Some topologies on a Šerstnev probabilistic normed space

In this paper we will introduce two other topologies, coarser than the so-called strong topology, on a class of Šerstnev probabilistic normed spaces, and obtain some important properties of these topologies. We will show that under the first topology, denoted by τ₀, our probabilistic normed space is decomposable into the topological direct sum of a normable subspace and the subspace of probably null elements. Under the second topology, which is in fact the inductive limit topology of a family of locally convex topologies, the dual space becomes a locally convex topological vector space.     

All-optical half adder based on photonic crystals for BPSK signals

Optical and Quantum Electronics - This paper aims at first deriving the general forms of the electromagnetic vector and scalar potentials inside a cylindrical wave-guide by placing a 3D-charged...     

Sensitive Voltammetric Method for Rapid Determination of Sarcosine as a New Biomarker for Prostate Cancer Using a TiO2 Nanoparticle/Ionic Liquid Modified Carbon Paste Electrode

Russian Journal of Electrochemistry - Sarcosine has been identified as a key metabolite marker for monitoring and early diagnosis of metastatic prostate cancer (PCa), and it is detectable in the...     

Optimization of effective processing parameters of hybrid anti-corrosion Si/Zr sol–gel coatings doped with cerium salt for aluminum alloy 6061

Journal of Sol-Gel Science and Technology - In this study, the Taguchi method was used to design of experiment to obtain optimum conditions for hybrid Si–Zr sol–gel coating doped with...     

Covalent bonding of magnetic Fe3O4 nanoparticles to aminopropyl‐functionalized magnesium phyllosilicate clay: Synthesis and cytotoxic potential investigation

Stable water dispersion of Fe₃O₄ magnetic nanoparticles (NPs) were successfully synthesized by using 3‐glycidoxypropyltrimethoxysilane (GPTMS) and Mg‐phyllo (organo) silicate known as aminoclay (AC) containing pendant amino groups with the approximate composition (R₈Si₈Mg₆O₁₆(OH)₄, R = CH₂CH₂CH₂NH₂). The Fe₃O₄‐GPTMS magnetic NPs with an epoxy functional group are suitable for forming a covalent bond with the amine group of aminoclay in an epoxy ring opening reaction. Appropriate Fe₃O₄‐GPTMS‐aminoclay (FG‐AC) magnetic composite are promising carriers for the targeting and delivery of platinum‐based anticancer drugs. Analysis of the cytotoxicity of the nanostructures on a K562 leukemia cell line using a colorimetery assay shows that both the FG‐AC and cis‐platin/FG‐AC magnetic composite were biocompatible. The nanostructures characterizations were investigated by Fourier transform infrared spectroscopy, X‐ray diffraction, transmission electron microscopy and energy dispersive analysis of X‐ray techniques. Magnetic measurement revealed that the saturated magnetization of the FG‐AC nanocomposite reached 7.6 emu/g and showed the characteristics of magnetism.     

On the nonlinear primary resonances of a piezoelectric laminated micro system under electrostatic control voltage

In this article, a comprehensive nonlinear analysis for a piezoelectric laminated micro system around its static deflection is presented. This static deflection is created by an electrostatic DC control voltage through an electrode plate. The micro system beam is assumed as an elastic Euler-Bernoulli beam with clamped-free end conditions. The dynamic equations of this model have been derived by using the Hamilton method and considering the nonlinear inertia, curvature, piezoelectric and electrostatic terms. The static and dynamic solutions have been achieved by using the Galerkin method and the multiple-scales perturbation approach, respectively. The results are compared with numerical and other existing experimental results. By studying the primary resonance excitation, the effects of different parameters such as geometry, material and excitations voltage on the system?s softening and hardening behaviors are evaluated. In a piezoelectrically actuated micro system it was showed that because of existence of curvature and inertia nonlinear terms a small change in excitation amplitude can lead to the formation and expansion of nonlinear response. In this paper, it is demonstrated that by applying an electrostatic DC control voltage, these nonlinearities can be controlled and altered to a linear domain. This model can be used to design a nano or micro-scale smart device.     

The response of selected isomers of B80 buckyball toward NH3 adsorption: a density functional theory investigation

Density functional theory calculations at the B3LYP/6-31G(d) and B3LYP/6-31+G(d) levels were carried out for the adsorption of NH₃ on three symmetric isomers of B₈₀ {C ₁, T _h, I _h}. To investigate the binding features of B₈₀ isomers with NH₃, different studies including the structural and electronic parameters, the ¹⁴N electric field gradient tensors and the atoms in molecules (AIM) properties were considered. The calculated parameters by these investigations can be used as powerful tools to find out some of the unknown aspects of electronic structures of the boron buckyball and its isomers. According to previous studies, boron buckyball as an amphoteric and a hard molecule has two distinct reactive sites defined as cap and frame which act as an acid and a base, respectively. Regarding the obtained results in this study, all the isomers had the same exposure when NH₃ molecule reacted with the external wall of B₈₀. For instance, the stability of N–B bond in the cap site was significantly more than the stability of N–B bond in the frame. Moreover, the adsorption of NH₃ on frame site showed a considerable reduction in HOMO–LUMO energy gap. According to AIM theory, an electrostatic nature was observed for N–B interaction. Concerning the selected isomers of buckyball, the capability of the NH₃–B₈₀ complexes to localize electron at the N–B bond critical points depend on the reaction sites significantly. In general, ¹⁴N nuclear quadruple coupling constants and asymmetry parameter reveal a remarkable effect of NH₃ adsorption on electronic structure of the B₈₀.     

Theoretical prediction of proton and electron affinities,gas phase basicities,and ionization energies of sulfinamides

Structural Chemistry - Sulfinamides, as an asymmetric synthesizer, especially in drug synthesis, play critical roles in organic chemistry. In this study, the gas phase ion energetics data including...     

A simple graphical approach to predict local residue conformation using NMR chemical shifts and density functional theory

The dependency of amino acid chemical shifts on φ and ψ torsion angle is, independently, studied using a five‐residue fragment of ubiquitin and ONIOM(DFT:HF) approach. The variation of absolute deviation of ¹³C^α chemical shifts relative to φ dihedral angle is specifically dependent on secondary structure of protein not on amino acid type and fragment sequence. This dependency is observed neither on any of ¹³C^β, and ¹H^α chemical shifts nor on the variation of absolute deviation of ¹³C^α chemical shifts relative to ψ dihedral angle. The ¹³C^α absolute deviation chemical shifts (ADCC) plots are found as a suitable and simple tool to predict secondary structure of protein with no requirement of highly accurate calculations, priori knowledge of protein structure and structural refinement. Comparison of Full‐DFT and ONIOM(DFT:HF) approaches illustrates that the trend of ¹³C^α ADCC plots are independent of computational method but not of basis set valence shell type. © 2016 Wiley Periodicals, Inc.