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121.
A. Ebru Aydin 《Tetrahedron: Asymmetry》2013,24(8):444-448
Novel chiral norephedrine-based β-amino alcohol ligands containing a thiophene ring were prepared from norephedrine and substituted furan carbaldehydes (methyl- or ethyl-substituted) and used in combination with VO(acac)2 for the asymmetric oxidation of aryl methyl sulfides using H2O2 as an oxidant. Amino alcohol derived Schiff bases 4,5a–b gave higher enantiomeric excesses than amino alcohol-derived reduced Schiff based ligands 6,7a–b. Of these chiral ligands, (1S,2R)-5b and (1S,2R)-7b gave high yields (90%) with moderate to high enantioselectivities (78%, 96% ee, respectively). The oxidation of other aryl methyl sulfides with (1S,2R)-5b and (1S,2R)-7b as ligands afforded the corresponding sulfoxides in 60–89% yields and with 92–99% ee. 相似文献
122.
J Lu C Aydin ND Browning BC Gates 《Langmuir : the ACS journal of surfaces and colloids》2012,28(35):12806-12815
Zeolite Hβ- and γ-Al(2)O(3)-supported mononuclear iridium complexes were synthesized by the reaction of Ir(C(2)H(4))(2)(acac) (acac is acetylacetonate) with each of the supports. The characterization of the surface species by extended X-ray absorption fine structure (EXAFS) and infrared (IR) spectroscopies demonstrated the removal of acac ligands during chemisorption, leading to the formation of essentially isostructural Ir(C(2)H(4))(2) complexes anchored to each support by two Ir-O(support) bonds. Atomic-resolution aberration-corrected scanning transmission electron microscopy (STEM) images confirm the spectra, showing only isolated Ir atoms on the supports with no evidence of iridium clusters. These samples, together with previously reported Ir(C(2)H(4))(2) complexes on zeolite HY, zeolite HSSZ-53, and MgO supports, constitute a family of isostructural supported iridium complexes. Treatment with CO led to the replacement of the ethylene ligands on iridium with CO ligands, and the ν(CO) frequencies of these complexes and white line intensities in the X-ray absorption spectra at the Ir L(III) edge show that the electron density on iridium increases in the following order on these supports: zeolite HY < zeolite Hβ < zeolite HSSZ-53 ? γ-Al(2)O(3) < MgO. The IR spectra of the iridium carbonyl complexes treated in flowing C(2)H(4) show that the CO ligands were replaced by C(2)H(4), with the average number of C(2)H(4) groups per Ir atom increasing as the amount of iridium was increasingly electron-deficient. In contrast to the typical supported catalysts incorporating metal clusters or particles that are highly nonuniform, the samples reported here, incorporating uniform isostructural iridium complexes, provide unprecedented opportunities for a molecular-level understanding of how supports affect the electronic properties, reactivities, and catalytic properties of supported metal species. 相似文献
123.
Let (M, g) be an n-dimensional Riemannian manifold and T*M be its cotan-gent bundle equipped with the rescaled Sasaki type metric. In this paper, we firstly study the paraholomorphy property of the rescaled Sasaki type metric by using some compati-ble paracomplex structures on T*M. Second, we construct locally decomposable Golden Riemannian structures on T*M . Finally we investigate curvature properties of T*M . 相似文献
124.
A simple, sensitive, selective, precise and stability-indicating high-performance thin-layer chromatographic (HPTLC) method was developed and applied to human urine for the densitometric determination of sulfanilamide. A mixture of chloroform-ethyl
acetate-xylene (2.5: 4.0: 1.0, v/v/v) was used as a mobile phase. The system was found to give compact spots for sulfanilamide
(retardation factor, R
f = 0.21±0.02). The linear regression analysis data for the calibration plots showed good linear relationship with r
2 = 0.9970 ± 0.0003 and r
2 = 0.9947 ± 0.020 within the concentration range of 50–250 ng per spot and 100–1000 ng per spot with respect to peak area,
respectively. The limit of detection (LOD) and quantification (LOQ) were 8 and 25 ng per spot, respectively. Sulfanilamide was subjected to acid and alkali hydrolysis, oxidation, dry heat
and wet heat treatment. According to the International Conference on Harmonization (ICH) guidelines the method was validated for precision, recovery and robustness. The ultraviolet (UV) spectra of the degradation products which had different spectra from sulfanilamide were also recorded.
The article is published in the original. 相似文献
125.
Aydin Tavman 《Russian Journal of Inorganic Chemistry》2010,55(3):377-383
2-(2-Hydroxy-5-methylphenyl)-1H-benzimidazole ligand (HL) and its complexes with Cu(NO3)2, Zn(NO3)2 have been synthesized and characterized. The structures of the compounds were confirmed on the basis of elemental analysis,
molar conductivity, magnetic moment, FT-IR, 1H- and 13C NMR. Cu(II) complex has 1: 2 metal: ligand ratio, while Zn(II) complex is 1: 1. Crystal structure of 2-(2-hydroxy-5-methylphenyl)-1H-benzimidazolium chloride (HL · HC1) was determined by single-crystal X-ray diffraction. It crystallizes in the orthorombic,
space group P212121and Z = 4. 相似文献
126.
