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41.
We propose for the first time a few examples of stable transition metal complexes of an all-metal antiaromatic molecule Al4Li4. We demonstrate that these all-metal species can be stabilized by complexation with 3d transition metals very similar to their organic counterpart, C4H4. Complexation to transition metal ions reduces the frontier orbital energies and introduces aromatic charactersitics. We consider a series of such complexes: [eta4-(Al4Li4)-Fe(CO)3, eta2,sigma2-(Al4Li4)-Ni, and (Al4Li4)2Ni] and compare and contrast their energetics with their organometallic counterparts. Fragmentation energy, orbital correlation energy analysis, and the nucleus-independent chemical shift (NICS) values support the complexation-induced stabilities in these systems. 相似文献
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Seylan Ayan Özdemir Dogan Polina M. Ivantcova Nikita G. Datsuk Dmitry A. Shulga Vladimir I. Chupakhin Dmitry V. Zabolotnev Konstantin V. Kudryavtsev 《Tetrahedron: Asymmetry》2013,24(13-14):838-843
The (2R,4R,5S)- and (2S,4S,5R)-enantiomers of 4-(tert-butyl) 2-methyl 5-(4-bromophenyl)-pyrrolidine-2,4-dicarboxylate 3 were synthesized efficiently with an ee of >90% on a gram scale using a FAM-catalytic methodology. Subsequent modification afforded enantiopure N-((4-chlorophenyl)thio)acetyl pyrrolidine derivatives 4, which are potential thrombin inhibitors according to comprehensive molecular docking studies. 相似文献
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Şükriye Ulubay Karabiberoğlu Ebru Mavioglu Ayan Zekerya Dursun 《Electroanalysis》2013,25(8):1933-1945
A silver nanoparticle decorated poly(thiophene) modified glassy carbon electrode (GCE) was prepared for determination of caffeic acid. The Ag/PTh/GCE surface was characterized by scanning electron microscopy (SEM) and energy‐dispersive X‐ray (EDX) spectroscopy. The modified electrode has shown higher electrocatalytic activity towards the oxidation of caffeic acid. The peak current of was found linear in the concentration range from 1.00×10?8 to 4.83×10?6 M with a detection limit of 5.3×10?9 M (S/N=3). The modified electrode was used for determination of CA concentration in red wine samples. The thermodynamic constants, entropy change (ΔS), enthalpy change (ΔH) and Gibbs free energy change (ΔG) were calculated as ?166.34 J/(mol K), ?154.24 kJ/mol and ?104.75 kJ/mol at 25 °C, respectively. 相似文献
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The structures and proton‐coupled behavior of adenine–thymine (A‐T) and a modified base pair containing a thymine isostere, adenine–difluorotoluene (A‐F), are studied in different solvents by dispersion‐corrected density functional theory. The stability of the canonical Watson–Crick base pair and the mismatched pair in various solvents with low and high dielectric constants is analyzed. It is demonstrated that A‐F base pairing is favored in solvents with low dielectric constant. The stabilization and conformational changes induced by protonation are also analyzed for the natural as well as the mismatched base pair. DNA sequences capable of changing their sequence conformation on protonation are used in the construction of pH‐based molecular switches. An acidic medium has a profound influence in stabilizing the isostere base pair. Such a large gain in stability on protonation leads to an interesting pH‐controlled molecular switch, which can be incorporated in a natural DNA tract. 相似文献
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Ayan Chatterjee 《Annals of Physics》2011,(2):307-322
The paper deals with the extension of the Weak Isolated Horizon (WIH) formulation of black hole horizons to the non-minimally coupled scalar fields. In the early part of the paper, we introduce an appropriate Holst type action to incorporate scalar fields non-minimally coupled to gravity and construct the covariant phase space of the theory. Using this phase space, we proceed to prove the laws of black hole mechanics. Further, we show that with a gauge fixing, the symplectic structure on the horizon reduces to that of a U(1) Chern–Simons theory. The level of the Chern–Simons theory is shown to depend on the non-minimally coupled scalar field. 相似文献
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Das A Heo J Jankowski M Guo W Zhang L Deng H Bhattacharya P 《Physical review letters》2011,107(6):066405
We report ultralow threshold polariton lasing from a single GaN nanowire strongly coupled to a large-area dielectric microcavity. The threshold carrier density is 3 orders of magnitude lower than that of photon lasing observed in the same device, and 2 orders of magnitude lower than any existing room-temperature polariton devices. Spectral, polarization, and coherence properties of the emission were measured to confirm polariton lasing. 相似文献
49.
Charge‐Transfer Complex Formation in Gelation: The Role of Solvent Molecules with Different Electron‐Donating Capacities
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Shibaji Basak Sumantra Bhattacharya Dr. Ayan Datta Prof. Arindam Banerjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(19):5721-5726
A naphthalenediimide (NDI)‐based synthetic peptide molecule forms gels in a particular solvent mixture (chloroform/aromatic hydrocarbon, 4:1) through charge‐transfer (CT) complex formation; this is evident from the corresponding absorbance and fluorescence spectra at room temperature. Various aromatic hydrocarbon based solvents, including benzene, toluene, xylene (ortho, meta and para) and mesitylene, have been used for the formation of the CT complex. The role of different solvent molecules with varying electron‐donation capacities in the formation of CT complexes has been established through spectroscopic and computational studies. 相似文献
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Light Harvesting and Amplification of Emission of Donor Perylene–Acceptor Perylene Aggregates in Aqueous Medium
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Pradip K. Sukul Dr. Ayan Datta Dr. Sudip Malik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(11):3019-3022
With the aid of rational design, we have synthesized a pair of water‐soluble donor‐ and acceptor‐type twisted perylene bisimide units, which together form aggregates upon lowering the pH of the medium, providing bright yellow fluorescence. The light‐harvesting efficiency of the co‐assembled system can be tuned by controlling the ratio of donor to acceptor and 98.1 % efficiency has been achieved. 相似文献