New fluorinated polysiloxanes containing an ester function in the spacer. I. Synthesis and characterization

Unsaturated perfluoroalkyl esters derived from undecylenic acid: CH₂?CH? (CH₂)₈? COO? CH₂? CH₂? R_F (with R_F?C₆F₁₃, 2a and R_F?C₈F₁₇, 2b ) and C₈F₁₇? (CH₂)₁₀? COO? CH₂? CH?CH₂, 2c were prepared with excellent yields. Their hydrosilylation by methylhydrodimethylsiloxane copolymers of various Si? H contents gives new fluorinated polysiloxanes which were examined by ¹H- and ¹³C-NMR, GPC, differential scanning calorimetry, and optical polarizing microscopy. Polymers derived from compounds 2a and 2b exhibit mesomorphic structures. © 1994 John Wiley & Sons, Inc.     

A New Practical Preparation of bis(Trimethylsilyl) Peroxide

Bis(trimethylsilyl) peroxide can be readily obtained by reaction of trimethylchlorosilane with the hexamethylenetetramine-hydrogene peroxide complex.     

Ionization spectrum transformation and compression of powerful femtosecond laser pulses in experiments on the propagation in gas-filled dielectric capillaries

The propagation of an intense (I≤10⁶ W/cm²) femtosecond laser radiation with a duration of ～100 fs through gas-filled dielectric capillaries was studied. The radiation with a power up to 0.2 TW propagates along the paths up to 20 cm with a transmission efficiency of ～45%. The beam transverse structure at the output is close to the capillary fundamental mode under gas-ionization conditions. The transformation of pulse spectrum was studied as a function of input intensity. It is demonstrated experimentally that the pulse is compressed to a duration of ～30 fs due to the compensation of ionization-induced self-phase modulation in a linear dispersive element at the capillary output.     

Luminescence and relaxed excited state origin in CsI:Pb crystals

Emission and excitation spectra, luminescence polarization and decay kinetics have been studied for CsI:Pb crystals in the 0.36-300 K temperature range. The origin of the excited states responsible for the optical characteristics has been discussed. It has been concluded that the doublet ≈3.70 eV absorption (excitation) band is caused by the electronic transitions into the Pb²⁺ triplet state split due to the presence of a cation vacancy near a Pb²⁺ ion, while the higher-energy bands are of the charge-transfer origin. Like in CsI:Tl, four emission bands of CsI:Pb have been found to belong to the main luminescence centres. Two emission bands, peaking at 3.1 and 2.6 eV, are suggested to arise from the triplet relaxed excited state of a Pb²⁺ ion. Two visible emission bands, peaking at 2.58 and 2.23 eV, are interpreted as the luminescence of an exciton localized near the Pb²⁺ ion.     

Tunable fiber Bragg gratings for application in tunable fiber lasers

The resonance wavelength of the fiber Bragg gratings (FBGs) is tuned using two methods. Tunable FBGs are used as the selecting elements in the cavities of tunable lasers. An ytterbium-doped fiber laser with a wavelength tuning range of 1063–1108 nm and an output power of 6 W, a Raman fiber laser with a wavelength tuning range of 1252–1303 nm and an output power of 3 W, and an erbium-doped fiber laser with a wavelength tuning range of 1530–1580 nm are realized, and their characteristics are studied.     

Distributed-feedback fiber laser with optical amplifier

A single-frequency all-fiber laser source operating at 1093 nm with an output power of more than 1 W is developed. A master oscillator-power amplifier configuration that comprises a distributed-feedback fiber laser and an ytterbium-doped fiber amplifier is implemented. Some aspects of the stimulated Brillouin scattering specific to active fiber are discussed.     

Luminescence characteristics of Pb centres in undoped and Ce-doped Lu3Al5O12 single-crystalline films and Pb→Ce energy transfer processes

At 4.2-350 K, the steady-state and time-resolved emission and excitation spectra and luminescence decay kinetics were studied under excitation in the 2.5-15 eV energy range for the undoped and Ce³⁺-doped Lu₃Al₅O₁₂ (LuAG) single-crystalline films grown by liquid phase epitaxy method from the PbO-based flux. The spectral bands arising from the single Pb²⁺-based centres were identified. The processes of energy transfer from the host lattice to Pb²⁺ and Ce³⁺ ions and from Pb²⁺ to Ce³⁺ ions were investigated. Competition between Pb²⁺ and Ce³⁺ ions in the processes of energy transfer from the LuAG crystal lattice was evidenced especially in the exciton absorption region. Due to overlap of the 3.61 eV emission band of Pb²⁺ centres with the 3.6 eV absorption band of Ce³⁺ centres, an effective nonradiative energy transfer from Pb²⁺ ions to Ce³⁺ ions takes place, resulting in the appearance of slower component in the luminescence decay kinetics of Ce³⁺ centres and decrease of the Ce³⁺-related luminescence intensity.     

Ferrocenylalkyl azoles: bioactivity,synthesis, structure

The toxicity of ferrocenylethyl benzotriazole ( 1 ) and other ferrocene compounds including ferrocenylmethyl benzimidazoles ( 4,5,6,11 ), ferricenium salts ( 3,9,10 ) and ferrocenylmethyl adenine ( 7 ), was studied. All ferrocene complexes under investigation showed low or medium toxicities. On the basis of an earlier model of chemical carcinogenesis, the antitumor activity of ferrocenylalkyl azoles 1, 8 and ferricenium salts 9, 10 was studied in vivo in the so‐called sub‐capsular test on human tumors. This effectiveness was compared with that of cisplatin. A series of ferrocenylalkyl azoles were synthesized by interacting azoles either with α‐hydroxyalkyl ferrocenes FcC(OH)R₁R₂ in organic solvent in the presence of aqueous HBF₄ in quantitative yields or with trimethyl(aminomethyl)ferrocene iodide in an aqueous‐basic medium in good yields. The X‐ray determinations of molecular and crystal structures of α‐(1‐benzotriazolyl)ethylferrocene ( 1 ) and α‐(1‐naphthatriazolyl)ethylferrocene ( 12 ) were performed. Copyright © 2008 John Wiley & Sons, Ltd.     

Finite-element simulation of contact interaction with the use of concepts of contact pseudomedium mechanics

In the present paper, we analyze an algorithm for solving problems of elastic and elastoplastic contact between rigid deformable bodies taking into account the presence of additional media with various properties in the contact region. These may be nonlinear properties of surface rough layers and films. To take into account the influence of such layers, the finite-element scheme uses contact finite elements with nonlinear properties. We describe an algorithm developed for solving problems with various types of nonlinearities. Using the example of experimental studies described in detail in [1, 2], we identify the nonlinear properties of contact finite elements. Several examples are used to demonstrate the algorithm operating capability.