A speciation procedure has been established for the flame atomic absorption spectrometric determination of Cr(III) and Cr(VI) based on coprecipitation of Cr(III) by using praseodymium(III) hydroxide (Pr(OH)3) precipitate. In the presented system, Cr(III) was quantitatively (>95%) recovered at the pH range of 10.0?C12.0 on Pr(III) hydroxide, while the recoveries of Cr(VI) were below 10%. The method was applied to the determination of the total chromium after reduction of Cr(VI) to Cr(III) by using hydroxylamine hydrochloride. The concentration of Cr(VI) is calculated by difference of total chromium and Cr(III) levels. The analytical parameters including pH of the aqueous medium, amount of Pr(III), centrifugation speed, sample volume were optimized. The influences of matrix ions were also investigated. The method was validated by the analysis of TMDA 70 fortified lake water certified reference material. The method was applied to the speciation of chromium in water samples. 相似文献
127.
S. R. Garaeva A. A. Medzhidov O. Beukgunger A. Aydin B. Yalcin M. G. Abbasov 《Russian Journal of Coordination Chemistry》2012,38(2):140-144
The heterovalent trinuclear cobalt complexes [Co2IIIL4
i
· CoII(H2O)4] · nXmY (L
i
are deprotonated Schiff bases derived from substituted salicylaldehydes and β-alanine; i = 1–3) were obtained and characterized. An X-ray diffraction study of the trinuclear cobalt complex with N-(2-carboxyethyl)salicylaldimine
showed that the central Co(II) ion and the terminal Co(III) ions are linked by bridging carboxylate groups. Either terminal
Co(III) atom is coordinated to two ligand molecules. They form an octahedral environment consisting of two azomethine N atoms,
two phenolate O atoms, and two O atoms of two carboxylate groups. The central Co(II) atom is coordinated to four water molecules
and to two O atoms of two bridging carboxylate ligands involved in the coordination sphere of the terminal Co(III) atoms. 相似文献
128.
Compensation behaviors, magnetic susceptibilities and the phase diagrams of the ternary system of the type ABC consisting of Ising spins σ = 1/2, S = 3/2 and m = 5/2 in the presence of a single-ion anisotropy are studied on the Bethe lattice within the framework of the exact recursion
relations. Both ferromagnetic and antiferromagnetic exchange interactions are considered. The exact expressions for sublattice
magnetizations and magnetic susceptibilities are obtained, and then thermal behaviors of the sublattice magnetizations, total
magnetization, magnetic sublattice susceptibilities and total susceptibility are investigated. We find that the system only
undergoes a second order phase transition for the different and same bilinear nearest-neighbor exchange interaction parameters,
but displays compensation behaviors for only different bilinear interaction parameters. We also present the phase diagrams
for the different and same bilinear nearest-neighbor exchange interaction parameters. A comparison is made with the other
ternary system of the type ABC consisting of different spin values. 相似文献
129.
Koray Aydin Zhaofeng Li Serafettin Bilge Ekmel Ozbay 《Photonics and Nanostructures》2008,6(1):116-VII
We report on the transmission properties of the omega (Ω) type metamaterials. Transmission through the periodic Ω-only and Ω-wire metamaterials are studied experimentally and numerically. A resonance band gap is observed for the periodic Ω medium around the resonance frequency of the single Ω unit cell. A transmission band is observed below the resonance band gap, when the periodic Ω structure is embedded in a negative permittivity medium composed of thin metallic wire arrays. We also studied the effect of periodicity on the transmission spectra of Ω type metamaterials. 相似文献
130.
Cd/p-Si Schottky barrier diodes (SBDs) with and without the native oxide layer have been fabricated to determine the importance of the fact that the series resistance value is considered in calculating the interface state density distribution (ISDD) from the forward bias current-voltage (I-V) characteristics of the Cd/p-Si SBDs. The statistical analysis yielded mean values of 0.71 ± 0.02 eV and 1.24 ± 0.12 for the BH and ideality factor of the Cd/p-Si SBDs (15 dots) without the native oxide layer (MS), respectively, and mean values of 0.79 ± 0.02 eV and 1.36 ± 0.06 eV for the Cd/p-Si SBDs (28 dots) with the native oxide layer (metal-insulating layer-semiconductor (MIS)). The interface state density (Nss) distributions of the devices were calculated taking into account their series resistance values. At the same energy position near the top of the valence band, the interface state density values without taking into account the series resistance value of the devices are almost one order of magnitude larger than Nss obtained taking into account series resistance value. 相似文献