Dehydrogenation of propane on aluminoplatinum catalysts modified with Re,Zr, Sc,and Sn

The effect of addition of Re, Zr, Sc, and Sn on an aluminoplatinum catalyst in the reaction of dehydrogenation of propane was investigated. It was shown that addition of 0.2–0.5% Zr, Sc, or Re virtually does not alter the catalytic properties of the aluminoplatinum catalyst (APC); addition of 0.2% Sn increases the activity, selectivity, and stability of Pt/Al₂O₃. The amount of coke deposited on the APC after the first 5 min of work decreases by three times in the presence of Sn. The coke is more enriched with hydrogen than the other systems formed on the surface of Pt-Sn/Al₂O₃.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 765–771, April, 1991.     

Structural and spectroscopic study on imidazole-copper(II)-N-protected amino acid complexes. Crystal and molecular structure of tetrakis(imidazole)copper(II)bis(N-tosylvalinate)

A pink-red air-stable, crystalline compound of empirical formula [Cu(Im)₄(N-tsval)₂] (Im=imidazole; ts=4-toluenesulfonyl group, hereafter abbreviated as tosyl;N-tsval=N-tosylvalinate monoanion) was synthesized and characterized by means of structural and spectroscopic measurements. The crystal structure of the compound was determined from three-dimensional diffractometer data. The crystals are monoclinic, space groupC2/c, a=18.952 (5),b=12.372 (2),c=17.594 (3) Å,=93.77 (2)°,Z=4. The structure was solved by the heavy-atom method and refined through least-squares calculations toR=0.035 for 2284 observed reflections. The coordination about the copper atom is elongated octahedral, with four imidazole molecules as equatorial ligands and two sulfonic oxygens in axial positions.     

Beryllium diffusion across GaAs/(Al,Ga)As heterojunctions and GaAs/AlAs superlattices during MBE growth

Beryllium diffusion during MBE growth of (Al, Ga)As layers, (Al, Ga)As/GaAs heterojunctions and GaAs/AlAs superlattices has been studied by electrochemical C-V and secondary ion mass spectrometry (SIMS) concentration profiling, in conjunction with transmission electron microscopy. Diffusion times were comparatively short since they were limited to part of the growth sequence, so non-equilibrium effects had a significant influence. The results are consistent with an interstitial-substitutional mechanism in which lattice site incorporation becomes more difficult with increasing band gap enthalpy. Incorporation involves a kick-out reaction which leads to the observed disordering of the superlattices.     

Selecting the duration of excitation pulses for an electroluminescent thin-film matrix

The factors influencing the optimum selection of the excitation pulse width of thin-film electroluminescent devices is examined. It is shown that to excite an individual cell, a pulse width of 5–7 sec is sufficient, but to excite the matrix, the pulse width is determined by the independence of the conducting layer and the dimensions of the matrix. Formulas are cited for engineering calculations of the required pulse width.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 59–62, December, 1987.     

Kinetics of photoconductivity in a semiconductor under strong interband optical excitation (possible stochasticity)

Stationary states and the kinetics of change carriers are studied in an almost intrinsic semiconductor containing deep levels of one kind and subjected to exposure under photon energy greater than the forbidden bandwidth. The exposure intensity is assumed sufficiently large, such that the concentration of the photoexcited charge carriers would exceed equilibrium significantly. Taken into account are both the charge carrier heating by the light and the dependence of the forbidden bandwidth on the electron and hole concentration and temperature. The conditions are mentioned for which stochastic or periodic electron and hole temperature and concentration self-oscillations should occur in the specimen.Deceased.Translated from Izvestiya Vysshikh Uchebynykh Zavedenii, Fizika, No. 6, pp. 87–95, June, 1987.     

Electron emission from Al,Pt, Ag,and Au surfaces under the action of resonant photons with λ=2537 and 1850 Å

An original variant of an electronic device is described, which can be used for gamma-process selection under ionized gas conditions. The device is based on a Hanley and Schaffernicht electron gun. Selection of photons and metastable atoms is performed by a quartz tube located in axial symmetry with the primary electron gun. The desired signal is measured from the flow of secondary electrons emitted from Al, Pt, Ag, and Au surfaces under the action of resonant photons radiated from the levels Hg(6³P₁) and Hg(6¹P₁). For =2537 Å the following values were obtained for _ph 9.1, 3.8, 1.1, 0.25. Analogous values of _ph for =1850 Å were equal to 45.5, 10.8, 6.5, 3.2. The _ph values are in units of 10^–4.Translated from Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 68–74, December, 1987.     

Some inequalities for partial orders

We establish some inequalities connecting natural parameters of a partial order P. For example, if every interval [a,b] contains at most maximal chains, if some antichain has cardinality v, and if there are ₁ chains whose union is cofinal and coinitial in P, then the chain decomposition number for P is ₁v (Theorem 2.2), and the inequality is sharp in a certain sense (Section 3).This paper was written while the authors were visitors at the Laboratoire d'algèbre ordinale, Département de Mathématiques, Université Claude Bernard, Lyon 1, France.Research supported by NSERC grant # A5198.     

Accounting for kinematic inhomogeneity in calculations of the subcritical deflection of laminar cylindrical shells

Conclusion The range of application of kinematically homogeneous models 2 and 3 for estimating the stress-strain state of a laminar shell is limited to the class of structures, whose stiffness characteristics of the individual layers differ by one-two orders of magnitude. In this case, the shell's subcritical deflection can be computed from simplest model 1 for relatively long shells (at least for L/R 2 in the cases under consideration). In other cases, the stressstrain state of a laminar shell should be evaluated on the basis of the fracture-line hypothesis (model 4). Consideration of transverse-reduction deformations of the shell's layers does not introduce significant corrections into the results of the computation.Translated from Mekhanika Kompozitnykh Materialov, No. 2, pp. 299–304, March–April, 1987.     

Refinements of Yu. V. Prokhorov's theorems on the asymptotic behavior of the binomial distribution

One finds the asymptotic behavior of the minimax distance between the binomial and its approximating normal or Poisson distributions, taken with the second terms of their expansions.Translated from Veroyatnostnye Raspredeleniya i Matematicheskaya Statistika, pp. 4–19, 1986.