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131.
This research extends previous work with dynamic models to manage groundwater quality by using the consumptive nitrate use rate instead of the nitrate application rate. The analysis indicates that misspecification results in overestimation of economic benefits, and supra-optimum nitrogen fertilizer application rates and groundwater nitrate stocks at a steady state. 相似文献
132.
One of the shortcomings of R&D evaluation is a lack of emphasis on analytical assessment of the value of an on-going R&D project. This paper addresses the problem concerning the distributive aspect of access to superior knowledge. Decision tree analysis and probability models appear to be appropriate tools for assessing the values of an intermediate result and patent reward of a firm's R&D decision in an environment of perfect information and oligopolistic competition. The assessed values are used as minimum prices acceptable to the firm when the knowledge is disseminated to the public. This paper will attempt to resolve this problem through the determination of the appropriate values of the reservation price of the first-stage invention in terms of the final reward and of a patent reward for which the inventor is willing to apply. 相似文献
133.
J Z Hu R J Pugmire A M Orendt D M Grant C Ye 《Solid state nuclear magnetic resonance》1992,1(4):185-195
Taking advantage of the long 13C T1 values generally encountered in solids, selective saturation and inversion of more than one resonance in 13C CP/MAS experiments can be achieved by sequentially applying several DANTE pulse sequences centered at different transmitter frequency offsets. A new selective saturation pulse sequence is introduced composed of a series of 90 degrees DANTE sequences separated by interrupted decoupling periods during which the selected resonance is destroyed. Applications of this method, including the simplification of the measurement of the principal values of the 13C chemical shift tensor under slow MAS conditions, are described. The determination of the aromaticity of coal using a relatively slow MAS rate is also described. 相似文献
134.
Silver nitrate-acetonitrile and π iodine-benzene complexes in thermotropic liquid crystals have been studied by 1H, 2H, and 13C NMR spectroscopy and by optical microscopy. Evidence for at least two silver complexes in each liquid crystal is presented. 相似文献
135.
The magnified cross-section of the LDV probe volume fringe field created on a far screen (image plane) with an imaging lens is examined both analytically and experimentally. It is shown that measurements of the image plane fringe field can be used to quantitatively determine the fringe field existing within the probe volume. Because the fringe spacing in the magnified image is more accessible experimentally, both longitudinal- and lateral-coordinate variations in fringe spacing can be determined, permitting a complete mapping of the fringe field. The detailed knowledge of the fringe field thus obtained allows beam quality, alignment, and fringe uniformity to be evaluated with greater precision than is possible with other techniques.The authors would like to acknowledge C. F. Edwards and R. L. Schmitt for the loan of the beam profiler and for many helpful discussions. This work was performed at the Combustion Research Facility, Sandia National Laboratories, and was supported by the U.S. Department of Energy, Office of Industrial Technologies, Advanced Industrial Concepts Division. 相似文献
136.
J.-M. Colmont B. Bakri G. Wlodarczak G. Cazzoli C. Puzzarini 《Journal of Molecular Spectroscopy》2005,231(2):171-187
For atmospheric purposes, the N2- and O2-, or Air-broadenings of selected transitions of ozone have been investigated in the 195-300 K temperature range. More precisely, the following 13 transitions in the 280-345 GHz frequency range have been studied: the 22,0 ← 21,1 (279.5 GHz), 242,22 ← 241,23 (286.2 GHz), 32,2 ← 31,3 (286.3 GHz), 52,4 ← 51,5 (293.2 GHz), 134,10 ← 143,11 (300.7 GHz), 140,14 ← 131,13 (301.8 GHz), 72,6 ← 71,7 (303.2 GHz), 262,24 ← 261,25 (315.9 GHz), 53,3 ← 62,4 (317.2 GHz), 201,19 ← 200,20 (320.0 GHz), 266,20 ← 275,23 (343.2 GHz), 262,24 ← 253,23 (343.2 GHz), and 43,1 ← 52,4 (343.5 GHz) lines. Systematic errors are known to be the principal error source and recent intercomparisons of line-broadening coefficients showed differences up to 20%, thus a large effort in minimizing systematic error sources has been taken and cross check measurements with different techniques have been carried out. The conclusion of the intercomparison performed indicates an excellent agreement of the results and that an uncertainty less than 3%, which also takes into account the systematic errors, can be claimed for the line-broadening parameters. 相似文献
137.
F. Rubio F. García H. D. Burrows A. A. C. C. Pais A. J. M. Valente M. J. Tapia J. M. García 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1788-1799
The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H2O and D2O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H2O and D2O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007 相似文献
138.
C. P. Massarolo G. P. Menzala A. F. Pazoto 《Mathematical Methods in the Applied Sciences》2007,30(12):1419-1435
The aim of this work is to consider the Korteweg–de Vries equation in a finite interval with a very weak localized dissipation namely the H?1‐norm. Our main result says that the total energy decays locally uniform at an exponential rate. Our analysis improves earlier works on the subject (Q. Appl. Math. 2002; LX (1):111–129; ESAIM Control Optim. Calculus Variations 2005; 11 (3):473–486) and gives a satisfactory answer to a problem suggested in (Q. Appl. Math. 2002; LX (1):111–129). Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
139.
We introduce a random perturbed version of the classical fidelity and we show that it converges with the same rate of decay
of correlations, but not uniformly in the noise. This makes the classical fidelity unstable in the zero-noise limit. 相似文献
140.
The hyperfine constants for muonium in elemental and binary inorganic solids suggest formation of three different families
of defect centre, with distinct electronic structures. The overall range of values, spanning nearly five orders of magnitude,
and their correlation with host properties such as band gap and electron affinity, reveal a deep-to-shallow instability which
has profound implications for the electrical properties of hydrogen impurity in electronic materials, both semiconducting
and dielectric. 相似文献