全文获取类型
收费全文 | 434篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 266篇 |
晶体学 | 1篇 |
力学 | 9篇 |
数学 | 76篇 |
物理学 | 92篇 |
出版年
2019年 | 4篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 4篇 |
2013年 | 19篇 |
2012年 | 14篇 |
2011年 | 24篇 |
2010年 | 19篇 |
2009年 | 19篇 |
2008年 | 7篇 |
2007年 | 24篇 |
2006年 | 24篇 |
2005年 | 27篇 |
2004年 | 16篇 |
2003年 | 8篇 |
2002年 | 6篇 |
2001年 | 6篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1996年 | 6篇 |
1995年 | 14篇 |
1994年 | 10篇 |
1993年 | 14篇 |
1992年 | 6篇 |
1991年 | 8篇 |
1989年 | 3篇 |
1986年 | 2篇 |
1985年 | 7篇 |
1984年 | 11篇 |
1983年 | 3篇 |
1982年 | 15篇 |
1981年 | 10篇 |
1980年 | 6篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1977年 | 11篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1973年 | 7篇 |
1971年 | 4篇 |
1970年 | 2篇 |
1966年 | 2篇 |
1965年 | 3篇 |
1964年 | 2篇 |
1963年 | 3篇 |
1962年 | 2篇 |
1959年 | 2篇 |
1958年 | 2篇 |
1955年 | 2篇 |
1952年 | 2篇 |
排序方式: 共有444条查询结果,搜索用时 15 毫秒
21.
Ben Yahia H Gaudin E Darriet J Banks M Kremer RK Villesuzanne A Whangbo MH 《Inorganic chemistry》2005,44(9):3087-3093
A new magnetic oxide, CuMnVO4, was prepared, and its crystal structure was determined by single-crystal X-ray diffraction. The magnetic properties of CuMnVO4 were characterized by magnetic susceptibility and specific heat measurements, and the spin exchange interactions of CuMnVO4 were analyzed on the basis of spin-polarized electronic band structure calculations. CuMnVO4 contains MnO4 chains made up of edge-sharing MnO6 octahedra containing high-spin Mn2+ cations. Our work shows that CuMnVO4 undergoes a three-dimensional antiferromagnetic transition at approximately 20 K. Both the intrachain and interchain spin exchanges are antiferromagnetic, and the interchain spin exchange is not negligible compared to the intrachain spin exchange. 相似文献
22.
Wijkens P Jastrzebski JT van Der Schaaf PA Kolly R Hafner A van Koten G 《Organic letters》2000,2(11):1621-1624
A general method for the functionalization of Si-Cl terminated carbosilane dendritic molecules via organolithium or organomagnesium reagents is described. Quantitative exchange of the bromine atoms of 4-bromophenyl-functionalized dendrimers affords polylithiated species that are valuable starting materials for further functionalization, e.g., into pyridyl alcohols. The latter were successfully applied as catalyst precursors in a ruthenium-mediated ring-closure metathesis reaction. 相似文献
23.
Abstract— A relationship between Chl a and each of its accessory pigments, neoxanthin, violaxanthin, lutein, Chl b and carotene, is demonstrated in soybean and peanut genotypes. These genotypes include normal and Chl-deficient types. Plots of Chl a content against accessory pigment content generate straight-line relationships that are extrapolated to intersect the Chl a axis. The points of intersection correctly predict the order of origin of certain accessory pigments (lutein, carotene and Chl b ), but incorrectly predict that neoxanthin and violaxanthin arise after the introduction of Chl a . 相似文献
24.
Ronald E. Banks Ismail M. Farhat Roy Fields Robin G. Pritchard Mohamad M. Saleh 《Journal of fluorine chemistry》1985,28(3):325-340
The nitrosoarenes ArNO (Ar = C6H5, 2-MeC6H4, 2,4,6- Me3C6H2 and C6F5) have been condensed with 4-(dichloroamino)- tetrafluoropyridine to provide the azoxy-compounds pyFN()Ar (pyF = 2,3,5,6-tetrafluoro-4-pyridyl); de-oxygenation of the first three with triphenylphosphine or triethyl phosphite gave the corresponding azo-compounds, and the reverse reaction was achieved in the case of pyFNNC6H2Me3-2,4,6 using peroxytrifluoroacetic acid. Thermolysis of 4-azidotetrafluoropyridine in the presence of pentafluoronitrosobenzene provided the perfluorinated azoxy-compound pyFN()C6F5. X-Ray methods have been used to determine the molecular geometry of pyFN()C6H2Me3-2,4,6. 相似文献
25.
26.
27.
Banks CE Kruusma J Moore RR Tomcík P Peters J Davis J Komorsky-Lovrić S Compton RG 《Talanta》2005,65(2):423-429
Three different electroanalytical techniques for the detection of manganese in marine sediments are evaluated. The anodic stripping voltammetry of manganese at an in situ bismuth-film-modified boron-doped diamond electrode and cathodic stripping voltammetry at a carbon paste electrode are shown to lack the required sensitivity and reproducibility whereas cathodic stripping voltammetry at a bare boron-doped diamond electrode is shown to be reliable and selective with a limit of detection, from applying a 60 s accumulation period of 7.4 × 10−7 M and a sensitivity of 0.24 A M−1. The method was used to evaluate the manganese content of marine sediments taken from Šibenik, Croatia. 相似文献
28.
29.
30.
J. W. Banks 《国际流体数值方法杂志》2011,65(5):602-608
In this short note we describe a simple extension to the multi‐material shock‐capturing algorithm presented in (J. Comput. Phys. 2007; 223 :262–297) that can be used to maintain sharp material interfaces. The method takes the form of an artificial compression which is designed so that the material indicator jumps across only a few cells but which does not excite physical instabilities in the flow. The advantages of the approach include its simplicity and flexibility in that it provides a parameter that effectively determines the captured interface thickness. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献