Cycloaddition of diazomethane to unsymmetrical carbodiimides and mass spectroscopy study of 1,5-disubstituted 1,2,3-Triazoles

By the reaction of unsymmetrically substituted carbodiimides with diazomethane the corresponding 1,2,3-triazoles have been obtained. The structure of the adducts was elucidated by IR, UV,¹H-NMR and high resolution mass spectrometry.

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Cycloaddition von Diazomethan an unsymmetrische Carbodiimide und massenspektroskopische Studien an 1,5-disubstituierten 1,2,3-Triazolen

Zusammenfassung Die Struktur der aus unsymmetrischen Carbodiimiden und Diazomethan gebildeten 1,2,3-Triazolen wurde durch IR-,UV-,¹H-NMR- und Massenspektrometrie aufgeklärt.

     

On art,science, beauty and the experimentalist

Comments are made on the concepts of beauty and art, and their relationship with physical phenomena. Experimental physicists have means at their disposal to produce objects of art just as the painter uses oil and the sculptor uses marble to produce objects of art. Several new photographs of “log-art” or artistic science are shown.     

Intrinsic Josephson junctions in Bi2Sr2CaCu2O8+δ single crystals

We report on thec-axis superconducting energy gap parameter Δ _c (T) of intrinsic Josephson tunnel junctions inBi ₂ Sr ₂ CaCu ₂ O _8+δ (Bi2212) single crystals. Δ _c (4.2K)≈10−13 meV, which is approximately a factor of two smaller than reported in the majority of tunneling experiments. Δ _c (T) deviates strongly from the BCS temperature dependence. These observations may be explained by a multilayer model of Bi2212 which assumes that theBi−O layers are superconducting due to the proximity effects. The Josephson tunneling then takes place between adjacentBi−O layers while there is a strong proximity coupling betweenBi−O andCu−O layers. The work is supported by Swedish Supercon-ductivity Consortium and NUTEK, and, in part, by Russian Foundation for Basic Research, grant #95-02-04307     

A high order discontinuous Galerkin Nitsche method for elliptic problems with fictitious boundary

We present a discontinuous Galerkin method, based on the classical method of Nitsche, for elliptic problems with an immersed boundary representation on a structured grid. In such methods very small elements typically occur at the boundary, leading to breakdown of the discrete coercivity as well as numerical instabilities. In this work we propose a method that avoids using very small elements on the boundary by associating them to a neighboring element with a sufficiently large intersection with the domain. This construction allows us to prove the crucial inverse inequality that leads to a coercive bilinear form and as a consequence we obtain optimal order a priori error estimates. Furthermore, we prove a bound of the condition number of the stiffness matrix. All the results are valid for polynomials of arbitrary order. We also discuss the implementation of the method and present numerical examples in three dimensions.     

Regioselective copper-catalyzed amination of chlorobenzoic acids: synthesis and solid-state structures of N-aryl anthranilic acid derivatives

[reaction, structure: see text] A chemo- and regioselective copper-catalyzed cross-coupling reaction for effective amination of 2-chlorobenzoic acids with aniline derivatives has been developed. The method eliminates the need for acid protection and produces a wide range of N-aryl anthranilic acid derivatives in up to 99% yield. The amination was found to proceed with both electron-rich and electron-deficient aryl chlorides and anilines and also utilizes sterically hindered anilines such as 2,6-dimethylaniline and 2-tert-butylaniline. The conformational isomerism of appropriately substituted N-aryl anthranilic acids has been investigated in the solid state. Crystallographic analysis of seven anthranilic acid derivatives showed formation of two distinct supramolecular architectures exhibiting trans-anti and unprecedented trans-syn dimeric structures.     

Regioselective copper-catalyzed amination of bromobenzoic acids using aliphatic and aromatic amines

A chemo- and regioselective copper-catalyzed cross-coupling procedure for amination of 2-bromobenzoic acids is described. The method eliminates the need for acid protection and produces N-aryl and N-alkyl anthranilic acid derivatives in up to 99% yield. N-(1-Pyrene)anthranilic acid has been employed in metal ion-selective fluorosensing. Titration experiments showed that this pyrene-derived amino acid forms an equimolar complex with Hg(II) in water resulting in selective fluorescence quenching even in the presence of other metal ions such as Zn(II) and Cd(II).     

The Love's problem for hyperbolic thermoelasticity

In our paper we investigated the initial-boundary value problem for elastic layer situated on half space of another elastic medium. In this medium the thermomechanical interactions were taken into consideration. The system of equations with initial-boundary conditions describes the phenomenon of wave propagation with finite speed. In our problem there are two surfaces ie. free surface and contact surface between layer and half space. On the free surface are setting boundary conditions for normal and tangent surface force. We consider two types of contact between layer and half-space: rigid contact and slip contact. The initial-boundary value problem was solved by using integral transformations and Cagniard-de Hoope methods. From the solution of this problem follows that in layer and half space exist some kind of thermoelastic waves. We investigated moreover the conditions which should be fullfiled for propagation of Rayleigh and Love's type waves on the contact surface between layers and half space. The results obtained in our investigation were used in technical applications especially engineering design and diagnostics of roads and airfields. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)