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991.
The reaction between thiocarbamate herbicides and 2,6-dichlorobenzoquinone-N-chloroimine or 2,6-dibromobenzoquinone-N-chloroimine is suitable for the detection of these herbicides on thin-layer plates with high sensitivity. The reactions were followed by infrared, nuclear magnetic resonance and mass spectrometry. We have established the formation of 2,6-dichlorobenzoquinone-S-alkyl sulphenylimines. In the case of the bromo-derivative, halogen exchange and substitution on the quinone ring took place simultaneously leading to the formation of mixed halogenated 2,6-dihalo- and, in addition, 2,3,6-trihalobenzoquinone-S-alkyl sulphenylimines. The final product of the detection reaction, i.e. 2,6-dichlorobenzoquinone-S-alkyl sulphenylimine was reacted with 2,6-dibromobenzoquinone-N-chloroimine where 2,6-dichloro-3-bromobenzoquinone-S-alkyl sulphenylimine formed as a consequence of the looser bromine-carbon linkage on the 2 and 6 positions of the quinone ring. 相似文献
992.
A conformational analysis has been made by the method of molecular mechanics of the -apienes — natural sesquiterpenes isolated from plants of the Apiaceae family. The results of the mathematical method with the inclusion of those x-ray structural studies have shown that in the molecules under consideration it is possible to expect the predominant realization of four conformations of the 11-membered ring:14A
8
7
,14A
7
8
,14A
7
8
, and14A
8
7
. These four conformations of unsubstituted -apiene and its natural derivatives have been characterized energetically, and the barriers to their interconversions have been evaluated.Institute of Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 197–202, March–April, 1992. 相似文献
993.
The classical Harary-Read numbers for catafusenes (catacondensed simply connected polyhexes) are reproduced without using generating functions. A complete (mathematical) solution is given for the distribution of these numbers over the different symmetry groups to which the catafusenes belong. 相似文献
994.
R. Bacaud M. Besson D. Brodzki P. Bussière H. Charcosset G. Diega-Mariadassou M. Oberson B. K. Sharma 《Hyperfine Interactions》1989,46(1-4):583-589
Mössbauer Spectroscopy, X-Ray Diffraction and Electron Microscopy were applied to the study of solid residues of coal hydroliquefaction, for which tin-based catalysts were used. In the general case hydroliquefaction runs were performed in the presence of added sulphur and of finely dispersed SnO2 as a catalyst precursor. The only observed tin species were SnO2 and SnS, the former with percentages higher than expected from XRD, due to its large f factor, the latter as a symmetric doublet, which suggests that any asymmetry should be ascribed to small particle sizes rather than to structure. When the S content was only that of coal and the catalyst precursor β-Sn, FeSn2 occurred together with Sn sulfides and oxides, while no β-Sn was detected. The main catalytic role is ascribed to SnS. 相似文献
995.
S. I. Dolinsky V. P. Druzhinin M. S. Dubrovin V. B. Golubev V. N. Ivanchenko A. P. Lysenko A. A. Mikhailichenko E. V. Pakhtusova A. N. Peryshkin S. I. Serednyakov Yu. M. Shatunov V. A. Sidorov 《Zeitschrift fur Physik C Particles and Fields》1989,42(4):511-518
The results of the measurements of radiative decays of ρ and ω mesons with the Neutral Detector at thee + e ? collider VEPP-2M are presented. The branching ratio of the decay ω→π 0γ was measured with higher than in previous experiments accuracy: $${\rm B}(\omega \to \pi ^0 \gamma ) = 0.0888 \pm 0.0062$$ . The ρ0→π 0 γ branching ratio was measured for the first time: $$B(\rho ^0 \to \pi ^0 \gamma ) = (7.9 \pm 2.0) \cdot 10^{ - 4} $$ . The decays ρ, ω→ηγ were studied. Their branching ratios with the assumption of constructive ρ?ω interference are: $$\begin{gathered} B(\omega \to \eta \gamma ) = (7.3 \pm 2.9) \cdot 10^{ - 4} , \hfill \\ B(\rho \to \eta \gamma ) = (4.0 \pm 1.1) \cdot 10^{ - 4} \hfill \\ \end{gathered} $$ . The branching ratios of ρ, ω→ηγ and ω→e + e ? decays were also measured: $$\begin{gathered} B(\omega \to \pi ^ + \pi ^ - \pi ^0 ) = 0.8942 \pm 0.0062, \hfill \\ B(\omega \to e^ + e^ - ) = (7.14 \pm 0.36) \cdot 10^{ - 5} \hfill \\ \end{gathered} $$ . The upper limit for the ω→π 0 π 0 γ branching ratio was placed: B(ω→π 0 π 0 γ)<4·10?4 at 90% confidence level. 相似文献
996.
