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21.
A simple method to measure the complex degree of spatial coherence of a partially coherent quasi-monochromatic light field is presented. The Fourier spectrum of the far-field interferogram generated by a mask with multiple apertures (small circular holes) is analyzed in terms of classes of aperture pairs. A class of aperture pairs is defined as the set of aperture pairs with the same separation vector. The height of the peaks in the magnitude spectrum determines the modulus of the complex degree of spatial coherence and the corresponding value in the phase spectrum determines the phase of the complex degree of spatial coherence. The method is illustrated with experimental results. 相似文献
22.
Véronique Vacchina Sébastien Oguey Catherine Ionescu David Bravo Ryszard Lobinski 《Analytical and bioanalytical chemistry》2010,398(1):435-449
A method was developed for the determination of metal complexes with glycine (glycinates, [M(Gly)x(H2O)y(SO4)z]n, where M denotes Zn, Cu, Mn and Fe) in premix samples used for the preparation of animal feeds enriched in essential trace
elements. The method was based on the extraction of the glycinates with 10 mM ammonium acetate (pH 7.4) followed by their
determination using capillary electrophoresis with ICP MS detection. The stability of the glycinates in solution was verified
by electrospray TOF-MS. Each supplement was shown to be a mixture of complexes, with polymerization degrees ranging from n = 1 to n = 4 (depending on the metal), that were fully or partially dehydrated. The metal glycine complex moiety was found to be preserved
during capillary electrophoresis. The detection limits, calculated as three times the standard deviation of the blank plus
the blank, were between 0.05 and 0.2 μg mL−1 (as the metal), and the calibration curves were linear, allowing the analysis of premix samples. Repeatability for glycinate
standards was below 12%, and analytical precision was typically within 15%. 相似文献
23.
Carpino LA Abdel-Maksoud AA Ionescu D Mansour EM Zewail MA 《The Journal of organic chemistry》2007,72(5):1729-1736
Of the three theoretically possible, Bsmoc-related, naphthothiophene sulfone-based amino-protecting groups, the two most readily available derivatives, the alpha- and beta-Nsmoc analogues, have been examined as substitutes for the Bsmoc residue in cases where the latter lead to oily protected amino acids or amino acid fluorides. All of the naphtho systems gave easily handled solid amino acid derivatives. The intermediate sulfone alcohol 11 used as the key reagent for introduction of the alpha-Nsmoc protecting group was readily made from alpha-tetralone (Scheme 1). The corresponding beta-analogue 17 was made similarly on a small scale, but due to the high cost of beta-tetralone, an alternate route involving reaction of rhodanine with alpha-naphthaldehyde was used for large-scale work (Scheme 2). All proteinogenic amino acids were converted to their alpha- and beta-Nsmoc derivatives. Deblocking studies showed that the reactivity toward deblocking by piperidine followed the order alpha-Nsmoc > Bsmoc > beta-Nsmoc. 1H NMR experiments showed that deblocking of the two new systems was mechanistically similar to that previously established for the Bsmoc derivative in that the reaction is initiated by Michael addition to the beta-carbon atom of the alpha,beta-unsaturated sulfone system. Application of alpha- and beta-Nsmoc amino acids to the solid-phase synthesis of two model peptides was examined. An advantage of the alpha-Nsmoc system over the long-known Bsmoc system proved to be the milder conditions needed for the deblocking step relative to the Bsmoc case, which is itself more readily deblocked than the classic Fmoc analogue. 相似文献
24.
Novel supports based on carboxymethylcellulose (CMC), crosslinked with epichlorohydrin (EPC), and microparticles based on acetylphthalylcellulose (APC), for sustained‐release of isosorbide dinitrate (Isoket, Ik), were obtained. The drug has been included into CMC hydrogels through diffusion from ethanol‐water solution. Studies about the ethanol–water ratio influence on including the drug have shown an increased amount of included drug at higher content of water in the alcohol‐water mixture. Isoket–ACP microparticles have been obtained by drug and polymer co‐precipitation from emulsified aqueous solution. The kinetics for “in vitro” release of Ik from polymeric materials, in simulated conditions for intestinal tract medium, where the drug is preferentially absorbed, has been analyzed. The experimental data have shown a “zero” order kinetic for drug release, which is characteristic for systems controlled by diffusion. 相似文献
25.
