Tuning the surface state dimensionality of Cu nanostripes

Stepped Cu nanostripes with varying terrace widths are self-assembled during Ag-induced periodic faceting of vicinal Cu(111). By changing Ag coverage the average terrace size within individual Cu stripes is readily tuned, making it possible to select the one-dimensional or two-dimensional character of surface states. Furthermore, the average terrace size can be smoothly switched from 10 to 30 A, thereby tracking the transition from step-lattice, quasi-two-dimensional umklapp bands to terrace-confined one-dimensional quantum well states.     

Development and Application of new C30-Modified TLC Plates

JPC – Journal of Planar Chromatography – Modern TLC - This paper reports the efficiency of the C30 phase for HPLC and TLC separation of a mixture of tocopherol homologs and...     

Comparative molecular dynamics and Monte Carlo study of statistical properties for coarse-grained heteropolymers

Employing a simple hydrophobic-polar heteropolymer model, we compare thermodynamic quantities obtained from Andersen and Nosé-Hoover molecular dynamics as well as replica-exchange Monte Carlo methods. We find qualitative correspondence in the results, but serious quantitative differences using the Nosé-Hoover chain thermostat. For analyzing the deviations, we study different parameterizations of the Nosé-Hoover chain thermostat. Autocorrelations from molecular dynamics and Metropolis Monte Carlo runs are also investigated.     

Graft polymerization of styrene initiated by covalently bonded peroxide groups on silica

The graft polymerization of styrene initiated by immobilized peroxide groups was investigated. Three different types of modification reactions were used to introduce peroxide groups which are directly attached onto the surface of two different silica supports. Silanol groups were chlorinated using thionyl chloride or tetrachlorosilane. In another reaction pathway 1,3,5-benzenetricarbonyl chloride enabled the introduction of free acid chloride residues bonded onto the surface of silica. tert-Butyl hydroperoxide (TBHP) was used to transform the chlorosilyl and the acid chloride groups into peroxide residues. In a further reaction step the covalently bonded peroxides initiated the polymerization of styrene to form grafted polystyrene directly attached onto the silica support. Solid-state 13C CP/MAS NMR spectroscopy, and thermogravimetric and scanning electron microscope measurements enabled a clear structure and property elucidation of the different bonded phases. The highest amount of grafted polystyrene was achieved employing the acid chloride synthesis pathway with silica-gel, whereas modification of spherical silica only led to minor amounts of grafted polymer. The results contribute to the evolving need to understand particle surface modifications and may have positive impact on development of new HPLC stationary phases for improved elutant resolution.     

Measurement of textile materials thermal properties

The determination of thermal properties of textile materials is difficult and subject to errors. Here we used two experimental methods. A PhotoPyroElectric method (Front PPE configuration with a modulated heat flow imposed on the surface of the sensor) and a commercial device (Alambeta) based the hot plate method. Two theorical approaches for the latter device were used. We tested the two methods on different textile materials (cotton, modal, wool and spacer). We observe good agreement between thermal conductivities measured with the two methods.