全文获取类型
收费全文 | 551篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 427篇 |
晶体学 | 1篇 |
力学 | 5篇 |
数学 | 20篇 |
物理学 | 105篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 13篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2016年 | 2篇 |
2015年 | 6篇 |
2014年 | 11篇 |
2013年 | 29篇 |
2012年 | 30篇 |
2011年 | 27篇 |
2010年 | 17篇 |
2009年 | 17篇 |
2008年 | 36篇 |
2007年 | 39篇 |
2006年 | 34篇 |
2005年 | 25篇 |
2004年 | 31篇 |
2003年 | 25篇 |
2002年 | 23篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1996年 | 9篇 |
1995年 | 3篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 13篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1974年 | 5篇 |
1973年 | 2篇 |
1961年 | 1篇 |
1938年 | 1篇 |
1937年 | 1篇 |
排序方式: 共有558条查询结果,搜索用时 15 毫秒
11.
Akira Yamasaki 《Analytica chimica acta》1981,133(4):741-746
The TOOL-IR. PDB and COOD systems are compared for the construction of data bases for 59Co-n.m.r. bibliographic and spectral data. The spectral data used are the chemical shifts from several different standards, and the line widths and coupling constants (if present). The PDB system is effective for storage and retrieval of bibliographic data, but the COOD system is better for the retrieval of spectral data, and for combination of data files on literature and chemical shifts. 相似文献
12.
13.
Hiroyuki Ishibashi Motofumi Okada Atsuko Akiyama Kazuyuki Nomura Masazumi Ikeda 《Journal of heterocyclic chemistry》1986,23(4):1163-1166
2,3-Dihydro-5H-1,4-benzoxathiepins were prepared by intramolecular Friedel-Crafts reactions of ethyl α-[2-(aryloxy)ethylthio]-α-chloroacetates or by acid-catalyzed cyclizations of ethyl α-[2-(aryloxy)ethylsulfinyl]-acetate. 1,2,3,5-Tetrahydro-4,1-benzothiazepines were similarly prepared. 相似文献
14.
15.
16.
17.
The hydrophobic dyes tetrabromophenolphthalein ethyl ester and 2,6-dichlorophenolindo-phenol are proposed as visual indicators for two-phase titrations. The aqueous phase is colourless throughout the titration and these indicators make it possible to detect the end-point of the titration by the colour of one or the other phase. The indicators allow the two-phase titration of the silver(I)-1,10-phenanthroline complex with tetraphenylborate and of pentachlorophenol with tetraphenylphosphonium chloride. 相似文献
18.
19.
Tokuda N Sasaki N Watanabe H Miki K Yamasaki S Hasunuma R Yamabe K 《The journal of physical chemistry. B》2005,109(26):12655-12657
Electroless deposition of Ag on atomically flat H-terminated Si(111) surfaces in aqueous alkaline solutions containing Ag ions produced two different sizes of Ag nanowires along atomic step edges: (1) a narrow nanowire of 10 nm in width and 0.5 nm in height and (2) a wide nanowire of 35 nm in width and 11 nm in height. The narrow and wide nanowires were formed by immersion in the solutions containing less than 1 ppb and 8 ppm dissolved-oxygen concentrations, respectively. This result indicates that the dissolved oxygen initiates the formation of Ag nucleation sites and that the fabrication method has a possibility of controlling the size of Ag nanowires. 相似文献
20.
K Otsubo S Morita M Uchida K Yamasaki T Kanbe T Shimizu 《Chemical & pharmaceutical bulletin》1991,39(11):2906-2909
The enantiomers of 2-(4-chlorobenzoylamino)-3-[2(1H)-quinolinon-4-yl] propionic acid [(+/-)-1, rebamipide, OPC-12759], a new antiulcer agent that enhances mucosal resistance, were synthesized from optically active alpha-amino acid derivatives of 2(1H)-quinolinone. The key intermediates, alpha-amino acid derivatives, were prepared by asymmetric synthesis and optical resolution. The (+)-1 was about 1.7 times as potent as the (-)-isomer in antiulcer activity against ethanol-induced gastric ulcers. 相似文献