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Mikhaleva A. I. Korostova S. E. Vasil'ev A. N. Balabanova L. N. Sokol'nikova N. P. Trofimov B. A. 《Chemistry of Heterocyclic Compounds》1977,13(12):1305-1309
In the presence of 2,2-azobisisobutyronitrile or in the absence of an initiator alkanethiols add to 1-vinylpyrroles exclusively counter to Markovnikov's rule to give 1-(2-alkylthioethyl)pyrroles (in yields up to 94%).Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1636–1639, December, 1977. 相似文献
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B. A. Trofimov N. I. Golovanova A. I. Mikhaleva S. E. Korostova A. N. Vasil'ev L. N. Balabanova 《Chemistry of Heterocyclic Compounds》1977,13(7):739-742
The relative basicities of a series of N-vinylpyrroles and some of their analogs with saturated substituents attached to the nitrogen atom were investigated (the v
OH shifts in the IR spectrum of phenol were measured). The v
OH values were measured in the interval 100–150 cm–1. Alkyl substituents in the 2 and 3 positions raise the basicity of the pyrrole ring, while a phenyl substituent in the 2 position lowers it. N-Vinyl-pyrroles are 25% less basic than their limiting analogs-N-ethyl- and N-(2-alkylthioethyl)pyrroles. The inductive effect of the substituent makes the major contribution to the basicities of the investigated pyrroles. The v
OH values for N-vinyl-2,3-diphenylpyrrole are not in conformity with the general tendencies and constitute evidence for the appreciable contribution of continuous conjugation through the double bond, the pyrrole ring, and the benzene ring in the 3 position.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 915–918, July, 1977. 相似文献
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G. A. Shvekhgeimer K. I. Kobrakov O. S. Kartseva L. V. Balabanova 《Chemistry of Heterocyclic Compounds》1991,27(3):299-302
A number of haloalkyltetrazoles were obtained by the addition of polyhalo derivatives to vinyltetrazoles. A number of haloalkyl-substituted benzazoles were obtained by the reaction of imino ester hydrochlorides that have haloalkyl radicals with o-phenylenediamine and o-aminophenol.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 369–372, March, 1991. 相似文献
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A. Ya. Samuilov S. V. Nesterov F. B. Balabanova Ya. D. Samuilov A. I. Konovalov 《Russian Journal of Organic Chemistry》2014,50(2):155-159
Quantum-chemical method B3LYP/6-311++G(df,p) was applied to the study of complex formation between phenol and methanol. The complexes of molecules bound by the hydrogen bond possess enhanced donoracceptor and acid-base properties as compared to monomer molecules. The reactions of phenol and methanol complexes with methyl isocyanate proceed through a concerted late asymmetric transition state by the type of nucleophilic addition. The most kinetically and thermodynamically favorable transformation is the process involving the complex “phenol-acceptor, methanol-donor.” Phenol compounds are able to catalyze the addition of alcohols to isocyanates. 相似文献
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F. K. Velichko T. T. Vasil'eva L. V. Balabanova G. A. Shvekhgeimer 《Russian Chemical Bulletin》1988,37(6):1280-1280
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, p. 1446, June, 1988. 相似文献
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The mechanism of ultrafine (<100 nm) SiO2 particle production under thermal arc plasma conditions is studied by modelling. Two cases of the process are considered in the model: (i) when it is determined as a pure free-molecular coagulation; (ii) when the coagulation is influenced by the interparticle forces. The Hamaker formula is used to present the van der Waals forces between the particles. Particle size distribution functions (PSDF) are calculated for both cases. It is shown that inclusion of the interparticle interactions does not affect the self-preservation of the PSDF. The mean particle sizes are obtained from the PSDF and compared. Higher values are observed in the case that includes van der Waals forces. Comparison between experimental and calculated PSDF shows better agreement in the case considering interparticle forces. 相似文献
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B. A. Arbuzov N. N. Zobova F. B. Balabanova M. F. Tarasova 《Russian Chemical Bulletin》1973,22(2):440-441
Conclusions Trichoroacetyl isocyanate under the influence of quinoline forms ditrichloroacetylcarbodiimide, which adds to the C=N bond of quinoline on the type of a 2+4-cycloaddition. Benzoyl isocyanate under the influence of quinoline forms the dimer.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp.456–458, February, 1973. 相似文献