全文获取类型
收费全文 | 342篇 |
免费 | 16篇 |
国内免费 | 1篇 |
专业分类
化学 | 267篇 |
晶体学 | 1篇 |
力学 | 17篇 |
数学 | 22篇 |
物理学 | 52篇 |
出版年
2023年 | 4篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 5篇 |
2019年 | 7篇 |
2018年 | 15篇 |
2017年 | 6篇 |
2016年 | 15篇 |
2015年 | 12篇 |
2014年 | 13篇 |
2013年 | 29篇 |
2012年 | 41篇 |
2011年 | 34篇 |
2010年 | 22篇 |
2009年 | 15篇 |
2008年 | 14篇 |
2007年 | 17篇 |
2006年 | 19篇 |
2005年 | 15篇 |
2004年 | 18篇 |
2003年 | 15篇 |
2002年 | 11篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1994年 | 1篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有359条查询结果,搜索用时 15 毫秒
131.
132.
High efficiency grating-based diffractive elements were previously proposed in order to generate desired arrays of various optical beams. The elements enable us to generate a diversity of arrays of optical beams in desired shapes, so that the arrays produced by the method are homogeneous, uniform and lacking of unwanted higher diffraction orders. In this technique a modulated grating is used to restructure Fresnel zone plate or zone plate-based elements to get modified grating-based elements. To examine the method, a variety of rectangular arrays of optical spots and annular beams are created by the ordinary and modified elements. It is shown that the arrays generated by the modified elements are much more uniform than the same arrays produced by the ordinary ones. In addition to the uniformity of the arrays, the unwanted higher diffraction orders are also totally eliminated. This article exploits simulation and experimental studies in order to demonstrate the functionality of the proposed technique as a multi functional high-efficiency beam shaping. 相似文献
133.
134.
N. L. Babak I. M. Gella A. N. Semenenko S. V. Shishkina O. V. Shishkin V. I. Musatov V. V. Lipson 《Russian Journal of Organic Chemistry》2014,50(7):1048-1055
Crotonization of allobetulone with aromatic and heteroaromatic aldehydes gave a number of new α,β-unsaturated ketones of the lupane series, and their steric structure was determined by X-ray analysis of (E)-4-[(3-oxoallobetulan-2-ylidene)methyl]benzonitrile as an example. 相似文献
135.
136.
137.
Takehiro YamagishiTakanori Kusano Babak KaboudinTsutomu Yokomatsu Chiseko SakumaShiroshi Shibuya 《Tetrahedron》2003,59(6):767-772
The diastereoselective synthesis of β-substituted α-hydroxyphosphinates was achieved by hydrophosphinylation of α-oxy aldehydes and α-amino aldehydes with ethyl allylphosphinate catalyzed by lithium phenoxide. 相似文献
138.
A separation of bis(α-hydroxyalkyl) phosphinic acid diastereoisomers is described. A novel method for the determination stereochemistry of bis(α-hydroxyalkyl) phosphinic acid diastereoisomers has been developed. The stereochemistry of one diastereoisomer was confirmed after converting to the corresponding methyl ester using trimethyl orthoformate. 相似文献
139.
A mild, organometallic alternative to ozonolysis utilizing oxone and OsO(4) is presented. This is a direct oxidation of olefins via the carbon-carbon cleavage of an osmate ester by the action of oxone. Twenty-four different olefins were converted to their corresponding ketones or carboxylic acids in high yields (>80%). Free alcohols, acetate- and benzyl-protected alcohols, and 1,2-diols were stable under these conditions. This method should be applicable for traditional organic synthesis. 相似文献
140.
A microscale protocol for determination of absolute configurations of 2,3-epoxy alcohols is described. 2,3-Disubstituted (cis and trans), 2,2-disubstituted, 2,2,3-trisubstituted, and 2,3,3-trisubstituted epoxy alcohols rendered prominent ECCD signals upon complexing with a Lewis acidic porphyrin tweezer and consequently provide straightforward assignment of chirality for epoxy alcohols. This method proved to be rapid, simple, sensitive, and reliable for the class of molecules listed above. 相似文献