Ni80P20合金的非晶化度与催化活性的关联

采用淬冷法,通过改变冷却铜辊的转速,得到了一系列具有不同非晶化度的Ｎｉ８０Ｐ２０合金材料。以乙炔加氢为探针反应的催化研究结果表明,合金的催化活性随非晶化程度的增加而增加,同时,非晶态合金具有比相应的晶态金合明显优良的催化稳定性,ＸＲＤ和ＡＥＳ深度分析显示：在氧化－还原活化处理过程中,相对晶态合金而言,非晶态合金显示明显的“惰性”,活化后的表面上含有较多的对加氢反应有促进作用的氧化镍相互作用的结构。     

ASYMPTOTIC BEHAVIOR OF SOLUTIONS OF SOME NONLINEAR DIFFERENCE EQUATIONS

In this paper, we investigate the asymptotic behavior of the extremal solutions of a difference equation and their character and prove the existence of the non-extremal solutions.     

固定效应部分线性可加面板数据模型的惩罚二次推断估计

具有较强解释力和灵活性的部分线性可加面板数据模型在各学科领域应用广泛.针对个体内存在相关结构的固定效应部分线性可加面板数据模型,本文在结合幂样条函数和最小二乘虚拟变量(LSDV)法的基础上,利用惩罚二次推断函数(PQIF)法对模型进行估计,在一定的正则条件下,证明了参数估计的渐近正态性和非参数估计的收敛性,Monte Carlo数值模拟显示所述估计方法具有良好的有限样本表现,同时,我们还将估计技术应用于实际数据分析中.     

基于荧光共轭聚合物的金属离子传感研究

设计合成了一系列结构相似的共轭主链含5%苯并噻二唑结构单元及侧链带胺类金属离子螯合基团的阴离子型水溶性共轭聚合物PFA, PFBTA和PFBTNA, 并对它们在不同极性溶剂中的光物理性质进行了研究. 利用分子主链含适量苯并噻二唑共聚单元的聚芴衍生物聚集态不同荧光光谱及颜色发生显著变化这一特性, 研究了这一系列水溶性聚芴衍生物在水/甲醇(9/1)溶液中对金属离子的荧光响应过程. 结果表明, 金属离子不仅能通过能量及电荷转移猝灭聚合物荧光, 还可以通过静电相互作用力使聚合物聚集态发生改变, 进而影响聚合物的光学性质. 同时分子链上引入金属离子螯合基团能够显著提高体系的检测灵敏度, 聚合物PFBTA和PFBTNA可以特异性识别Cu²⁺离子, 并且可做为其它金属离子的广谱型比色法检测材料.     

杉木针叶磷脂酰甘油脂肪酸组成分析

用改进的DEAE阴离子交换柱色谱法和硅胶薄层色谱法分离制备杉木针叶磷脂酸甘油，用气相色谱法测定了它的脂肪酸组成。分析结果表明，抗寒性强的杉木品种的针叶磷脂酰甘油脂肪酸的（18:1＋18:2＋18:3）／[16:0＋16:1（3t）]比值比不抗寒品种的高。     

面向对象建模语言AML的设计与实现

ＡＭＬ语言吸取了Ａｄａ９５ 基本原理和思想,引进它的基本数据类型、语句等设施,对其作更高层次的抽象和扩充．用３ 种有相同名字不同类型的程序包从不同的侧面描述给定模块的模型,提高了系统的完整性和一致性;同时运用二级并发模型和限制设施,详述了系统的并发性和不确定性的描述问题．     

Optimal deterministic algorithms for some variants of Online Quota Traveling Salesman Problem

This paper is concerned with the Online Quota Traveling Salesman Problem. Depending on the symmetry of the metric and the requirement for the salesman to return to the origin, four variants are analyzed. We present optimal deterministic algorithms for each variant defined on a general space, a real line, or a half-line. As a byproduct, an improved lower bound for a variant of Online TSP on a half-line is also obtained.     

Synchrotron radiation photoemission spectrum study on K3C60 film

K₃C₆₀, single crystal film was prepared on the cleaved (111) surface of C₆₀, single crystal. Synchrotron radiation angle-resolved photoemission spectra were measured at normal emission with sample temperature at × 150K. Up to four subpeaks of LUMO-derived band were observed. These sub-peaks exhibit distinct energy dispersions which resemble in general the theoretical ones calculated for K₃C₆₀ at low temperature with the so-called one-dimensional disordered structure. But there is large deviation of experimental sub-band intervals from the theoretical values. This result is meaningful for the studies of the physical properties of alkali-doped C₆₀ solids, e.g. the mechanism for superconductivity.     

A note on the entropy of mean curvature flow

The entropy of a hypersurface is given by the supremum over all F-functionals with varying centers and scales, and is invariant under rigid motions and dilations. As a consequence of Huisken's monotonicity formula, entropy is non-increasing under mean curvature flow. We show here that a compact mean convex hypersurface with some low entropy is diffeomorphic to a round sphere. We also prove that a smooth selfshrinker with low entropy is a hyperplane.