Generalization of strain-gradient theory to finite elastic deformation for isotropic materials

This paper concerns finite deformation in the strain-gradient continuum. In order to take account of the geometric nonlinearity, the original strain-gradient theory which is based on the infinitesimal strain tensor is rewritten given the Green–Lagrange strain tensor. Following introducing the generalized isotropic Saint Venant–Kirchhoff material model for the strain-gradient elasticity, the boundary value problem is investigated in not only the material configuration but also the spatial configuration building upon the principle of virtual work for a three-dimensional solid. By presenting one example, the convergence of the strain-gradient and classical theories is studied.     

Effects of gamma and electron radiation on chemical composition and some phyto-chemical properties of whole flaxseed

Journal of Radioanalytical and Nuclear Chemistry - The effects of gamma (GR; 0, 5, 10, 15 and 20 kGy) and electron irradiation (ER; 0, 5, 10, 15 and 20 kGy) on proximate...     

On the prediction of equilibrium phase behavior of amino acids in aqueous and aqueous-electrolyte solutions using SAFT equation of state

We present an approach based on the statistical associating fluids theory (SAFT) to predict the solubility of amino acids in aqueous and aqueous-electrolyte solutions. This approach can describe the association interactions and their effects on the solubility of amino acids. Using the experimental data of activity coefficients of amino acids in water, the parameters of SAFT model for amino acids are obtained. The solubility of several amino acids in the temperature range of 273.15–373.15 K is predicted. Results obtained from the model are in a good accordance with the experimental data. Also, we examine the effect of pH on the solubility of dl-methionine. Addition of an extra amino acid to the binary solution of amino acid + water makes the system more complex. To check the accuracy of model, we study the ternary solution of dl-serine + dl-alanine + water and dl-valine + dl-alanine + water. Predicted results depict that the proposed model has the ability to describe the ternary solution of amino acids, accurately. Finally, the solubility of amino acids in aqueous-electrolyte solutions is investigated. The long-range interactions caused by the presence of ions affects the solubility of amino acids, leading them to be salted in or out. To treat this kind of interaction, the restrictive primitive mean spherical approximation (RP-MSA) is coupled with the SAFT equation of state. The proposed model can accurately predict the solubility of amino acids in aqueous-electrolyte solutions.     

Solvent-Free,Microwave-Assisted,One-Pot Synthesis of 2-Acetyl-N,3-diaryl-4-nitro-butanamides

A combination of benzyltriethylammonium borohydride and chlorotrimethylsilane (1:1) in dichloromethane (0–25°C) has been found to be a convenient reagent system for the selective reduction of carboxylic acids to alcohols.     

Assessment of <Emphasis Type="Italic">Σ−Y</Emphasis><Subscript>liq</Subscript> model predictions for air-assisted atomisation

In a series of recent works, R. Borghi and co-workers proposed a new Eulerian model of two-phase turbulent flows which introduced a transport equation for the average area of the liquid–gas interface. This work is devoted to the assessment of this model’s ability to predict the effects of liquid properties and injection regimes on the atomisation quality. Air-assisted atomisation, for which extensive experimental data are available, is chosen as a test case. It is shown that the model predictions are in good agreement with the observed trends for a wide range of variations of the liquid properties, such as density and surface tension, as well as the injection regimes, defined by the liquid and gas jet exit velocities.      

A four-coordinate cadmium(II) polymer for efficient adsorption of Congo red,kinetic, isotherm,fluorescence and antibacterial activity

A 3-D cadmium-based coordination polymer, [CdCl₂L]_n (1) (where L = 1,1-(1,6-hexanediyl)bis(1,3-dihydro-3-methyl-1H-imidazole-2-thione), was synthesized and structurally characterized. The capability of the polymer as an efficient sorbent for Congo red (CR) removal from aqueous solution has been evaluated. Compound 1 has a tetrahedral arrangement with a CdS₂Cl₂ core. L in 1 is bidentate to two neighboring Cd^II centers via the methimidazole sulfurs to create 1D chains propagating along the c-axis. The remaining coordination sites are occupied by two terminal chlorides. The chains are further stabilized by intermolecular C–H?Cl hydrogen bonds between the chlorides and hydrogens of the imidazole rings. Parallel chains stack in the 3-D structure. The Cd^II polymer sorbent was characterized by infrared spectroscopy, elemental analysis, UV–vis, solid fluorescence and X-ray single-crystal diffraction. Sorption kinetics were studied by three kinetic models, second order, Elovich and intraparticle diffusion. The results indicate that the mechanism of the sorption process followed Elovich kinetic model. Sorption equilibrium was also studied with Langmuir, Temkin, and Freundlich isotherm models. The sorption process followed the Temkin isotherm. MIC, MBC, and DNA cleavage activities of 1 were also studied. Furthermore, the UV–vis and solid state fluorescence spectra of 1 were measured.