全文获取类型
收费全文 | 9329篇 |
免费 | 367篇 |
国内免费 | 61篇 |
专业分类
化学 | 6389篇 |
晶体学 | 93篇 |
力学 | 279篇 |
数学 | 808篇 |
物理学 | 2188篇 |
出版年
2023年 | 54篇 |
2022年 | 190篇 |
2021年 | 226篇 |
2020年 | 178篇 |
2019年 | 172篇 |
2018年 | 172篇 |
2017年 | 144篇 |
2016年 | 296篇 |
2015年 | 269篇 |
2014年 | 353篇 |
2013年 | 596篇 |
2012年 | 742篇 |
2011年 | 823篇 |
2010年 | 469篇 |
2009年 | 385篇 |
2008年 | 616篇 |
2007年 | 580篇 |
2006年 | 512篇 |
2005年 | 473篇 |
2004年 | 408篇 |
2003年 | 325篇 |
2002年 | 326篇 |
2001年 | 216篇 |
2000年 | 177篇 |
1999年 | 129篇 |
1998年 | 69篇 |
1997年 | 79篇 |
1996年 | 95篇 |
1995年 | 80篇 |
1994年 | 75篇 |
1993年 | 57篇 |
1992年 | 60篇 |
1991年 | 47篇 |
1990年 | 51篇 |
1989年 | 34篇 |
1988年 | 26篇 |
1987年 | 12篇 |
1986年 | 10篇 |
1985年 | 26篇 |
1984年 | 18篇 |
1983年 | 17篇 |
1982年 | 18篇 |
1981年 | 16篇 |
1980年 | 12篇 |
1979年 | 13篇 |
1978年 | 16篇 |
1977年 | 10篇 |
1976年 | 13篇 |
1975年 | 10篇 |
1972年 | 9篇 |
排序方式: 共有9757条查询结果,搜索用时 15 毫秒
11.
We consider a SA-SA' critical point in the presence of a symmetry-breaking external magnetic (electric) field with a positive magnetic (dielectric) anisotropy or a dislocation layer. Via a renormalization group analysis of the model hamiltonian, we show that the upper critical dimensions below which mean-field theory breaks down is dc = 2·5. Thus the SA-SA' transition in three dimensions becomes mean-field like in the presence of a symmetry-breaking field. We estimate the reduced temperature region where we can expect to see the mean field SA-SA' critical point in the presence of a magnetic field or a dislocation layer. 相似文献
12.
Jin Kyu Park Dong Hun Lee Bok Ju Song Jae Buem Oh Hwan Kyu Kim 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1326-1342
We have designed and synthesized novel perfluorinated polyimides with 3D controlled structure. At first, we successfully developed the new synthetic routes to diamines with pendant bulky perfluorinated aromatic units in a multi‐step synthetic procedure. Novel perfluorinated polyimides were prepared in a two‐step reaction in N‐methyl‐2‐pyrrolidinone (NMP) solution: The first step was for the synthesis of polyamic acids (PAAs) and the second reaction was for the imidization of PAA. The polymer yield was over 89% and the inherent viscosity of PAAs was in the range of 0.24–0.36 dL/g. The thin films were prepared by spin‐coating the PAA solution in NMP onto various substrates such as a Si wafer or a KBr pellet, dried at 80 °C and further cured at 230 °C. The resultant polyimides are thermally stable over 400 °C. The refractive index and birefringence of the resultant polyimides are 1.5858–1.6452 and 0.01–0.005, respectively. The refractive index of polyimide decreases with increasing the fluorine content. The copolymerization and the ether linkages into the backbone reduce the birefringence of polyimides. Surprisingly, the pendant ether linkage is not a crucial factor in reducing the polyimide birefringence. Their birefringence is comparatively very low, compared with that of previous polyimides. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1326–1342, 2006 相似文献
13.
Chae Kyu Kim Eun Seok Song Hyung Joo Kim Chiyoung Park Young Chul Kim Jai Kyeong Kim Jae Woong Yu Chulhee Kim 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):254-263
We have synthesized conjugated dendrimer with triazine peripheries, and their luminescence properties were investigated. The dendrimers consist of dendritic triazine wedges for electron transport, distyrylbenzene core as an emitting moiety, and t‐butyl peripheral groups for good processing properties. The dendrimers have LUMO values of about ?2.7 eV possibly because of the triazine moiety with high electron affinity. Photoluminescence study indicates that energy transfer occurs from the triazine wedges to the stilbene bridge, and finally to the core chromophore units due to a cascade decrease of bandgap from the peripheral wedge to core moiety. Therefore, the emission wavelength was determined by the structure of the core unit. The energy transfer efficiency of distyrylbenzene‐cored dendrimers was about 75 and 55% for Trz‐1GD‐DSB and Trz‐2GD‐DSB, respectively. A preliminary electroluminescence property also was investigated. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 254–263, 2006 相似文献
14.
In order to obtain the depth profile of a thin film, we investigated the emission characteristics of a voltage modulation glow discharge to optimize the modulation parameters (modulation voltage, offset voltage, and modulation frequency). In this study, a phase-sensitive detection method with a lock-in amplifier to the modulation technique led to a higher sensitivity and a larger signal-to-noise ratio in the emission analysis compared to the normal dc amplification method. Upon increasing the maximum voltage, the emission intensity of the Cu atomic line (CuI 239.34 nm) increased linearly at a modulation voltage of 400 V and an offset voltage of 300 V. On the other hand, the emission intensity was gradually reduced when a modulation frequency increased. It is advantageous for surface analysis that the voltage modulation technique gives a lower sputtering rate rather than the conventional dc discharge. 相似文献
15.
16.
17.
18.
19.
William W. Paudler Richard A. Vandahm Young N. Park 《Journal of heterocyclic chemistry》1972,9(1):81-85
The diazaanalog of “cycl[3,2,2]azine”, “1,4-diazacycl[3,2,2]azine” (1,4,7b-triazacyclopent-[cd]indene) and its 2-methyl derivative were prepared. These compounds are subject to facile acid-catalyzed hydrolysis affording substituted imidazo[1,2-a]pyridines. 相似文献
20.