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Neil S. Keddie Geert Bultynck Tomas Luyten Alexandra M.Z. Slawin Stuart J. Conway 《Tetrahedron: Asymmetry》2009,20(6-8):857-866
The synthesis of d-myo-inositol 1,4,5-trisphosphate (InsP3) from methyl α-d-glucopyranose, via a type 2 Ferrier rearrangement is reported. A key intermediate in this synthesis possesses orthogonal protecting groups at the 1-, 4- and 5-position, making it a versatile starting point for the synthesis of unnatural InsP3 derivatives. Biological evaluation of the synthetic InsP3 demonstrates that this compound evokes selective Ca2+ release via activation of InsP3 receptors. 相似文献
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Amanda D. French Hannah M. Ashbaugh Gary Steinmetz Melanie Barnes Warren C. Conway David M. Klein 《International journal of environmental analytical chemistry》2017,97(6):499-507
The S.M.A.R.T. (small mass, affordable, rapid, transfer-less) digestion method was developed to determine heavy metal concentrations in small sample masses. The S.M.A.R.T. digestion method is a hot water bath digestion where sample digestion and dilution are performed in the original sample tube. This method is faster than the typical methods used and reduces potential sources of error. Masses as small as 0.01 g have been digested and analysed using this method. The preparation and digestion time is reduced from 10 h to less than 4 h. Acid volumes are reduced from millilitres to microlitres and the only disposable supplies needed are sample tubes and pipette tips. Method accuracy was determined by digesting seven replicates of two standard reference materials using the S.M.A.R.T. method and analysing samples by inductively coupled plasma mass spectrometry. The S.M.A.R.T. digestion method was found to provide excellent recoveries for Al (76 ± 2.7%), Mn (99 ± 11%), Co (92 ± 17%), Ni (93 ± 28%), Cu (109 ± 33%), Zn (97 ± 7.1%), As (108 ± 20%), Sr (90 ± 12%), Mo (84 ± 23%), Ag (91 ± 1.8%), Cd (95 ± 6.2%), Sn (139 ± 52%) and Pb (95 ± 22%). This study has successfully developed an efficient and reproducible digestion method for heavy metal determination in limited biomass samples. 相似文献
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We prove a no-triplets theorem for spin 1 particles, which implies a strengthened form of the no-cloning theorem. 相似文献
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Eugene Y. Cheung Kenneth D.M. Harris Barbara R. Conway 《Journal of solid state chemistry》2007,180(3):1068-1075
We report the formation and structural properties of co-crystals containing gemfibrozil and hydroxy derivatives of t-butylamine H2NC(CH3)3−n(CH2OH)n, with n=0, 1, 2 and 3. In each case, a 1:1 co-crystal is formed, with transfer of a proton from the carboxylic acid group of gemfibrozil to the amino group of the t-butylamine derivative. All of the co-crystal materials prepared are polycrystalline powders, and do not contain single crystals of suitable size and/or quality for single crystal X-ray diffraction studies. Structure determination of these materials has been carried out directly from powder X-ray diffraction data, using the direct-space Genetic Algorithm technique for structure solution followed by Rietveld refinement. The structural chemistry of this series of co-crystal materials reveals well-defined structural trends within the first three members of the family (n=0, 1, 2), but significantly contrasting structural properties for the member with n=3. 相似文献
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John T. Conway 《Integral Transforms and Special Functions》2017,28(6):443-459
Integration formulas are derived for the three canonical Legendre elliptic integrals. These formulas are obtained from the differential equations satified by these elliptic integrals when the independent variable u is the argument of Jacobian elliptic function theory. This allows a limitless number of indefinite integrals with respect to the amplitude to be derived for these three elliptic integrals. Sample results are given, including the integrals derived from powers of the 12 Glaisher elliptic functions. New recurrence relations and integrals are also given for the 12 Glaisher elliptic functions. 相似文献
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John T. Conway 《Integral Transforms and Special Functions》2017,28(6):488-503
A method developed recently for obtaining indefinite integrals of functions obeying inhomogeneous second-order linear differential equations has been applied to obtain integrals with respect to the modulus of the complete elliptic integral of the third kind. A formula is derived which gives an integral involving the complete integral of the third kind for every known integral for the complete elliptic integral of the second kind. The formula requires only differentiation and can therefore be applied for any such integral, and it is applied here to almost all such integrals given in the literature. Some additional integrals are derived using the recurrence relations for the complete elliptic integrals. This gives a total of 27 integrals for the complete integral of the third kind, including the single integral given in the literature. Some typographical errors in a previous related paper are corrected. 相似文献
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The problem treated here is that of an isotropic body having a doubly periodic rectangular or triangular array of perfectly bonded circular elastic inclusions. The body is in tension or compression. This simulates a composite material wherein a relatively weak matrix is reinforced by stronger (and more rigid) fibers. Bond stresses for both rectangular and triangular arrays have been calculated using either boundary point matching or boundary point least squares techniques. Numerical results based on a plane strain analysis are given in graphical form. 相似文献