Synthesis and Characterization of Surfactant-encapsulated Polyoxoanions: [(C_nH_(2n+1))_2N(CH_3)_2]_(12)[Mo_(36)(NO)_4O_(108)(H)2O)_(16)] (n=12, 18)

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A Novel Adaptive Predictor for Chaotic Time Series

Many chaotic time series show non-Gaussian distribution, and non-Gaussianity can be characterized not only by higher-order cumulants but also by negative entropy. Since negative entropy can be accurately approximated by some special non-polynomial functions, which also can form an orthogonal system, these functions are used to construct an adaptive predictor to replace higher-order cumulants. Simulation shows the algorithm performs well for different chaotic systems.     

基于观测器的模糊时滞系统指数稳定的一种设计方法

研究了一类模糊时滞系统的指数稳定问题.首先利用T-S模型对非线性不确定性时滞系统进行建模,在此基础上设计了基于观测器的模糊状态反馈控制器,通过巧妙选取Lyapunov函数给出了模糊闭环时滞系统的条件及稳定裕度且模糊反馈增益和模糊观测器增益可通过求解线性矩阵不等式获得.     

Covalent Organic Frameworks Based Single-site Electrocatalysts for Oxygen Reduction Reaction

Single site catalysts(SSCs) are a new type of heterogeneous catalysts formed by isolated metal atoms supported on kinds of substrates. SSCs have shown great potential for energy conversion and storage in recent years, especially for oxygen reduction reactions(ORR). Typically, SSCs are confined on the substrate by strong chemical interactions, such as coordination bonds. Therefore, the surface chemical environment and porous properties of the supports are crucial to the performance of SSCs. In recent years, COFs have become excellent candidates for preparing SSCs as they can precisely assemble monomers into highly ordered crystalline porous materials with a fine structure and definite components. In this review, we not only summarize the characteristics and advantages of COFs based SSCs, but also highlight the applications of COFs constructed from different single active sites for ORR in recent years. Finally, challenges in practical application, feasible strategies and perspectives are proposed for the of COFs based SSCs.     

地震作用多层砌体房屋横墙抗剪分析

分析了在地震作用下，多层砌体刚性楼面的房屋中，490mm,370mm和240mm的抗剪横墙在地震荷载作用下哪一道横墙先破坏取决于墙体负荷宽度，由此，提出了一种横墙抗震验算的直接判别方法，供设计人员参考使用。     

叶酸修饰的AgInS2量子点在体外癌细胞成像上的应用

成功制备出高品质的三元AgInS₂量子点。通过配体交换法将油溶性AgInS₂量子点转为水溶性量子点, 通过dBSA修饰水溶性量子点形成配位体壳, 使量子点具有更好的稳定性(4周)。从透射电子显微镜(TEM)观察到dBSA修饰后的量子点的粒径增加, 分散性较好, 并且在可见光区域有明显的光致发光。用叶酸对dBSA-MPA量子点进行修饰, 并通过傅立叶变换红外光谱进行了验证。将得到的FA-dBSA-MPA纳米复合材料应用于能与叶酸受体特异性结合的乳腺癌细胞中, 并在荧光倒置显微镜中检测到量子点成功对乳腺癌细胞进行了标记。与dBSA-MPA量子点相比, 表面被叶酸修饰后的量子点与癌细胞的结合效率显著提高。     

基于曲梁弹性理论的弯曲覆岩变形及应力分析

引入适用于极坐标下曲梁的位移函数,通过理论分析得出用位移函数表示的曲梁控制方程和位移分量、应力分量.在此基础上,采用差分原理给出曲梁控制方程、位移分量和应力分量的差分代数方程.最后,采用数值计算方法,分析了煤层开采后弯曲覆岩的位移和应力分布特征,结果表明:1)煤层开采后弯曲覆岩产生下沉变形;弯曲岩层环向位移既有拉伸也有压缩.2)离开切眼不远处径向应力将达到峰值,径向应力由内边界向外逐渐增大;工作面后方不远处环向应力将达到峰值,环向应力较容易引起压缩破断;离开切眼不远处剪应力将达到峰值,对于小角度截面上的剪应力由内边界向外逐渐增大.研究结果为煤矿工程提供了科学依据与参考.     

基于AGV的智能仓库系统订单分批问题研究

研究了基于自动引导小车(AGV)的“货到人”智能仓库订单分批拣选问题, 在同时考虑工作人员拣选商品成本和AGV搬运货架成本的前提下, 建立了以总成本极小化为目标函数的订单分批问题整数规划模型。根据订单中包含的商品信息和商品所在的货架信息构建了描述订单之间关系的加权相似度指标, 分析了加权相似度与总拣选成本之间的正相关关系。基于订单之间的加权相似度设计了求解模型的贪婪算法。利用具体算例进行模拟计算, 分析了加权系数的变化对订单分批结果的影响, 以及加权系数λ的取值与工作人员拣取一件商品的成本c₁和AGV搬运一次货架的成本c₂之间的关系, 得到了贪婪算法中加权系数λ的确定方法。进一步分析了贪婪算法的计算时间和计算效果, 结果显示, 通过适当选取加权系数, 利用贪婪算法可以在短时间内得到订单分批问题的近似最优解;对于小规模算例, 贪婪算法在最坏情况下近似比不超过1.35。利用本文的模型和算法进行订单分批, 兼顾了工作人员拣取商品的成本和AGV搬运货架的成本, 可以有效提高订单拣选效率, 降低订单拣选总成本。     

Weighted estimates for bilinear square functions with non-smooth kernels and commutators

Under weaker conditions on the kernel functions,we discuss the boundedness of bilinear square functions associated with non-smooth kernels on the product of weighted Lebesgue spaces.Moreover,we investigate the weighted boundedness of the commutators of bilinear square functions(with symbols which are BMO functions and their weighted version,respectively)on the product of Lebesgue spaces.As an application,we deduce the corresponding boundedness of bilinear Marcinkiewicz integrals and bilinear Littlewood-Paley^-functions.     

具有稳定自治动态的一般非线性系统的镇定问题

针对一般非线性系统,在它的自治动态是稳定的条件下,应用Lyapunov方法获得它可全局渐近稳定的充分条件,同时在系统函数是解析的情况下,基于输出反馈控制律,构造出了类Luenberger观测器,使得闭环系统的平衡点全局渐近稳定.