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121.
Two kinds of temperature-sensitive composite polymer particles were prepared by seeded emulsion copolymerizations of (dimethylamino)ethyl methacrylate and ethylene glycol dimethacrylate with 0.14 μm-sized polystyrene and 0.26 μm-sized poly(methylmethacrylate) seed particles. To evaluate the usefulness as a carrier for biomolecules, the enzymatic activities of trypsin adsorbed on these two composite polymer particles were measured at temperatures above and below each lower critical solution temperature (LCST). In both cases, adsorbed trypsin retained its enzymatic activity during repeated adsorption/desorption measurements. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 883–888, 1998 相似文献
122.
Abdillah Sani Bin Mohd Najib Xiaobo Peng Ayako Hashimoto Shusaku Shoji Takayuki Iida Yunxing Bai Hideki Abe 《化学:亚洲杂志》2019,14(16):2802-2805
Mesoporous precious metals with abundant active sites and high surface area have been widely recognized as high‐performance catalytic materials. However, the templated synthesis is complex and costly. Herein, we report a mesoporous rhodium (m‐Rh) that can be readily synthesized from entangled nanofibres of Rh and Y2O3 without templates. The entangled nanofibres, prepared from uniform Rh‐Y alloys under redox atmosphere, were the key precursor in the synthesis processes. Moreover, the m‐Rh efficiently catalyzed carbon dioxide reforming of methane (DRM) at a low reaction temperature of 683 K. Further, electrochemical methods of CO electro‐oxidation were innovatively used to demonstrate the stability of CO and oxygen species for the DRM reaction. 相似文献
123.
Ayako Imai Kenji Mawatari Nobuo Ueno Kazuyuki Sakamoto 《Applied Surface Science》2009,256(4):1156-1159
The thickness-dependent electronic structures of Dy silicide films grown on a Si(1 1 1) surface have been investigated by angle-resolved photoelectron spectroscopy. Two (1×1) periodic bands, both of them cross the Fermi level, have been observed in the silicide films formed by Dy coverages of 1.0 monolayer and below, and more than five () periodic bands have been observed in thicker films. Taking the () periodic structure of Dy atoms in the submonolayer silicide film into account, the periodicity of the two metallic bands indicate that they mainly originate from the orbitals of Si atoms, which form a (1×1) structure. Of the () periodic bands observed in thick films, four of them are well explained by the folding of the (1×1) bands into a () periodicity. Regarding the other band, the three () periodic bands would originate from the electronic states related to the inner Si layers that form a () structure, and the one observed in the 3.0 ML film only might originate from the electron located at the interface between bulk Si and the Dy silicide film. 相似文献
124.
125.
Keiichiro Yoshida Toshiaki Yamamoto Tomoyuki Kuroki Masaaki Okubo 《Plasma Chemistry and Plasma Processing》2009,29(5):373-386
A pilot-scale pulse corona induced plasma chemical process (PPCP) reactor for controlling gas-phase dioxins and NO
x
simultaneously is installed in a garbage incineration plant. The flow rate of the sampled flue gas is 5,000 Nm3/h (N: standard state) in maximum at the PPCP reactor, which consists of 22 wire-cylinder electrodes and is energized by a
50 kW nanosecond pulse high voltage generator. With an applied plasma energy density of 2.9–6.1 Wh/Nm3, the decomposition efficiency for dioxins is 75–84% based on TEQ (toxic equivalents); the conversion efficiency of NO to
NO2 is ~93% at maximum. The flue gas treated by the PPCP reactor is introduced at a rate of 50 Nm3/h to a wet-type chemical reactor, which uses an aqueous solution of sodium sulfite (Na2SO3). More than 90% of NO
x
is reduced to nitrogen, with negligible byproducts such as NO2
− or NO3
− ions left in the solution. 相似文献
126.
