ICP-AES法测定浙江雪胆中的微量元素

采用电感耦合等离子体原子发射光谱仪（ICP-AES）对浙江雪胆和中华雪胆水溶性部分、甲醇提取物和全样中的8种微量元素进行了测定。结果表明，浙江雪胆中含有丰富的人体必需微量元素，且微量元素的含量明显高于中华雪胆，这为浙江雪胆的进一步的开发利用提供科学依据。     

Synthesis of 2-Benzylthio-5-phenyl-3,4-disubstituted Thiophenes by Intramolecular Condensation of α-Oxo Ketene Dibenzyl~thioacetals

Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ａｓａｋｉｎｄｏｆｖｅｒｓａｔｉｌｅｉｎｔｅｒｍｅｄｉａｔｅｓ ,α ｏｘｏｋｅｔｅｎｅｄｉｔｈｉｏａｃｅｔａｌｓ 1(Ｆｉｇ .1)ａｒｅｉｍｐｏｒｔａｎｔｉｎｏｒｇａｎｉｃｓｙｎｔｈｅ ｓｉｓ1ａｎｄｍｏｓｔｗｏｒｋｓａｒｅｆｏｃｕｓｅｄｏｎｔｈｅα ｏｘｏｋｅｔｅｎｅｄｉｍｅｔｈｙｌｔｈｉｏａｃｅｔａｌｓ .2 Ｉｎｏｕｒｓｔｕｄｉｅｓ ,ｉｔｉｓｆｏｕｎｄｔｈａｔｓｏｍｅｒｅａｃｔｉｏｎｓｕｐｏｎｔｈｅｓｅｋｉｎｄｏｆｉｎｔｅｒｍｅｄｉａｔｅｓａｒｅｍｏｄｕｌａｔｅｄｂｙｔｈｅ…     

Spectroscopic evidence for triplet excitation energy transfer among carotenoids in the LH2 complex from photosynthetic bacterium Rhodopseudomonas palustris

The LH2 complex from Rhodopsudomonas (Rps.) palustris is unique in the heterogeneous carotenoid compositions. The dynamics of triplet excited state Carotenoids (3Car*) has been investigated by means of sub-microsecond time-resolved absorption spectroscopy both at physiological temperature (295 K) and at cryogenic temperature (77 K). Broad and asymmetric Tn←T-1 transient absorption was observed at room temperature following the photo-excitation of Car at 532 nm, which suggests the contribution from various carotenoid compositions having different numbers of conjugated C=C double bonds (Nc=c). The triplet absorption bands of different carotenoids, which superimposed at room temperature, could be clearly distinguished upon decreasing the temperature down to 77 K. At room temperature the shorter-wavelength side of the main Tn←T1 absorption band decayed rapidly to reach a spectral equilibration with a characteristic time constant of-1 μs, the same spectral dynamics, however, was not observed at 77 K. The     

双烯醇酮乙酸酯的极谱催化波及应用研究

采用线性扫描极谱技术,研究了在H2O2存在下双烯醇酮乙酸酯的极谱催化波。结果表明,在pH 4.0±0.5的B-R缓冲溶液、8.0×10-3mol/L H2O2溶液和0.1 mol/L KCl底液中,双烯醇酮乙酸酯于-1.01 V处产生一极谱催化波;其一阶倒数峰电流与双烯醇酮乙酸酯的浓度在1.0×10-8~1.0×10-7mol/L范围内有良好的线性关系,iP′=1.384×1011c 2.374×104(nA/s),相关系数r=0.9991;讨论了极谱催化波的产生机理。     

The Interaction between Propranolol and Gold Nanoparticles and its Analytical Application

The addition of propranolol induced the aggregation of gold nanoparticles, and increased Rayleigh light scattering (RLS) intensity greatly. The interaction between them was studied by RLS spectrum, UV-Vis spectrum and transmission electron microscopy (TEM). Based on these results, a novel method was proposed for propranolol assay. With the combination of solid phase microextraction (SPME), the proposed method was successfully applied to determine propranolol in urine.     

酶促缩聚和原子转移自由基聚合法合成AB型两亲性嵌段共聚物

Novozyme-435催化10-羟基癸酸进行自缩聚反应得到线性聚酯, 端基分别是羟基(—OH)和羧基(—COOH), 在三乙胺催化下, 分别用α-溴代丙酰溴和三甲基氯硅烷(TMSCL)进行端基官能化生成一个单官能度的大分子引发剂, 在CuCl/2,2'-联吡啶(bpy)催化体系中, 引发甲基丙烯酸环氧丙酯(GMA)的原子转移自由基反应(ATRP), 得到聚(10-羟基癸酸酯)/聚甲基丙烯酸环氧丙酯(PHDA-b-PGMA) AB 型两亲性嵌段共聚物, 其结构及分子量(分布)通过核磁共振和凝胶渗透色谱(GPC)确证. 此AB型两亲性嵌段共聚物在水溶液中能自组装形成纳米粒子, 用原子力显微镜(AFM)观察粒子的形状和大小.     

α,α-二乙酰基二苄硫缩烯酮的碱催化脱乙酰基反应及缩合反应机理研究

α-羰基二硫缩烯酮是一类极其重要的有机合成中间体，烷硫基对该类具有推-拉电子效应的共轭体系的性质影响很大。据此，我们率先提出了烷硫基对α-羰基二硫缩烯酮类化合物的化学行为具有调控作用的观点，并将其归因于空间电子因素的作用，α-乙酰基-α′-羰基二苄硫缩烯酮(1)具有多反应性特征。近来，我们利用该特征在氢氧化钠催化下通过化合物1的环合合成了多取代噻吩类化合物；在乙醇钠-醋酸铅作用下经乙氧基对化合物1的苄硫基的取代实现了α-羰基-O，O-缩烯酮的合成。     

降低均质压燃发动机碳氢排放的一种新方法

将发动机多维CFD程序KIVA-3V与化学动力学程序CHEMKIN Ⅲ及DETCHEM相耦合,模拟了缝隙区催化燃烧对HCCI发动机排放特性的影响.利用此模型分析了活塞冠侧面催化剂铂涂层对HCCI发动机缸内温度场及HC浓度场的影响,结果表明当活塞冠侧面存在催化剂时,与缸内无催化燃烧相比,HC、CO的排放得到很大程度降低,但Nox的排放将略有升高.     

多椭球投射式LED前照灯光学设计

LED光源具有寿命长、点亮速度快、节能等优点,非常适合作为新一代的汽车前照灯的主要光源。研究了使用LED光源和多椭球反射镜的投射式前照灯的设计方法,建立了光学系统模型。阐述了反射镜、挡板、透镜的设计思想。采用Cree xre-7090 LED作为光源,并在此基础上采用ASAP进行了计算机模拟。结果表明,可产生宽广但不高的光型,明暗截止线清晰。