Two mechanisms of the interaction between atoms and solids

The chemical action of atoms on solids can be due to both direct reactions with the structural units of solids and heterogeneous recombination energy transfer to the crystal lattice.

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The Crystal Structures of Rubidium and 4-Amino-1,2,4-Triazolium Tetrafluoroantimonates(III)

The crystal structures of complex antimony(III) fluorides RbSbF₄ (I) and (C₂N₄H₅)SbF₄ (II) were determined. The crystals of I and II are monoclinic; for I: a = 4.628(1) Å, b = 6.167(1) Å, c = 7.922(1) Å, = 100.582(3)°, V = 222.24(7) ų, Z = 2, (calcd.) = 4.23 g/cm³, (exp.) = 4.25 g/cm³, F(000) = 248, space group P2₁/m, R = 0.0395; for II: a = 4.678(1) Å, b = 7.339(4) Å, c = 10.185(1) Å, = 90.88(2)°, V = 349.6(2) ų, Z = 2, (calcd.) = 2.69 g/cm³, (exp.) = 2.70 g/cm³, F(000) = 264, space group P2₁. The structure of I is formed by Rb⁺ cations and [SbF₄] ^n– _n anionic chains composed of SbF₅E octahedra with two bridging fluorine atoms. The structure of IIis formed by (C₂N₄H₅)⁺ cations and isolated [SbF₄]^– anions in which the antimony polyhedra are SbF₄E trigonal bipyramids. The relationship between the crystal structures and electrophysical and biological properties of single-charged cation tetrafluoroantimonates(III) was studied.     

“Poisson” models of random fields with applications in transport theory

A comparative analysis of various models of exponentially correlated random fields associated with Poisson point ensembles is given. Algorithms for the modeling of radiative transfer in random media of this type are considered. An asymptotic estimate for the particle passage probability is constructed assuming that the flow of trajectory intersections with domains of constant random density is Poisson distributed.     

Manifestation of a semimetallic state in cyclotron resonance in low-symmetry HgTe-based quantum wells

Cyclotron-resonance measurements in 21-nm-thick HgTe/CdHgTe quantum wells of different crystallographic orientations have been performed. It has been found that, in contrast to the structures with the (001) orientation of the quantum-well plane, (013)-oriented quantum wells are semimetallic and their absorption spectra exhibit both electron and hole cyclotron-resonance lines. The simultaneous presence of the two types of charge carriers originates from an overlap between the upper heavy-hole quantum-confinement subbands hh1 and hh2. This overlap is caused by the strong interaction of these subbands with the Dyakonov-Khaetskii interface state. Calculations carried out using the eight-band kp-Hamiltonian indicate that, for known values of the band-structure parameters, the overlap between hh2 and hh1 subbands does not occur; this result is in agreement with the cyclotron-resonance data for (001)-oriented structures. The enhanced interaction between heavy-hole and interface states owing to the existence of steps at low-symmetry heterointerfaces may be the mechanism responsible for the appearance of an overlap between subbands in HgTe quantum wells with orientation different from (001).     

Periodical structure formation on a magnesium and aluminum surface under high power ion beam irradiation of nanosecond duration

The formation of periodical structures, and also, micro- and nanoparticles on a polycrystalline magnesium and aluminum surface under high power proton-carbon beam irradiation has been investigated. The spatial parameters of these structures and particle sizes have been determined. The possible mechanisms for periodical structure formation have been considered.     

Biopolymer composites based on modified lignin and nanocellulose

New composite lignocellulose materials were prepared using modified lignin and nanocellulose. The materials were studied by elemental and thermal gravimetric analysis, and their tensile tests were performed. The results obtained show that addition of nanocellulose to modified lignin makes possible its use as filler in paper production.     

Some remarks on the efficient algorithms of numerical statistical simulation

Some numerical algorithms for the simulation of random variables and functions, as well as for parametrical numerical statistical analysis are considered. Specifications and explanations of the algorithms important for practical purposes are given.