Three-component synthesis of N-sulfonylformamidines in the presence of magnetic cellulose supported N-heterocyclic carbene-copper complex,as an efficient heterogeneous nanocatalyst

A cellulose based magnetic nanocomposite possessing NHC-Cu Complex has been synthesized and characterized. It was then applied as a highly active catalyst in one-pot three-component reaction of sulfonyl azides, secondary amines and triethylamine to afford N-sulfonylformamidines. Copper catalyzed oxidative transformation of C-N bond of triethylamine is a key step to give desired products. In contrast with the good reactivity of the conventional secondary amines, aromatic amines and NH containing heteroaromatics had no activity in these reactions. Moreover, the used nanocatalyst which could be recovered by external magnet, showed reasonable catalytic activity for several times.     

Analytical and finite-element study of optimal strain distribution in various beam shapes for energy harvesting applications

Owing to the increasing demand for harvesting energy from environmental vibration for use in self-powered electronic applications, cantilever-based vibration energy harvesting has attracted considerable interest from various parties and has become one of the most common approaches to converting redundant mechanical energy into electrical energy. As the output voltage produced from a piezoelec-tric material depends largely on the geometric shape and the size of the beam, there is a need to model and compare the performance of cantilever beams of differing geometries. This paper presents the study of strain distribution in various shapes of cantilever beams, including a convex and concave edge profile elliptical beam that have not yet been discussed in any prior literature. Both analytical and finite-element models are derived and the resultant strain distributions in the beam are computed based on a MATLAB solver and ANSYS finite-element analysis tools. An optimum geome-try for a vibration-based energy harvesting system is verified. Finally, experimental results comparing the power density for triangular and rectangular piezoelectric beams are also pre-sented to validate the findings of the study, and the claim, as suggested in the literature, is verified.     

Design of polyethers,thioethers, and amines with pendent iron moieties

Soluble organoiron polyethers, thioethers, and amines were synthesized via nucleophilic aromatic substitution reactions. The synthesis of these classes of organometallic polymers involved either the reaction of cyclopentadienyliron complexes of dichloroarenes with various oxygen and sulfur dinucleophiles or the reaction of ether‐ or amine‐containing diiron complexes with dithiols. Polymerization reactions with the diiron complexes gave rise to organoiron polymers with alternating ether/thioether or amine/thioether bridges. Removal of the iron moieties from the backbone of these polymers allowed for the production of the corresponding organic materials. Furthermore, the organometallic polymers had much higher solubilities than their organic analogues. Thermogravimetric analysis of the organoiron polymers indicated that the polymers lost their metallic moieties at approximately 200 °C, whereas degradation of the polymer backbones occurred around 500 °C. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1216–1231, 2001     

Biosensors based on cholinesterase inhibition for insecticides, nerve agents and aflatoxin B1 detection (review)

The present review reports the research carried out during last 9 years on biosensors based on cholinesterase inhibition for nerve agents, organophosphorus and carbammic insecticides, and aflatoxin B₁ detection. Relative applications in environmental and food areas are also reported. Special attention is paid to the optimization of parameters such as enzyme immobilization, substrate concentration, and incubation time in the case of reversible inhibition by aflatoxin B₁ or irreversible inhibition by organophosphorus and carbamic insecticides, and nerve agents in order to optimize and improve the analytical performances of the biosensor. Evaluation of selectivity of the system is also discussed.     

Robin-type boundary control problems for the nonlinear Boussinesq type equations

In this paper, we study a linear and a nonlinear boundary control problems arising from viscous flows. The equations are of nonlinear Navier-Stokes type for the velocity and pressure, of transport-diffusion type for the temperature and the salinity. The essential difficulties are due to the nonlinear nature of a part of the boundary conditions and to the nature of the equations: time-dependent, coupled and nonlinear. The existence and the conditions of the uniqueness of the solution, for the variational problem, are studied. The control is of linear or nonlinear Robin-type and acts on a part of the boundary during a time T. The cost function measures the distance between the observed and the computed vorticity. The existence of an optimal control in the admissible set of states and controls is proved. A first order necessary conditions of optimality are obtained.     

Justification of the kinematic assumptions for thin-walled rods with shallow profile

In this Note we present a justification of the kinematic assumptions for thin-walled rods with shallow profile. These assumptions are fundamental to writing the one-dimensional equilibrium equations for such structures. The obtained kinematics are different from the Vlassov case, which is only valid for strongly curved profiles. They are also different from the that classically used in shell theory. The justification given in this Note is based on an asymptotic approach. To cite this article: L. Grillet et al., C. R. Mecanique 333 (2005).     

Subgrid models preserving the symmetry group of the Navier–Stokes equations

In order to preserve the physical properties of the flow (scaling laws, conservation laws, …) during the simulation, a class of subgrid models respecting the symmetry group of the Navier–Stokes equations is built. The class is then refined such that models satisfy the second law of thermodynamics and are suited to take into account the inverse energy cascade. A simple model belonging to the class is tested and a better result than those provided by Smagorinsky and dynamic models is obtained. To cite this article: D. Razafindralandy, A. Hamdouni, C. R. Mecanique 333 (2005).