Reacting [PtCl(PTA)3]Cl(PTA = 1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane) with KSeCN in aqueous or MeOH medium results in the abstraction of the PTA ligands to yield SePTA. The reaction also proceeds quantitatively by direct reaction of PTA and KSeCN in water or methanol. The methylated PTA ligand, [PTA-Me]I (1-methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane iodide), reacts accordingly with KSeCN, albeit significantly slower. The crystal structure of SePTA, 1, and [SePTA-Me]I · CH3OH, 2, revealed PSe bond distances of 2.0991(19) and 2.100(2) Å, respectively. The first order phosphorous selenium coupling constants, 1JP-Se (D2O), of 722 and 788 Hz for SePTA and [SePTA-Me]I, respectively, indicates the latter is significantly less electron rich. 相似文献
26.
Xiangbo Meng Mihnea Ionescu Mohammad Norouzi Banis Yu Zhong Hao Liu Yong Zhang Shuhui Sun Ruying Li Xueliang Sun 《Journal of nanoparticle research》2011,13(3):1207-1218
This study attempted to synthesize one-dimensional (1D) coaxial nanotubes of Fe2O3 based on carbon nanotubes (CNT@Fe2O3) via atomic layer deposition (ALD) using ferrocene and oxygen as precursors. Results disclosed that undoped CNTs were suitable
for the ALD of Fe2O3 (ALD-Fe2O3) only if they were chemically functionalized, due to their inert surface nature. It was further demonstrated that the effects
of both covalent and non-covalent methodologies were limited in functionalizing undoped CNTs, leading to random and non-uniform
deposition of Fe2O3. In sharp contrast, it was found that, as an alternative, nitrogen-doped CNTs (N-CNTs) contributed uniform and tunable ALD-Fe2O3, due to their active surface nature induced by incorporated N atoms. Consequently, various 1D heterostructural coaxial nanotubes
were obtained with well-controlled growth of Fe2O3 on N-CNTs. For a better understanding, the underlying mechanisms were explored based on different N-doping configurations.
In addition, high-resolution transmission electron microscopy and X-ray diffraction jointly demonstrated that as-deposited
Fe2O3 is single-phase crystalline α-Fe2O3 (hematite). The as-synthesized heterostructural coaxial nanotubes of CNT@Fe2O3 may find great potential applications in photocatalysis, gas-sensing, and magnetic fields. 相似文献
27.
Ioan R. Ionescu Darko Volkov 《Journal of Computational and Applied Mathematics》2008,220(1-2):143-162
We study in this paper an eigenvalue problem (of Steklov type), modeling slow slip events (such as silent earthquakes, or earthquake nucleation phases) occurring on geological faults. We focus here on a half space formulation with traction free boundary condition: this simulates the earth surface where displacements take place and can be picked up by GPS measurements. We construct an appropriate functional framework attached to a formulation suitable for the half space setting. We perform an asymptotic analysis of the solution with respect to the depth of the fault. Starting from an integral representation for the displacement field, we prove that the differences between the eigenvalues and eigenfunctions attached to the half space problem and those attached to the free space problem, is of the order of d-2, where d is a depth parameter: intuitively, this was expected as this is also the order of decay of the derivative of the Green's function for our problem. We actually prove faster decay in case of symmetric faults. For all faults, we rigorously obtain a very useful asymptotic formula for the surface displacement, whose dominant part involves a so called seismic moment. We also provide results pertaining to the analysis of the multiplicity of the first eigenvalue in the line segment fault case. Finally we explain how we derived our numerical method for solving for dislocations on faults in the half plane. It involves integral equations combining regular and Hadamard's hypersingular integration kernels. 相似文献
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30.
Cristodor Ionescu 《代数通讯》2013,41(12):4801-4805
In this note we will prove that the Hochschild homology algebra of a topological algebra and its universally complete differential algebra are isomorphic in the case of a formally smooth morphism 相似文献