Hiroshi Kobayashi Toyoko Suzuki Mineho Moritaka Emi Miyanaga Masayoshi Okubo 《Colloid and polymer science》2009,287(3):251-257
Seeded emulsion polymerizations of styrene using polystyrene (PS) seed particles with incorporated nonionic emulsifier were
carried out at 40 and 70 °C to investigate the influence of temperature during the polymerization process including the swelling
step of the seed particles with monomer on the formation of multihollow PS particles. An increase in the temperature during
the polymerization process caused an increase in the rate of coalescence (i.e., the degree of coalescence at any given time)
of the small water domains in the inside. After the coalescence proceeded excessively, the water domains were eventually discharged
from the particles to the medium, resulting in nonhollow particles. The results show that it is important for the preparation
of the multihollow PS particles to control the coalescence of a lot of small water domains inside the seed particles with
the incorporated nonionic emulsifier, and strongly support the formation mechanism previously proposed.
Part CCCXX of the series “Studies on Suspension and Emulsion”. 相似文献
127.
Hideko T. Oyama Yoshikazu Tanaka Ayako Kadosaka 《Polymer Degradation and Stability》2009,94(9):1419-1426
Although poly(lactic acid) is known as a biodegradable polymer, its hydrolytic degradation is extremely slow, taking years in water and in the human body. In this study the effects of blending oligomeric poly(aspartic acid-co-lactide) (PALs) on the hydrolytic degradation of poly(l-lactic acid) (PLLA) were studied in detail. It was found that the addition of PAL did not accelerate the hydrolysis of the PLLA in air (25 °C, 60% relative humidity), but significantly accelerated it in a phosphate buffer solution. The degradation rate becomes higher for the blends containing PAL with higher molar ratios of lactide to aspartic acid units, [LA]/[Asp], when PLLA/PAL blends prepared with different PALs are compared at the same PAL concentration. TEM results, in which the distribution of PALs with higher [LA]/[Asp] occurs at a smaller scale in blends, imply that higher miscibility of the PAL with PLLA results in higher contact area between the components, thereby accelerating the degradation efficiently. 相似文献
128.
Per B. Zetterlund Fawaz Aldabbagh Masayoshi Okubo 《Journal of polymer science. Part A, Polymer chemistry》2009,47(15):3711-3728
Supercritical carbon dioxide (scCO2) is an inexpensive and environmentally friendly medium for radical polymerizations. ScCO2 is suited for heterogeneous controlled/living radical polymerizations (CLRPs), since the monomer, initiator, and control reagents (nitroxide, etc.) are soluble, but the polymer formed is insoluble beyond a critical degree of polymerization (Jcrit). The precipitated polymer can continue growing in (only) the particle phase giving living polymer of controlled well‐defined microstructure. The addition of a colloidal stabilizer gives a dispersion polymerization with well‐defined colloidal particles being formed. In recent years, nitroxide‐mediated polymerization (NMP), atom transfer radical polymerization (ATRP), and reversible addition fragmentation chain transfer (RAFT) polymerization have all been conducted as heterogeneous polymerizations in scCO2. This Highlight reviews this recent body of work, and describes the unique characteristics of scCO2 that allows composite particle formation of unique morphology to be achieved. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 3711–3728, 2009 相似文献
129.
Matsuo Y Muramatsu A Kamikawa Y Kato T Nakamura E 《Journal of the American Chemical Society》2006,128(30):9586-9587
A series of conical molecules featuring a [60]fullerene/ferrocene hybrid and five aralkyl side chains (Fe[C60{C6H4-(OCO-C6H3-(OR)2-3,4)-4}5]Cp) have been synthesized and examined for their structural and electrochemical properties as well as their ability to form supramolecular structures in crystals and liquid crystals. When the R group on the side is a methyl group, the compound forms crystals in which the dipolar conical molecules are stacked head-to-tail to form a columnar structure. When the R group is as long as a C18H38 group, the compound forms liquid crystals. Oxidation of the liquid crystalline compound by an aminium salt [(4-BrC6H4)3N][SbCl6] produces the corresponding paramagnetic Fe(III) compound that also exhibits liquid crystalline properties. 相似文献
130.