Electrochemical Characterization of Nickel Electrodes in Phosphate and Carbonate Electrolytes in View of Assessing a Medical Diagnostic Device for the Detection of Early Diabetes

In view of optimizing a multi‐electrode device using proprietary technology for noninvasive assessment of eccrine sweat gland activity and thus the early detection of diabetes, we thoroughly explored the electrochemical behavior of a nickel electrode in a three‐electrode set up combining a nickel counter electrode and a nickel pseudo‐reference electrode in synthetic buffered phosphate and carbonate solutions in presence of chloride, lactate and urea that mimic the composition of physiological sweat. This approach provides insight into the origin of the onset of responses measured upon the application of low voltage potential with variable amplitudes to Ni electrodes on the skin. For low voltage amplitude of ca. ΔE=0.6 V, the electrochemical reactions measured at the electrodes are those related to the oxidation of Ni leading to the formation of a passive layer, as well as the reduction of this passive layer. For voltage amplitude higher than 1 V, or current densities higher than 1 mA/cm², the breakdown of the passive layer becomes the main electrochemical anodic reaction, while its reduction and the electrolytic solution govern the cathode reactions. This brings explanation of the nonlinear current‐voltage features measured during the clinic tests. Finally, the obtained results make possible the definition of the experimental electrochemical conditions where the Ni electrodes can be renewed.     

Boundary-induced localized structures in a nonlinear optical feedback experiment

Experimental and numerical evidence of symmetry-breaking bifurcations of a circular dissipative soliton with additional boundary conditions in the feedback of a liquid crystal light valve are reported. By tuning the strength of the nonlinearity or the size of the additional boundaries, the circular structure breaks up into polygonal symmetries and the system exhibits multistability. The experimental results are confirmed by numerical simulations with different configurations of the polarizers thus demonstrating the universality of the phenomenon.     

Distinguisher-based attacks on public-key cryptosystems using Reed–Solomon codes

Because of their interesting algebraic properties, several authors promote the use of generalized Reed–Solomon codes in cryptography. Niederreiter was the first to suggest an instantiation of his cryptosystem with them but Sidelnikov and Shestakov showed that this choice is insecure. Wieschebrink proposed a variant of the McEliece cryptosystem which consists in concatenating a few random columns to a generator matrix of a secretly chosen generalized Reed–Solomon code. More recently, new schemes appeared which are the homomorphic encryption scheme proposed by Bogdanov and Lee, and a variation of the McEliece cryptosystem proposed by Baldi et al. which hides the generalized Reed–Solomon code by means of matrices of very low rank. In this work, we show how to mount key-recovery attacks against these public-key encryption schemes. We use the concept of distinguisher which aims at detecting a behavior different from the one that one would expect from a random code. All the distinguishers we have built are based on the notion of component-wise product of codes. It results in a powerful tool that is able to recover the secret structure of codes when they are derived from generalized Reed–Solomon codes. Lastly, we give an alternative to Sidelnikov and Shestakov attack by building a filtration which enables to completely recover the support and the non-zero scalars defining the secret generalized Reed–Solomon code.     

Ageing of nickel used as sensitive material for early detection of sudomotor dysfunction

The surface ageing of nickel electrodes was studied in the frame of the development of non-invasive biomedical devices, dedicated to the detection of sudomotor dysfunction manifested by an alteration of the ionic balance in human sweat. In this kind of technology, low voltage potentials with variable amplitudes are applied to nickel electrodes, placed on skin regions with a high density of sweat glands, and the electrical responses are measured. The trick is that nickel electrodes play alternately the role of anode and cathode, thus the analysis of the temporal evolution of the physico-chemical properties of nickel is of prime importance to ensure the good performance of the device. Electrochemical measurements coupled to surface chemical characterizations (X-ray photoelectron spectroscopy (XPS), Time of Flight-Secondary Ion Mass Spectrometry (ToF-SIMS)) were performed on pure Ni samples, immersed in buffered chloride solutions mimicking human sweat. The shapes of voltammograms, recorded in a restricted anodic potential range, show that the nickel surface was gradually passivated as a function of the number of scans. This was confirmed by XPS data, with the formation of a 1 nm thick duplex layer composed by nickel hydroxide (outermost layer) and nickel oxide (inner layer). In a negative extended potential range, though the electrochemical behavior of electrodes was not modified upon cycling the potential, XPS data show that the inner layer was thickening, indicating a surface degradation of the nickel electrode. Below pitting potentials, adsorbed chloride was only hardly detected by XPS, and the surface composition of the nickel samples was similar after treatments in chloride or chloride-free buffered solutions. In a larger potential range enabling to reach the breakdown potential, the highly chemically sensitive ToF-SIMS characterization pointed out that the surface concentration of adsorbed chloride was higher in pits than elsewhere on the surface sample.     

Determination of solid materials rigidity modulus by a new nondestructive optical method

We propose a new optical method for the determination of the rigidity modulus G of solid materials. The rigidity modulus is determined by measuring the twisted angle θ as a response of the material sample, depending on the applied force. The measuring of this twisted angle can be carried out by using an adapted polarimetric sensor. The effective measurement of rigidity modulus G for aluminum, Plexiglas and steel was experimentally obtained 1.4464×10¹⁰,0.99417×10⁹ and 1.0395×10¹¹ N m, respectively. The study has demonstrated the effective usefulness of our method for evaluating the rigidity modulus. A good agreement between the theoretical and experimental results was achieved.     

Preparation and Characterization of Homo‐ and Co‐Polymers of Some Vinyl Monomers via ATRP by Using Imine Macrocycle as Ligand

Imine macrocyclic ligand M₁ was involved in homo‐ and co‐polymerization of some vinyl monomers via atom transfer radical polymerization technique (ATRP). Hereby, vinyl acetate, styrene and methyl acrylate monomers were homopolymerized. On the other hand, they were involved in copolymerization with MMA. M₁∶CuBr∶initiator∶monomer percentages were 1∶2∶4∶400. ¹HNMR confirmed the structures of the resulting polymers. The thermal behaviors of some selected polymers were studied.     

Investigation of free vibrations of composite beams by using the finite-difference method

The free-vibration behavior of symmetrically laminated fiber-reinforced composite beams with different boundary conditions is examined. The effects of shear deformation and rotary inertia, separately and/or in combination, on the free-vibration properties of the beams are investigated. The finite-difference method is used to solve the partial differential equations describing the free-vibration motion in each case. The effect of shear deformation on the natural frequencies is considerable, especially for higher frequencies, whereas the influence of rotary inertia is less significant. The study includes comparisons with results available in the literature. In addition, the impact of such factors as the span/depth ratio, fiber orientation, stacking sequence, and material type on free vibrations of the composite beams is investigated. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 3, pp. 331–346, May–June, 2006.