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991.
M. G. Voronkov E. A. Grebneva O. M. Trofimova A. I. Albanov N. F. Chernov N. N. Chipanina 《Russian Journal of General Chemistry》2006,76(12):1851-1853
Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy. 相似文献
992.
A. A. Lamberov E. V. Dement’eva Kh. Kh. Gil’manov S. R. Egorova N. V. Romanova 《Russian Journal of Applied Chemistry》2006,79(9):1453-1457
The effect of the paste molding pressure on the physicomechanical and texture characteristics of catalysts was studied. An indirect criterion is suggested to evaluate the molding pressure in industrial extruders, whose optimal value ensures good physicomechanical properties of the catalysts and kinetic control over the catalyzed reaction. The results obtained were verified in paste molding on various industrial extruders, and this enabled the optimal choice of the molding equipment. 相似文献
993.
Summary We study the integration theory for general integral metrics when restricted to upper integrals q, finding improvements in the relation between the classes of the q-integrable and the ql-integrable functions. We give new results and notions which lead to the desirable characterizations of q-integrable functions as ql-integrable f with q(|f|) < ∞, and of ql-integrable functions via the integrability of their upper truncations, under natural conditions which are fulfilled in most
finitely additive integration theories. 相似文献
994.
Off-the-shell anomalous factors of the two-body Coulomb transition matrices appear in the integral form of the Faddeev second-order
nuclear-electronic amplitude, for proton-hydrogen charge transfer scattering in a typical nlm → n′l′m′ transition. A symmetric-impulse approximation (SIA) is applied to eliminate these factors and an induction method is proposed
to analytically calculate the remaining integrals. The nuclear-electronic amplitude is derived for the general case, and for
totally symmetric collisions, in terms of generalized hypergeometric functions of two variables, F
4, and of one variable, 3
F
2, respectively. The angular distribution of the second-order nuclear-electronic charge transfer amplitude shows the Thomas
mechanism as a peak or a hump for symmetric and asymmetric collisions. There also exists a peak in the forward angular distribution
of the second-order nuclear-electronic amplitude, which partly cancels the kinematic peak in the angular distribution of the
charge transfer differential cross sections. 相似文献
995.
Necessary and sufficient conditions in constrained optimization 总被引:22,自引:0,他引:22
Additional conditions are attached to the Kuhn-Tucker conditions giving a set of conditions which are both necessary and sufficient
for optimality in constrained optimization, under appropriate constraint qualifications. Necessary and sufficient conditions
are also given for optimality of the dual problem. Duality and converse duality are treated accordingly. 相似文献
996.
V. B. Larin 《Ukrainian Mathematical Journal》1989,41(5):532-538
Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 41, No. 5, pp. 615–621, May, 1989. 相似文献
997.
E. Mathieu Y. Foucher P. Dellamonica J. P. Daures 《Methodology and Computing in Applied Probability》2007,9(3):389-397
In AIDS control, physicians have a growing need to use pragmatically useful and interpretable tools in their daily medical
taking care of patients. Semi-Markov process seems to be well adapted to model the evolution of HIV-1 infected patients. In
this study, we introduce and define a non homogeneous semi-Markov (NHSM) model in continuous time. Then the problem of finding
the equations that describe the biological evolution of patient is studied and the interval transition probabilities are computed.
A parametric approach is used and the maximum likelihood estimators of the process are given. A Monte Carlo algorithm is presented
for realizing non homogeneous semi-Markov trajectories. As results, interval transition probabilities are computed for distinct
times and follow-up has an impact on the evolution of patients.
相似文献
998.
E. Granot S. Sternklar D. Schermann Y. Ben-Aderet M.H. Itzhaq 《Applied physics. B, Lasers and optics》2006,82(3):359-362
We use the spectral ballistic imaging technique to measure the impulse response of a Fabry–Pérot etalon with less than 0.2 ps
temporal resolution. The results show excellent agreement with the theoretical predictions and negligible noise. Comparison
to the Kramers–Kronig method along with its limitations is also presented.
PACS 42.65.Re; 07.60.Ly; 42.30.Kq 相似文献
999.
F.A. Fernández-Lima C.R. Ponciano E. Pedrero E.F. da Silveira 《Applied Surface Science》2006,252(23):8171-8177
Experimental results of laser sputtering of cesium and rubidium iodide secondary ions are presented. A TOF mass spectrometer, operating in linear mode, continuous extraction for positive or negative ions, was used for the analysis of (CsI)nCs+, (CsI)nI−, (RbI)nRb+ and (RbI)nI− ion emission as a function of the laser irradiance. Experimental data show that the cluster ion emission yields decrease exponentially with n, for all the laser irradiances applied. Theoretical analysis of the clusters structure was performed using density functional theory at the B3LYP/LACV3P level, for the positive and negative cluster series. A quasi-equilibrium evolution of the clusters is proposed to extract a parameter characteristic of the cluster recombination process: the effective temperature. The hypothesis of the atomic species’ recombination (during the expansion of a high density highly ionized cloud) leading to cluster formation is confirmed to some extent in a second set of experiments: the UV laser ablation of a mixed and non-mixed cesium iodide and potassium bromide targets. These experiments show that the emission yields contain contributions from both the recombination process and from the sample stoichiometry, even for high laser irradiances. 相似文献
1000.
Phase synchronization in a system of three virtual-cathode microwave oscillators (vircators) simulated by coupled van der Pol oscillators is studied. The phasing dynamics of the vircators is visualized with the phase portraits of the system in the triangular coordinates. Different phasing conditions are found. 相似文献