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121.
Fluorophosphate glasses of composition, P2O5 + K2O + KF + MO + Al2O3 + xEu2O3 (M = Mg, Sr and Ba; x = 0.01, 0.05, 0.1, 1.0, 2.0, 4.0 and 6.0 mol%) were prepared and characterized their optical properties. Crystal-field (CF) analysis revealed a relatively weak CF strength around Eu3+ ions in the Ba based fluorophosphate glasses. The Judd-Ofelt parameters have been estimated from the oscillator strengths of 7F0 → 5D2, 7F0 → 5D4 and 7F0 → 5L6 absorption transitions of Eu3+ ions and were used to evaluate the radiative properties of the 5D0 → 7FJ (J = 0-4) transitions. Considerable variation has been observed in the relative intensity ratio of 5D0 → 7F2 to 5D0 → 7F1 transitions of Eu3+ ions due to change in the alkaline earth metal ions. The decay of the 5D0 level shows single exponential and less sensitive to Eu3+ ions concentration as well as MgO/SrO/BaO modifiers. 相似文献
122.
The dynamics of a semi-flexible sheet or tethered membrane in a solvent is studied using the method of stochastic rotation
dynamics. Hydrodynamic interactions between different parts of the sheet are naturally included in this method. We confirm
the scaling law for the radius of gyration versus sheet size predicted for a self-avoiding tethered membrane. The mean-square displacement shows both sub-diffusive and diffusive
behavior similar to linear polymers. In the intermediate scattering function the sub-diffusive behavior appears as stretched
exponential which we reproduce in our simulations. Thereby, we confirm an early prediction between the roughness and the sub-diffusion
exponent derived from Zimm dynamics (E. Frey, D.R. Nelson, J. Phys. I 1, 1715 (1991)). Finally, we show that the diffusion coefficient of the square sheet is inversely proportional to the edge
length of the sheet again in good agreement with theoretical predictions. 相似文献
123.
The dynamics of a semi-flexible sheet or tethered membrane in a solvent is studied using the method of stochastic rotation dynamics. Hydrodynamic interactions between different parts of the sheet are naturally included in this method. We confirm the scaling law for the radius of gyration versus sheet size predicted for a self-avoiding tethered membrane. The mean-square displacement shows both sub-diffusive and diffusive behavior similar to linear polymers. In the intermediate scattering function the sub-diffusive behavior appears as stretched exponential which we reproduce in our simulations. Thereby, we confirm an early prediction between the roughness and the sub-diffusion exponent derived from Zimm dynamics (E. Frey, D.R. Nelson, J. Phys. I 1, 1715 (1991)). Finally, we show that the diffusion coefficient of the square sheet is inversely proportional to the edge length of the sheet again in good agreement with theoretical predictions. 相似文献
124.
The principal refractive indices of L-lysine monohydrochloride dihydrate (L-LMHCl) single crystal for different wavelengths were measured by minimum deviation method at room temperature. The experimental values of refractive indices fit well with the theoretical Cauchy's equations. The birefringence and the crossing angle between the optical axes were calculated. The parameters of Sellmeier's single term dispersion equation were determined by least square method. A simple interferometric technique was used to observe the interference patterns along the optic plane and to qualitatively analyze the optical homogeneity of the grown crystal. The nonlinear refractive index (n2) and nonlinear absorption coefficient (β) were also determined using Z-scan technique. The piezoelectric resonance in dielectric dispersions was observed at room temperature. 相似文献
125.
The dc and ac electrical transport property of Polyvinyl Alcohol-Multiwall Carbon Nanotubes (PVA-MWNT) composites has been investigated within a temperature range and in the frequency range 20Hz-1MHz. The temperature variation of dc conductivity gives the presence of two different activation energies. The dielectric properties of the samples have been explained in terms of electric modulus vector.The dielectric relaxation has been explained in terms of interfacial polarization occurring in between the insulating PVA matrix and MWNT conductive filler. The variation of the relaxation time with temperature also indicates the presence of two different activation energies. 相似文献
126.
127.
In this paper, an enantioselective synthesis of diplodialide-B has been described. To accomplish this target, a combination of regioselective ring opening of the chiral epoxide, Jacobsen hydrolytic kinetic resolution and Yamaguchi macrolactonization were used as the key steps. 相似文献
128.
129.
Indhumathi Kulandhaisamy Dinesh Babu Rajendran Malathi Kanagasabai Gunasekaran Gurusamy Balaji Moorthy Jithila V. George 《Waves in Random and Complex Media》2017,27(1):38-46
In this paper, an analog multiband phase shifter using slotline configuration is proposed. To implement the design, a pair of modified Split Ring Resonator (SRR) is employed. The periodic property of SRR provides multiband characteristics, whether the coupling slot gives the phase variations over the bands. The operation is well explained with an equivalent circuit model and its characteristics have been studied both in simulation and measurement. The prototype operates in 1.77–2.16, 3.5–3.97, 5.08–5.33, 6.43–6.93, and 8.01–8.59 GHz frequency bands which can be utilized for GSM, GPS, WLAN, C-band, and X-band applications, respectively. 相似文献
130.