N-Heterocyclic Carbenes Reduce and Functionalize Copper Oxide Surfaces in One Pot

Benzimidazolium hydrogen carbonate salts have been shown to act as N-heterocyclic carbene precursors, which can remove oxide from copper oxide surfaces and functionalize the resulting metallic surfaces in a single pot. Both the surfaces and the etching products were fully characterized by spectroscopic methods. Analysis of surfaces before and after NHC treatment by X-ray photoelectron spectroscopy demonstrates the complete removal of copper(II) oxide. By using ¹³C-labelling, we determined that the products of this transformation include a cyclic urea, a ring-opened formamide and a bis-carbene copper(I) complex. These results illustrate the potential of NHCs to functionalize a much broader class of metals, including those prone to oxidation, greatly facilitating the preparation of NHC-based films on metals other than gold.     

Chemisorption and reactivity of furan on Pd{111}

XPS, HREELS, ARUPS and Δø data show that furan chemisorbs non-dissociatively on Pd{111} at 175 K, the molecular plane being significantly tilted with respect to the surface normal. Bonding involves both the oxygen lone pair and significant π interaction with the substrate. The degree of decomposition that accompanies molecular desorption is a strong function of coverage: 40% of the adsorbate desorbs molecularly from the saturated monolayer. Decomposition occurs via decarbonylation to yield CO_a and H_a followed by desorption rate limited loss of H₂ and CO. It seems probable that an adsorbed C₃H₃ species formed during this process undergoes subsequent stepwise dehydrogenation ultimately yielding H₂ and C_a.     

Area-interaction point processes

We introduce a new Markov point process that exhibits a range of clustered, random, and ordered patterns according to the value of a scalar parameter. In contrast to pairwise interaction processes, this model has interaction terms of all orders. The likelihood is closely related to the empty space functionF, paralleling the relation between the Strauss process and Ripley'sK-function. We show that, in complete analogy with pairwise interaction processes, the pseudolikelihood equations for this model are a special case of the Takacs-Fiksel method, and our model is the limit of a sequence of auto-logistic lattice processes.     

Easy conjugate additions to Δ1(9)-octal-2-one and its 10-methyl derivative

Conjugate additions of lithiated arylacetonitriles to 2-octalones give good yields of $\text{cis}$-decalone products. The stereochemistry of the adducts is determined by ¹³C NMR spectroscopy.     

Carbon-13 nuclear magnetic resonance spectroscopy of naturally-occurring substances- LVII Triterpenes related to lupane and hopane

The ¹³C NMR spectra of lupeol and related triterpenes were recorded and all carbon shifts assigned. Their analysis aided in the shift assignment of the structurally related hopane-like triterpenes.