域模拟计算的影响

采用蒙特卡洛方法与漫射近似相结合的杂合算法,在不同的边界条件下(零边界条件、外延边界条件、部分流边界条件),对板状生物组织模型的漫射光的时域分布进行了计算,计算结果表明:采用外延边界条件,在保证计算精度的基础上,和单纯的蒙特卡洛方法相比,较大地提高了运算速度.     

蓖麻毒蛋白的提取及分析

本文报道了蓖麻毒蛋白的提取和分析,采用琼脂糖（Sepharose 4B)分离和纯化,研究了高效液相色谱法同时测定蓖麻毒蛋白和蓖麻碱,结果 令人满意。     

Error estimates for the finite element approximation of linear elastic equations in an unbounded domain

In this paper we present error estimates for the finite element approximation of linear elastic equations in an unbounded domain. The finite element approximation is formulated on a bounded computational domain using a nonlocal approximate artificial boundary condition or a local one. In fact there are a family of nonlocal approximate boundary conditions with increasing accuracy (and computational cost) and a family of local ones for a given artificial boundary. Our error estimates show how the errors of the finite element approximations depend on the mesh size, the terms used in the approximate artificial boundary condition, and the location of the artificial boundary. A numerical example for Navier equations outside a circle in the plane is presented. Numerical results demonstrate the performance of our error estimates.

     

稀土有机螯合物发光研究进展

总结了稀土有机螯合物结构与发光性能的关系：配体最低三重态能级与稀土离子激发态能级的匹配是中心稀土离子能否发光的主要因素;螯合物结构的平面性和刚性是中心离子发光效率高低的重要因素;适宜的第二配体的加入一般导致螯合物分子刚性和稳定性增高,因而有利于能量的传递,致使中心离子发光效率增高,但也不能忽视第二配体加入所引起光能的吸收和能量传递过程的竞争;配体的耐热,耐辐射性是配合物能否作为材料的必要因素,自行设计,合成了5类25种新的有机配体及其相应的二元,三元稀土螯合物,研究了这些螯合物的配位性质,发光性能,发光与结构关系及发光机制。提出并发展了稀土离子发光和电子振动光谱作为配合物和生物分子结构探针的两种新的方法。将稀土－β－二酮的发光螯合物与树脂制成荧光塑料;利用铕和铽螯合物的发光和免疫反应,检测了体液中生物活性物质的含量,证实以稀土离子替代放射性同位素作为标记物,有希望替代放射免疫分析方法,成为常规的临床检验方法,利用Tb^3 荧光检测了植物中生长激素的含量。     

C2H2在Ru(1010)表面上的分子轨道对称性

利用角分辨紫外光电子能谱对低温下（160 K）乙炔（C2H2）气体在Ru()表面的吸附 进行了研究.实验结果表明：乙炔的C-C轴并不平行于衬底表面, C-C轴在<0001>晶向和表 面法线组成的平面内有一定的倾斜.与气相乙炔分子不同,在Ru()表面吸附的乙炔分子的C-H 轴不是沿C-C轴向.     

Voltammetric Studies of the Interaction of Tris (1,10-phenanthroline) Cobalt (III) with Bovine Serum Albumin

Recently, the studies on the interaction of DNA with small molecules have been attracting much interest1-6. These researches not only gave the important information about thermodynamics and kinetics, but also can prompt the combination between the electrode substances and biomacromolecule with super catalysis and sensor character. It is of great significance in understanding energy conversion and metabolism in live body, biomolecular structure, various physical and chemical characters for e…     

A phase separation fluoroimmunoassay of estradiol

A competitive indirect fluoroimmunoassay of free estradiol (E₂) was established based on the thermal sensitivity of hydrogel–‐poly‐N‐isopropylacrylamide. Free estradiol was covalently bound to bovine serum albumin (BSA) to form complete antigen (E₂‐BSA), which was in turn labeled by fluorescein isothiocyanate (FTTC) as the fluorescence probe. The anti‐ E₂ monoclonal antibody (McAb) was prepared by an in vivo method, and coupled with N‐isopropylacrylamide (NIPA) to make an immune copolymer, poly‐N‐isopropylacylamidemonoclonal antibody (pNIPA‐McAb), for the determination of free E₂. The immunoassay method was based on the competitive binding of free E₂ and fluoresceinated antigen (E₂‐BSA‐FTTC) with limited amount of pNIPA‐McAb. When the immunological reaction was over, precipitation and centrifugal procedures were carried out to separate pNIPA‐McAb‐E₂‐BSA‐FTTC from other constituents in solution. The precipitate pNIPA‐McAb‐E₂‐BSA‐FTTC was dissolved in solution and then the fluorescence intensity was measured. The calibration curve covered a range of 78–500 ng/mL for free E₂. The recoveries were 91.2–107.2%.     

Continuous Production of Carbon Nanotubes by Using Moving Bed Reactor

Since the discovery in 19911, carbon nanotubes have been the subject of intensive research due to their extraordinary mechanical and electronic properties2-7. However, lack of sufficient amount of materials limited the study of the fundamental properties and development of more practical applications. It is highly desirable to have large quantities of pure nanotubes. To date, few methods have been developed for the production of high-quality tubes which can adapted to industrial production …