Thickness induced transversal percolation in Pt-Al2O3 nano-composites

Investigations of thickness induced percolation process in Pt_ξ-Al₂O₃ nano-composites were carried out using grazing angle X-ray scattering. It is shown that the morphological characteristics of the nano-scaled Pt particles change significantly within the growth transversal direction. The initially non percolated two phases Pt_ξ-Al₂O₃ nano-composites show a noteworthy tendency to a percolated morphology with a gradual transversal increase of Pt nano-particles' average diameter in addition to the increase of the Pt nano-particles' poly-dispersity. This transversal morphological evolution is followed by a percolation phenomenon of the Pt nano-particles for a thickness of about ∼119.5 nm. This transversal morphological evolution seems to corroborate far too much with a columnar growth process.     

Spectroscopical diagnostics of alpha particles in the TSP tokamak

Reported to the 5th All-Union Conference on High-Temperature Plasma Diagnostics (June 18–22, 1990, Minsk).     

Friedel-Crafts alkylation of indoles with epoxides catalyzed by nanocrystalline titanium(IV) oxide

Friedel-Crafts alkylation of indoles with epoxides to afford 3-alkyl indole derivatives at room temperature with moderate to good yields and high regioselectivity using nanocrystalline titanium(IV) oxide catalyst is described.     

High-throughput concept for tailoring switchable mirrors

The optical properties, the switching kinetics and the lifetime of hydrogen switchable mirrors based on Mg-Ni alloys are determined with particular regard to the composition of the optically active metal-hydride layer in combination with the thickness of the catalytic capping layer. For this, a high-throughput experiment is introduced. The switching kinetics and the reversibility of switchable mirrors are strongly thickness dependent, though the details hinge on the fine structure of the clustered capping layer. Therefore, the kinetics is correlated with the surface structures of Pd on Mg_yNi_1−y as investigated by scanning tunneling microscopy. The results are explained by the so-called strong metal-support interaction (SMSI) state, characterized by a complete encapsulation of the capping layer clusters by oxidized species originating from the support. The SMSI-effect is less important with increasing Pd-layer thickness, and is suppressed by a good wetting of the Pd-clusters on the optically active film. This explains the critical thickness for the catalyzed hydrogen uptake observed in many switchable mirror systems. Moreover, the degradation of the kinetics during cycling is found to depend on the Pd-layer thickness and on the gas environment. Only films, covered with at least 15 nm Pd, show small degradation caused by the SMSI-effect. The SMSI-effect is partly reversible: after changing the gas environment from hydrogen to oxygen, the oxide on the Pd-clusters can be partly removed.     

Low-temperature reaction of magnesium with fluorobenzene

The low-temperature reaction of magnesium with fluorobenzene has been investigated. Joint condensation of magnesium and fluorobenzene vapours at low temperatures quantitatively gave phenylmagnesium fluoride in one stage.     

Two-spin-majority cellular automaton as a model of 2D cluster and interface growth

A new probabilistic cellular automaton model is introduced to simulate cluster and interface growth in two dimensions. The dynamics of this model is an extension to higher dimensions of the compact directed percolation studied by Essam. Numerical results indicate that the two-dimensional cluster coarsening and growth can be described only approximately by the conventional cluster size scaling due to a crossover in the growth mode. The spreading of the initially flat interface follows a purely diffusional,t ^1/2, law.