V. V. Aivazyan I. V. Ajinenko Yu. A. Belokopytov P. C. Bosetti H. B?ttcher F. Botterweck P. V. Chliapnikov F. Crijns A. De Roeck E. A. De Wolf Th. Driever K. Dziunikowska A. Eskreys W. Friebel Z. C. Garutchava V. G. Gavrjusev H. Graessler P. van Hal T. Haupt W. Kittel S. S. Megrabyan F. Meijers A. B. Micha?owska V. I. Nikolaenko L. C. S. Oliveira K. Olkiewicz L. P. Petrovikh E. Riipinen V. M. Ronjin A. M. Rybin H. M. T. Saarikko W. Schmitz L. Scholten R. Schulte O. G. Tchikilev L. A. Tikhonova A. G. Tomaradze V. A. Uvarov F. Verbeure R. Wischnewski A. Wróblewski S. A. Zotkin NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,42(4):533-542
Forward-backward multiplicity correlations in σ+,K + p andpp collisions at 250 GeV/c ( \(\sqrt s \) =22 GeV) are given for all charges and for the different charge combinations. The correlations are found to be caused predominantly by centrally produced particles. It is demonstrated that this result is an agreement with observations at the ISR and the CERNp \(\bar p\) -Collider. The results are compared to expectations from LUND, DPM and FRITIOF Monte Carlo models and a geometrical picture relating correlations in hadron-hadron collisions toe + e ? data in terms of impact parameters is tested. 相似文献
997.
K. D. Duch M. Heel H. Kalinowsky F. Kayser E. Klempt B. May O. Schreiber P. Weidenauer M. Ziegler D. Bailey S. Barlag J. M. Butler U. Gastaldi R. Landua C. Sabev W. Dahme F. Feld-Dahme U. Schaefer W. R. Wodrich J. C. Bizot B. Delcourt J. Jeanjean H. Nguyen E. G. Auld D. A. Axen K. L. Erdman B. Howard R. Howard B. L. White S. Ahmad M. Comyn G. M. Marshall G. Beer L. P. Robertson M. Botlo C. Laa H. Vonach C. Amsler M. Doser J. Riedlberger U. Straumann P. Truöl ASTERIX Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,45(2):223-234
Antiproton-proton annihilation at rest in a gaseous H2 target at NTP into the final state π+ π? K ± π? (K 0) with an undetectedK 0 or \(\bar K^0 \) has been investigated. We observe theE(1420) resonance in the invariant mass spectrum (K 0)miss K ± π? with massM E =1413±8 MeV/c2 and widthГ E =62 ± 16MeV/c2 and find evidence for the production of thef 1(1285). The absolute branching ratio of \(\bar p\) p → π+ π? E 0,E 0 →K 0 L K ± π ? at (61±6)%P wave annihilation is (3.0±0.9)·10?4 of all annihilations. The observed suppression of theE production fromP wave with respect to theS wave together with some simple selection rules suggest that the quantum numbers of theE(1420) areJ pc=0?+ and not I++. 相似文献
998.
Edward B. Manoukian 《International Journal of Theoretical Physics》1989,28(5):501-510
Explicit solutions are derived for transition amplitudes associated with stimulated emission of relativistic particles by external sources inspacetime. More precisely, exact expressions are obtained for transition amplitudes for any process where there are initially, at a given time, an arbitrary number of particles localized in various regions of space, prior to the switching on of an intervening source, and then, finally, at a later time when the intervening source ceases to operate, a given number of particles are found to be localized in various regions of space. The analysis is given for massive particles ofarbitrary integer and half-integer spins. The solutions are obtained by carrying out a unitarity expansion inconfiguration space, where particles travel between emitters and detectors in the presence of an intervening source. Considered as an application is the process: particlearbitrary number of particles, where the latter particles emerge spatially with a cone. 相似文献
999.
Edward B. Manoukian 《International Journal of Theoretical Physics》1989,28(5):495-499
The problem of stimulated emission of photon excitations by external currents is studied inspacetime by making use of the concept of localized photon excitations in configuration space. An explicit expression is derived for the amplitude that an arbitrary number of photon excitations are produced and found in arbitrary localized regions in space when there are an arbitrary number of photon excitations prior to the switching on of the intervening current. Considered as an application is the reaction of a photon splitting to any number of photon excitations as the latter emerge spatially within a cone in the presence of a strong external electromagnetic current. This work is a generalization of work dealing with strictly massive particles. 相似文献
1000.
We discuss productions of scalar gluonium candidates in the radiativeJ/ decays. The branching ratios of such productions are estimated on the basis of the Euler-Heisenberg effective Lagrangian for gluon-photon couplings. We mention that these estimates cannot be expected to be accurate to better than within a factor 2. We show that the radiativeJ/ decays probably invalidate gluoniumgg interpretation of the GAMS meson F0(1590) and a narrow 0++ stateS lying below 1 GeV. However, a possible wide scalar effective gluonium candidate(920) is shown not to be excluded by the data on the decayJ/. We also find that the experimental data about radiativeJ/ decays presumably agree with a recently suggested interpretation of F0(1590) as being approximately a half-and-half mixture of pure 0++ gluoniumgg andSU(3)f singlet quarkoniumq¯q states. 相似文献