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S. A. Gurevich T. A. Zaraiskaya S. G. Konnikov V. M. Mikushkin S. Yu. Nikonov A. A. Sitnikova S. E. Sysoev V. V. Khorenko V. V. Shnitov Yu. S. Gordeev 《Physics of the Solid State》1997,39(10):1691-1695
The concentration and chemical state of copper in the subsurface region of Cu/SiO2 composite films obtained by simultaneous magnetron sputtering from two sources (Cu and SiO2) are determined by x-ray photoelectron spectroscopy (XPS). It is established that copper in the as-grown film is primarily in the form of unoxidized atoms dispersed in a SiO2 matrix. Annealing of the film results in practically no oxidation, but about 70% of the copper atoms condense into metallic clusters with sizes below 10 Å in the subsurface region and about 50 Å in the bulk of the film. The changes in the binding energy of core electrons, and especially in the energies of Auger electrons, are so large in this situation that photoelectron and Auger spectroscopy are efficient methods for monitoring the chemical state of this composite material. 相似文献
24.
Ya. V. Fattakhov M. F. Galyautdinov T. N. L’vova I. B. Khaibullin 《Technical Physics》1997,42(12):1457-1459
The first results regarding the formation of a two-dimensional periodic structure of local melting regions on a silicon surface
upon pulsed light irradiation are presented. The conditions are established, and the mechanism of the formation of such structures
is discussed.
Zh. Tekh. Fiz. 67, 97–99 (December 1997) 相似文献
25.
A converging perturbation series that can be summed analytically has been obtained for intersubband transitions of electrons
coherently tunneling through the middle of a dimensionally quantized level in an asymmetric double-barrier structure in a
high-frequency terahertz electric field. The possibility of a substantial increase in tunneling current accompanied by either
absorption or emission of a photon has been demonstrated. The quantum efficiency of radiative transitions between dimensionally
quantized levels can be up to 66%.
Zh. éksp. Teor. Fiz. 112, 237–245 (July 1997) 相似文献
26.
Elizabeth S. Senger 《School science and mathematics》1997,97(3):139-149
Thirteen fifth graders were given an assignment to invent their own numeration systems, following a unit on bases and a look at early events in the history of numbers. The task presented options that required the students to make decisions (such as whether to use a base, which base to use, design of symbols, etc.), and build a rationale for the elements of their system. Analyses of patterns embedded in their invented systems provided an assessment of student understanding of numeration. The progression of more and less complex thinking related to the student's choice of a base other than 10, consistency of logic throughout the system in words and symbols, rationale for change, and perception of real life examples that would change if the system was adopted. The invention task is presented as another way to make connections. 相似文献
27.
I. M. Karnaukh A. S. Moskovkin G. V. Ponomarev 《Chemistry of Heterocyclic Compounds》1994,30(1):20-25
The mass spectral behavior of 1, 2-di (mesoetioporphyr inyl-1)- and 1, 2-di (mesooctaethylporphyrlnyl) ethanes and ethylenes, their Cu and Ni complexes, as well as Ni Schiff bases of 1, 2-di (mesooctaethylporphyrinyl)ethane complexes, under ionization by electron impact and bombardment by accelerated atoms, was studied. Peaks of molecular ions, for which the basic decomposition pathways were established on the basis of an analysis of the parent and daughter ions, were observed in the electron impact mass spectra of all these compounds.For Communication 29, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 24–29, January, 1994. 相似文献
28.
V. A. Samsonov L. B. Volodarskii V. L. Korolev G. Kh. Khisamutdinov 《Chemistry of Heterocyclic Compounds》1994,30(10):1243-1249
The reaction of 4-aminobenzofurazan with aryldiazonium salts leads to the formation of 4-amino-5-aryl-azobenzofurazans and 5-amino-2-aryl-4-nitroso-2H-benzotriazoles, products of the rearrangement of the initially formed 4-amino-7-(arylazo)benzofurazans. Oxidation of the benzofurazan as well as of the triazole derivatives gives 7-aryl-1,2,3-triazol[4,5-e]benzofurazans. The chemical properties of some of the compounds obtained have been investigated.Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1432–1438, October, 1994. Original article submitted July 25, 1994. 相似文献
29.
S. V. Litvinenko V. I. Savich L. D. Bobrovnik 《Chemistry of Heterocyclic Compounds》1994,30(3):340-344
We have developed a method for synthesis of N-(3-clzloro-2-quinoxalyl)sulfonamides by reaction of 2,3-dichloroquinoxaline with substituted arylsufonamides. Based on the IR spectra, we have established that in the solid state, the synthesized compounds exist in the form of amide tautomers. Alkylation of these compounds leads to N-metliyl-N-(3-chloro-2-quinoxalyl)arylsulfonamides. We demonstrate the possibility of nucleophilic substitution of the halogen upon treatment with O- and N-nucleophiles. The use of bifunctional nucleophiles leads to condensed quinoxalines.Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 30, No. 3, pp. 387–392, March, 1994. 相似文献
30.