全文获取类型
收费全文 | 651篇 |
免费 | 85篇 |
专业分类
化学 | 596篇 |
晶体学 | 1篇 |
数学 | 41篇 |
物理学 | 98篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 17篇 |
2019年 | 26篇 |
2018年 | 12篇 |
2017年 | 4篇 |
2016年 | 40篇 |
2015年 | 36篇 |
2014年 | 18篇 |
2013年 | 38篇 |
2012年 | 48篇 |
2011年 | 39篇 |
2010年 | 23篇 |
2009年 | 31篇 |
2008年 | 55篇 |
2007年 | 47篇 |
2006年 | 37篇 |
2005年 | 51篇 |
2004年 | 27篇 |
2003年 | 35篇 |
2002年 | 14篇 |
2001年 | 14篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1994年 | 9篇 |
1993年 | 11篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 7篇 |
1981年 | 1篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 5篇 |
1975年 | 1篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有736条查询结果,搜索用时 296 毫秒
91.
92.
93.
94.
Anomalous dielectric behavior and thermal motion of water molecules confined in channels of porous coordination polymer crystals 总被引:1,自引:0,他引:1
Zhou B Kobayashi A Cui HB Long LS Fujimori H Kobayashi H 《Journal of the American Chemical Society》2011,133(15):5736-5739
Guest water molecules confined in channels of porous coordination polymer crystals [Ln(2)Cu(3)(IDA)(6)]·nH(2)O (Ln = La, Nd, Sm, Gd, Ho, Er; IDA = [NH(CH(2)COO)(2)](2-); n ≈ 9) exhibited large dielectric constants (ε) and antiferroelectric behaviors at high temperatures (e.g., ε(Sm) ≈ 1300 at 400 K). In addition, plots of the temperature dependence of ε showed broad peaks at ~170 K, below which ε became very small. These puzzling temperature dependences of ε are consistent with the results of molecular dynamics simulations, suggesting the "freezing of thermal motion" of water molecules at ~170 K. 相似文献
95.
Urita K Shiga Y Fujimori T Iiyama T Hattori Y Kanoh H Ohba T Tanaka H Yudasaka M Iijima S Moriguchi I Okino F Endo M Kaneko K 《Journal of the American Chemical Society》2011,133(27):10344-10347
An outstanding compression function for materials preparation exhibited by nanospaces of single-walled carbon nanohorns (SWCNHs) was studied using the B1-to-B2 solid phase transition of KI crystals at 1.9 GPa. High-resolution transmission electron microscopy and synchrotron X-ray diffraction examinations provided evidence that KI nanocrystals doped in the nanotube spaces of SWCNHs at pressures below 0.1 MPa had the super-high-pressure B2 phase structure, which is induced at pressures above 1.9 GPa in bulk KI crystals. This finding of the supercompression function of the carbon nanotubular spaces can lead to the development of a new compression-free route to precious materials whose syntheses require the application of high pressure. 相似文献
96.
Hayashi SY Tsurumaki E Inokuma Y Kim P Sung YM Kim D Osuka A 《Journal of the American Chemical Society》2011,133(12):4254-4256
Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14π-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials. 相似文献
97.
Brown MA Fujimori Y Ringleb F Shao X Stavale F Nilius N Sterrer M Freund HJ 《Journal of the American Chemical Society》2011,133(27):10668-10676
The nucleation and electronic structure of vapor-deposited Au on hydroxylated MgO(001) surfaces has been investigated under ultrahigh vacuum conditions. Hydroxylated MgO(001) surfaces with two different hydroxyl coverages, 0.4 and 1 monolayer, respectively, were prepared by exposure to water (D(2)O) at room temperature. Scanning tunneling microscopy experiments show significantly higher gold particle densities and smaller particle sizes on the hydroxylated MgO surface as compared to gold deposited on clean MgO(001). Infrared spectroscopy and X-ray photoelectron spectroscopy experiments were performed to reveal details about the initial nucleation of gold. Gold atoms are found to chemically interact with a specific type of hydroxyl groups on the MgO surface, leading to the formation of oxidized gold particles. The enhanced adhesion of Au particles, which is due to the formation of strong Au-O interfacial bonds, is responsible for the observed higher stability of small Au clusters toward thermal sintering on hydroxylated MgO surfaces. The results are compared to similar studies on Au/TiO(2)(110) model systems and powder samples prepared by the deposition-precipitation route. 相似文献
98.
meso-Aryl-substituted expanded porphyrins that are porphyrin homologues consisting of more than five pyrrolic units are a nice platform to realize diverse aromatic and antiaromatic species as well as stable radical species. They are also an ideal series to realize topologically twisted molecules with distinct M?bius aromaticity and antiaromaticity. 相似文献
99.
100.