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81.
Models for the prediction of the solid/liquid interfacial energy in pure substances and binary alloys, respectively, are reviewed and extended regarding the temperature and concentration dependence of the required thermodynamic entities. A CALPHAD-type thermodynamic database is used to introduce temperature and concentration dependent melting enthalpies and entropies for multicomponent alloys in the temperature range between liquidus and solidus. Several suitable models are extended and employed to calculate the temperature and concentration dependent interfacial energy for Al–FCC with their respective liquids and compared with experimental data. 相似文献
82.
Andreas Braumann Markus Kraft Wolfgang Wagner 《Journal of computational physics》2010,229(20):7672-7691
This paper is concerned with computational aspects of a multidimensional population balance model of a wet granulation process. Wet granulation is a manufacturing method to form composite particles, granules, from small particles and binders. A detailed numerical study of a stochastic particle algorithm for the solution of a five-dimensional population balance model for wet granulation is presented. Each particle consists of two types of solids (containing pores) and of external and internal liquid (located in the pores). Several transformations of particles are considered, including coalescence, compaction and breakage. A convergence study is performed with respect to the parameter that determines the number of numerical particles. Averaged properties of the system are computed. In addition, the ensemble is subdivided into practically relevant size classes and analysed with respect to the amount of mass and the particle porosity in each class. These results illustrate the importance of the multidimensional approach. Finally, the kinetic equation corresponding to the stochastic model is discussed. 相似文献
83.
In comparison to other eukaryotic cells, mammalian oocytes are characterised by a relative high diameter allowing in turn a straightforward micromechanical testing to study their mechanical properties. The structure of mammalian oocytes is characterised by the so-called zona pellucida (ZP), a thick glycoprotein layer, surrounding the cells interior, the ooplasm. In contrast to other cells, where the load is mainly carried by inner cell structures, in case of oocytes a huge amount of external loads is carried by the ZP. Aim of this work is the determination of the mechanical properties of oocytes. Therefore, a micromechanical setup has been developed and installed on a microscope. Beside the determination of the force-strain relation during loading, the deformation of the oocytes has been recorded optically, too. Both, the force-strain curves and the optical recordings build the basis for a proper parameter identification technique based on the inverse finite element method. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
84.
In this contribution we consider a port-Hamiltonian setting for partial differential equations. A crucial property of this system class is the property to be able to link a power balance relation to the structure of the equations. However, one has to take into account also the effects of energy flows via the boundary. This is straightforward when the Hamiltonian depends on derivative variables of first order, e.g. by using integration by parts. If second-order derivatives appear then integration by parts cannot be used without due care, thus we suggest an approach by using the so-called Cartan-form. We visualize the derivation of a power balance relation by using the Kirchhoff plate as an example. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
85.
A small-deformation strain gradient plasticity (GP) model for single-crystals has been proposed in [1], including a grain boundary (GB) yield condition without hardening. It has been extended by a hardening term for the GBs after a comparison to discrete dislocation dynamics (DDD) results in [2]. Differences between the strain gradients of the GP results and the DDD results motivate the consideration of a non-quadratic defect energy [3] in the GP model. It is shown that the gradients in the GP model can be improved using an exponent different from two. Remaining discrepancies in the strain profiles, compared to the DDD results, are attributed to the neglect of the individual gradients of plastic slip and due to the lack of a mechanism for the misorientation-dependent elastic interactions of dislocations across GBs [4] in the GP model. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
86.
M. Zeeman C. M. Auer R. G. Clements J. V. Nabholz R. S. Boethling 《SAR and QSAR in environmental research》2013,24(3):179-201
Abstract As testing is not required, ecotoxicity or fate data are available for ≈ 5% of the approximately 2,300 new chemicals/year (26,000 + total) submitted to the US-EPA. The EPA's Office of Pollution Prevention and Toxics (OPPT) regulatory program was forced to develop and rely upon QSARs to estimate the ecotoxicity and fate of most of the new chemicals evaluated for hazard and risk assessment. QSAR methods routinely result in ecotoxicity estimations of acute and chronic toxicity to fish, aquatic invertebrates, and algae, and in fate estimations of physical/chemical properties, degradation, and bioconcentration. The EPA's Toxic Substances Control Act (TSCA) Inventory of existing chemicals currently lists over 72,000 chemicals. Most existing chemicals also appear to have little or no ecotoxicity or fate data available and the OPPT new chemical QSAR methods now provide predictions and cross-checks of test data for the regulation of existing chemicals. Examples include the Toxics Release Inventory (TRI), the Design for the Environment (DfE), and the OECD/SIDS/HPV Programs. QSAR screening of the TSCA Inventory has prioritized thousands of existing chemicals for possible regulatory testing of: 1) persistent bioaccumulative chemicals, and 2) the high ecotoxicity of specific discrete organic chemicals. 相似文献
87.
88.
The new ternary carbodiimide LiY(CN2)2 was synthesized by solid state metathesis reaction between YF3 and Li2(CN2) in a silica tube at 550 °C. The X‐ray single‐crystal structure determination yielded an orthorhombic crystal system (Pbcn, Z = 4, a = 982.0(3), b = 698.5(2), c = 613.4(2) pm). The crystal structure can be considered related to the NiAs structure. The carbodiimide ions are arranged in layers following the motif of a hexagonal closest packing of sticks. Lithium and yttrium cations occupy all octahedral voids in an ordered fashion, alternating on top of each other along the hcp stacking direction. 相似文献
89.
90.
Li Luo Kathrin Häfliger Dan Xie Markus Niederberger 《Journal of Sol-Gel Science and Technology》2013,65(1):28-35
Homogeneous transparent conducting Sn:ZnO films on fused silica substrates were prepared by dip-coating from nanoparticle dispersions, while the nanocrystalline Sn:ZnO particles with different dopant concentrations were synthesized by microwave-assisted non-aqueous sol–gel process using Sn(IV) tert-butoxide and Zn(II) acetate as precursors and benzyl alcohol as solvent. The dopant concentration had a great impact on the electrical properties of the films. A minimum resistivity of 20.3 Ω cm was obtained for a porous Sn:ZnO film with initial Sn concentration of 7.5 mol% after annealing in air and post-annealing in N2 at 600 °C. The resistivity of this porous film could further be reduced to 2.6 and 0.6 Ω cm after densified in Sn:ZnO and Al:ZnO reaction solution, respectively. The average optical transmittance of a 400-nm-thick Sn:ZnO film densified with Sn:ZnO after the two annealing steps was 91%. 相似文献