密环菌甲素晶体结构研究

密环菌甲素(C₂₄H₃₀O₆)属正交晶系,空间群为P2₁ 2₁ 2₁,晶胞参数为a=18.784(9)?,b=14.002(7)?,c=8.598(5)?,z=4,计算密度D_c=1.216g·cm^-1。使用菲利浦PW-1100四圆衍射仪收集衍射强度。该结构是在MULTAN-78求解失败以后,使用MULTAN-80,在正切修正时选择统 关键词：     

A STUDY OF THE CRYSTALLIZATION OF AMORPHOUS Cu60Zr40 ALLOY

The crystallization of the amorphous Cu₆₀Zr₄₀ alloy has been studied by differential scanning calorimetry (DSC), scanning Auger microprobe (SAM) and transmission electron microscopy (TEM). The DSC trace showed that the sample exhibited a glass transition at 750 K and a strong exothermic effect beginning from 782 K. An enrichment of the element Zr and significant oxygen contamination in a zone near the surface to a depth of about 10 nm were revealed by SAM in the analysis of surface competition and depth profiles of the Cu₆₀Zr₄₀ sample. Also, the change of concentration ratio of Ca to Zr in amorphous matrix at the clean Cu₆₀Zr₄₀ surface as a function of annealing temperature was examined in detail, and it was found that the concentration of Zr at the surface is slightly higher than that in the bulk until 780K and that the concentration ratio of Cu to Zr in matrix has an abrupt increase in the temperature range of 780-800K. The observations by high resolution TEM revealed the appearance of cluster-like regions of approximately 1.5-2.0 nm in size just before crystallization and they distributed randomly throughout the sample. This phenomenon is analogous to the results obtained using field ion microscopy (FIM) by the present authors. The microstructural changes of the sample daring heating show the gradual crystallization of the amorphous matrix.     

多层地基沉降的概率分析

近年来概率的方法在土工工程中的应用已越来越受到注意。本文讨论多层地基沉降估算中的不确定性问题。最终沉降的估算是以Terzaghi的一维固结理论为基础的。压缩比、再压缩比,先期固结压力和土层的厚度作为随机变量处理,随机变量的均值、方差和协方差采用一阶二次矩法求得,并用Lambe的关于东北试验堤的数据作了计算。在本例中,压缩层厚度的不确定性构成了估算的沉降值方差的主要部分。估算的沉降与实测的沉降相比,变异系数相当一致,而均值为实测的1.8倍,差别的原因可能与一维计算的模式不够精确有关。     

物理教育研究评估

科学的定性及定量评估方法是物理教育研究重要的研究手段.目前国际通用的教育评估测试,根据测试目标的不同,可分为多种类型:学习内容调查、学习态度调查和科学分析能力调查等.我们已将本文中介绍的部分评估测试应用于国际教育研究领域.     

美国物理教育研究进展

对美国物理教育研究领域的发展和现状作了总体的介绍.物理教育研究的内容是物理教育教学的理论和方法,对象是与物理教学相关的各个方面及其之间的关联,提出并采用了许多新的教学方法和教学模式,目的是提高教学质量、发现并解决物理教学中存在的问题和难题,激发学生学习物理的积极性,加深对物理概念的理解和掌握,并提高他们分析和解决科学问题的能力.     

6-NO_2-BTAMB与钴显色反应的研究与应用

研究了6-NO2-BTAMB与钴显色反应。实验表明,在pH6.2—7.4(CH2)6N4-HCl体系中,钴与试剂定量地形成稳定的蓝绿色络合物,表观摩尔吸光系数ε650=1.18×105L·mol-1.cm-1;钴浓度在0—6μg/10mL范围内符合比耳定律。用于VB12和钴分子筛中微量钴的测定,结果令人满意。     

川芎挥发油化学成分GC/MS分析

使用水蒸气蒸馏法提取川芎中的挥发油,利用气相色谱-质谱联用技术对川芎化学成分进行分离鉴定,采用色谱峰面积归一化法确定各成分的相对含量。分析结果表明,共分离出53种组分,鉴定了其中的34个组分,占挥发油组分总量的64.42%。     

A Scheme for Information Erasure in a Double-Well Potential

We design an experimental scheme to realize one-bit information erasure and restoring processes by considering an overdamped colloidal particle in a double-well optical trap, which is added by a controllable laser tweezer. Using the Monte Carlo method, we simulate numerically the Langevin equation to calculate the mean work spent during the entire process and validate the entropy production fluctuation theory. Our result shows that the distribution of entropy production becomes narrow with increasing temperature and becomes stationary, represents the diminishing extent of irreversibility.     

Fast-Scale and Slow-Scale Subharmonic Oscillation of Valley Current-Mode Controlled Buck Converter

A valley current-mode （VCM） controfled buck converter with current source load （CSI） has complex phenomena of fast-scale and slow-scale subharmonic oscillations. The piecewise smooth switching model of the VCM controlled buck converter with CSI is established. It is found that attractive regions of fast-scale and slow-scale subharmonic oscillations exist in the bifurcation diagram, and two tori exist in the corresponding Poincare mapping. The research results by time-domain simulation indicate that U-type subharmonic oscillation （SO） constituted by SO and frequency-reduced subharmonic oscillation （FSO） exists in inductor current, and sine-type SO constituted by fast scale and low scale exists in output voltage respectively. Experimental results are given to verify the analysis and simulation results.     

基于多维Gumbel Copula函数的投资组合VaR分析

基于目前国内有关Copula函数的实证研究主要是研究二种资产的相关性为主,文章根据Copula函数在构建反映随机变量实际分布与相关性的联合分布函数上具有的优势,首先利用GJR模型构建资产的边缘分布,接着利用多元阿基米德Copula函数族中的Gumbel Copula函数构建了反映多个资产收益实际分布和相关性的联合分布函数,并使用蒙特卡罗模拟技术,分析在不同置信度下的投资组合的最小风险价值(VaR)及其资产组成,实证说明根据文章提出的模型度量资产的风险,可以使投资者选择的资产更加稳健,同时也有利于投资者对投资组合整体风险进行分散和监管。