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Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4(-) and comparison with imidazolium based systems 总被引:1,自引:0,他引:1
Abood HM Abbott AP Ballantyne AD Ryder KS 《Chemical communications (Cambridge, England)》2011,47(12):3523-3525
The addition of a simple amide to AlCl(3) causes the formation of a liquid of the form [AlCl(2)·nAmide](+) AlCl(4)(-). The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. This ionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids. 相似文献