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101.
Encapsulation of Pd(II) into superparamagnetic nanoparticles grafted with EDTA and their catalytic activity towards reduction of nitroarenes and Suzuki–Miyaura coupling 下载免费PDF全文
A robust, safe and magnetically recoverable palladium catalyst was synthesized by anchoring Pd(II) onto ethylenediaminetetraacetic acid‐coated Fe3O4 (Fe3O4@EDTA) magnetic nanoparticles. The Fe3O4 magnetic nanoparticle‐supported Pd(II)–EDTA complex catalyst thus obtained was characterized using scanning and transmission electron microscopies, thermogravimetric analysis, vibrating sample magnetometry, X‐ray diffraction, and inductively coupled plasma atomic emission and Fourier transform infrared spectroscopies. Fe3O4@EDTA–Pd(II) was screened for the Suzuki reaction and reduction of nitro compounds in water. The Pd content of the catalyst was measured to be 0.28 mmol Pd g?1. In addition, the Fe3O4@EDTA–Pd catalyst can be easily separated and recovered with an external permanent magnet. The anchored solid catalyst can be recycled efficiently and reused five times with only a very slight loss of catalytic activity. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
102.
Palladium–quaternary phosphonium phase transfer catalyst brush assembly as reusable and environmentally benign catalyst for coupling of aryl halides and sodium tetraphenylborate in neat water 下载免费PDF全文
A first example of simultaneous covalent anchoring of a palladate anion–phosphonium cation matrix on the surface of silica nanoparticles and application in the Suzuki coupling reaction of a variety of different haloarenes and sodium tetraphenylborate in neat aqueous media without the addition of any organic co‐solvent are described. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
103.
In this study, a general framework is proposed that combines the distinctive features of three well-known approaches: the adaptive memory programming, the simulated annealing, and the tabu search methods. Four variants of a heuristic based on this framework are developed and presented. The performance of the proposed methods is evaluated and compared with a conventional simulated annealing approach using benchmark problems for job shop scheduling. The unique feature of the proposed framework is the use of two short-term memories. The first memory temporarily prevents further changes in the configuration of a provisional solution by maintaining the presence of good elements of such solutions. The purpose of the second memory is to keep track of good solutions found during an iteration, so that the best of these can be used as the starting point in a subsequent iteration. Our computational results for the job shop scheduling problem clearly indicate that the proposed methods significantly outperform the conventional simulated annealing. 相似文献
104.
Farideh Namvar Susan Azizi Rosfarizan Mohamad Amin Boroumand Moghaddam Mozhgan Soltani Fazele Moshfegh 《Research on Chemical Intermediates》2016,42(3):1571-1581
Palm pollen (PP) has been widely used in nutrition, pharmaceutical and cosmetic industries. In the present study, we explored the potential of PP in the synthesis of a silver nanoparticle (Ag NP). PP was used as both reducing and stabilizing agent. The Ag/PP nanocomposite was examined by field emission electron microscopy, X-ray diffraction, Fourier transform infrared (FT-IR) spectroscopy, ultraviolet spectroscopy and zeta potential measurement. The biosynthesized NPs showed surface plasmon resonance centered at 425 nm with an average particle size measured to be 23 nm and a zeta potential of ?30.9 mV. Prominent FT-IR signals were obtained and ascribed to phenolic and carbohydrate compounds involved in the formation of the Ag NPs, and proteins which participated in stabilization of the Ag NPs. The biologically synthesized Ag NPs were found to be extremely effective against E. coli (13.8 ± 0.25 mm) with a minimum inhibitory concentration of 20 µg/mL. Thus, such biosynthesized Ag NPs can be used in medicinal applications. 相似文献
105.
采用一种简易的方法制备了新型Ni(OH)2-X/CPE电极,并将其用于电催化氧化甲醛反应.采用扫描电镜和能量散射谱对所制Ni(OH)2-X/CPE电极进行了表征,并运用循环伏安法、电化学阻抗谱和计时电流法考察了该电极的电化学性能.结果表明,该Ni(OH)2-X/CPE电极对甲醛氧化表现出高电催化活性,这归功于X具有纳米孔结构和大的比表面积.电子传递系数和催化反应速率常数分别为0.7和6.1×104 cm3/(mol·s).该电极对甲醛氧化具有高而稳定的电催化活性,且制备重复性高,有望应用于燃料电池中. 相似文献
106.
Seyed Naser Azizi Mohammad Javad Chaichi Parmis Shakeri Ahmadreza Bekhradnia 《Journal of fluorescence》2013,23(2):227-235
In this article, a novel chemiluminescence method using water-soluble CdS quantum dots (QDs) as sensitizers is proposed for the chemiluminometric determination of epinephrine. The method is based on the quenching effect of epinephrine on the chemiluminescence emission generated by the mixing of CdS quantum dots (QDs) with hydrogen carbonate (HCO3 -) in the presence of hydrogen peroxide (H2O2) in an alkaline medium. The optimization of variables influencing the chemiluminescence response of the method has been carried out by using experimental design. Under the optimal conditions, there is good linear relationship between the relative chemiluminescence intensity and the concentration of epinephrine over the range of 5?×?10?9–1?×?10?6?molL?1 with a 3σ detection limit of 5?×?10?11?molL?1. The method has been successfully applied to the determination of epinephrine in pharmaceutical formulation and the recovery test was done in human urine. 相似文献
107.
Complexation of a large variety of Anils (aniline-imines) with boron(III) precursors provides stable Boranils, some of which have been structurally characterized. Analysis of their optical properties reveals that the fluorescence stems from an intraligand charge transfer (ILCT) state with the best quantum yields reaching 90%. Chemistry on the Boranils allows grafting of photoactive modules acting as energy antennae for borondipyrromethene (Bodipy) and subphtalocyanine (SubPc) fluorophores. 相似文献
108.
A simple and facile method for the synthesis of 2,3‐dihydroquinazolin‐4(1H)‐ones through the direct cyclocondensation of one‐pot three‐component cyclocondensation of isatoic anhydride, ammonium acetate (or primary amines) and aldehydes; and anthranilamide and aldehydes using silica supported ferric chloride (SiO2‐FeCl3) as catalyst under solvent‐free conditions is described. 相似文献
109.
Najmadin Azizi Elahm Gholibeglo Sanaz Dehghan Nayeri 《Monatshefte für Chemie / Chemical Monthly》2012,37(8):1171-1174
Abstract
Multicomponent reactions with ultrasonic activation have been used as a simple, rapid, atom economic, and green method for the synthesis of dithiocarbamate derivatives in water. The one-pot, three-component condensation of primary and secondary amines with carbon disulfide and unsaturated carbonyl compounds or alkyl halides under ultrasonic irradiation was developed as a green and fast protocol for the rapid high-yielding preparation of dithiocarbamates in water. 相似文献110.
Tahereh Azizi 《International Journal of Theoretical Physics》2013,52(10):3486-3493
We study wormhole solutions in the framework of f(R,T) gravity where R is the scalar curvature, and T is the trace of the stress-energy tensor of the matter. We have obtained the shape function of the wormhole by specifying an equation of state for the matter field and imposing the flaring out condition at the throat. We show that in this modified gravity scenario, the matter threading the wormhole may satisfy the energy conditions, so it is the effective stress-energy that is responsible for violation of the null energy condition. 相似文献