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21.
K.K. Bajaj 《Solid State Communications》1974,15(7):1221-1224
A new phenomenological effective interaction potential between an electron and a hole of a Wannier exciton in a polarizable medium is proposed. Binding energies of Wannier excitons are calculated variationally using this potential in several polar crystals. A close agreement between the theoretical values thus calculated and the experimental values is found in all polar crystals including thallium halides. 相似文献
22.
Bajaj VS Farrar CT Hornstein MK Mastovsky I Vieregg J Bryant J Eléna B Kreischer KE Temkin RJ Griffin RG 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,(2):404-409
In this communication, we report enhancements of nuclear spin polarization by dynamic nuclear polarization (DNP) in static and spinning solids at a magnetic field strength of 9 T (250 GHz for g = 2 electrons, 380 MHz for 1H). In these experiments, 1H enhancements of up to 170 ± 50 have been observed in 1-13C-glycine dispersed in a 60:40 glycerol/water matrix at temperatures of 20 K; in addition, we have observed significant enhancements in 15N spectra of unoriented pf1-bacteriophage. Finally, enhancements of ∼17 have been obtained in two-dimensional 13C–13C chemical shift correlation spectra of the amino acid U–13C, 15N-proline during magic angle spinning (MAS), demonstrating the stability of the DNP experiment for sustained acquisition and for quantitative experiments incorporating dipolar recoupling. In all cases, we have exploited the thermal mixing DNP mechanism with the nitroxide radical 4-amino-TEMPO as the paramagnetic dopant. These are the highest frequency DNP experiments performed to date and indicate that significant signal enhancements can be realized using the thermal mixing mechanism even at elevated magnetic fields. In large measure, this is due to the high microwave power output of the 250 GHz gyrotron oscillator used in these experiments. 相似文献
23.
S. K. Sharma K. Sudarshan P. Maheshwari D. Dutta P. K. Pujari C. P. Shah M. Kumar P. Bajaj 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,82(3-4):335-340
Poly vinyl alcohol (PVA) capped CdSe nanoparticles having size in the range of 7–17 nm have been synthesized through chemical route and characterized using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Positron coincidence Doppler broadening (CDB) measurements have been carried out in these nanoparticles. It is observed that the electron momentum distributions show a variation in the core electron momentum region with the particle size. In order to examine the influence of defects, first principle calculations of electron momentum distributions in bulk CdSe and in the presence of Cd as well as Se vacancy defects have been performed. Comparison of experimental data with the calculated momentum distribution reveals the presence of Cd vacancy defects, the concentration of which decreases with the increase in the particle size. The present study also indicates possible Se enrichment on the surface of the nanoparticles with the decrease in the particle size. 相似文献
24.
25.
Rate coefficients for the reaction of Cl atoms with cycloalkenes have been determined using the relative rate method, at 298 K and atmospheric pressure of N2. Reference molecule was n‐hexane, and the concentrations of the organics were followed by gas chromatographic analysis. Cl atoms were prepared by photolysis of trichloroacetyl chloride at 254 nm. The relative rates of reactions of Cl atoms with cycloalkenes, with respect to n‐hexane, are measured as 1.12 ± 0.38, 1.31 ± 0.14, and 1.69 ± 0.18 for cyclopentene, cyclohexene, and cycloheptene, respectively. Considering the absolute value of the rate coefficient of the reaction of Cl atom with n‐hexane as 3.03 ± 0.06 × 10?10 cm3 molecule?1 s?1, the rate coefficient values for cyclopentene, cyclohexene, and cycloheptene are calculated to be (3.39 ± 1.08) × 10?10, (3.97 ± 0.43) × 10?10, and (5.12 ± 0.55) × 10?10 cm3 molecule?1 s?1, respectively. The experiments for each molecule were repeated six to eight times, and the slopes and the rate coefficients given above are the average values of these measurements, and the quoted error includes 2σ as well as all other uncertainties in the measurement and calculations. The rate coefficient increases linearly with the number of carbon atoms, with an increment per additional CH2 group being (8.7 ± 1.6) × 10?12 cm3 molecule?1 s?1. Chloroketones and chloroalcohols, along with unsaturated ketones and alcohols, were found to be the major products of Cl‐atom‐initiated oxidation of cycloalkenes in the presence of air. The atmospheric implications of these results are discussed, along with a comparison with the reported structure activity relationships. © 2009 Wiley Periodicals, Inc. Int J Chem Kinet 42: 98–105, 2010 相似文献
26.
We use a combination of both symbolic and numerical techniques to construct degree boundedC
k
-continuous, rational B-spline ε-approximations of real algebraic surface-surface intersection curves. The algebraic surfaces
could be either in implicit or rational parametric form. At singular points, we use the classical Newton power series factorizations
to determine the distinct branches of the space intersection curve. In addition to singular points, we obtain an adaptive
selection of regular points about which the curve approximation yields a small number of curve segments yet achievesC
k
continuity between segments. Details of the implementation of these algorithms and approximation error bounds are also provided.
Supported in part by NSF Grants CCR 92.22467, DMS 91-01424, AFOSR Grant F49620-10138 and NASA Grant NAG-1-1473.
Supported in part by K.C. Wong Education Foundation, Hong Kong. 相似文献
27.
Rukhsana Ilays Kureshy K. Jeya PrathapManish Kumar Prasanta Kumar BeraNoor-ul Hasan Khan Sayed Hasan Razi AbdiHari Chandra Bajaj 《Tetrahedron》2011,67(43):8300-8307
A series of chiral macrocyclic Cr(III) salen complexes 1-8 were synthesized and characterized. These complexes were found to be highly active, regio-, diastereo-, and enantioselective catalysts in aminolytic kinetic resolution (AKR) of racemic trans-epoxides as well as asymmetric ring opening (ARO) of prochiral meso-epoxides with various anilines as nucleophiles at room temperature in 18-24 h. Excellent yields (>99% with respect to the nucleophile) with high enantioselectivity (ee, >99%) of chiral anti-β-amino alcohols was achieved with concomitant recovery of corresponding epoxides in high ee (up to >99%). The complex 1 also catalyzed the ARO of meso-epoxides to provide corresponding syn-β-amino alcohols in high yield (99%) and ee (up to 91%). Due to built-in basic sites in the catalyst, no external base (as an additive) was required to promote AKR and ARO reactions. The catalyst 1 was conveniently recycled several times with retention of its performance. The AKR of trans-stilbene oxide with aniline was successfully demonstrated at relatively higher scale (10 mmol) using the catalyst 1. 相似文献
28.
29.
We discuss the notion of spin squeezing considering two mutually exclusive classes of spin-s states, namely, oriented and non-oriented states. Our analysis shows that the oriented states are not squeezed while non-oriented
states exhibit squeezing. We also present a new scheme for construction of spin-s states using 2s spinors oriented along different axes. Taking the case of s=1, we show that the ‘non-oriented’ nature and hence squeezing arise from the intrinsic quantum correlations that exist among
the spinors in the coupled state. 相似文献
30.
Single crystals of EuB6 were prepared by the floating-zone method. Magnetic and electric measurements on these crystals in the temperature range 1.6–300 K revealed that the pure EuB6 is an antiferromagnet with a Néel temperature of 5–6 K and has a carrier concentration of 4.2 × 1020 cm-3. It was found that in polycrystalline sample, defects of Eu ions reduce the carrier concentration and make the sample ferromagnetic. It is suggested that the conduction electrons in pure EuB6 originate from the overlap of the 4f band tail and the conduction band. 相似文献